• Journal of ILASS-Korea
• /
• v.3 no.3
• /
• pp.14-22
• /
• 1998

The growth by steam condensation of an hygroscopic aerosol is investigated using the condensation rate model which has been derived from the mass and heat transfer equations. The present model accounts for both the solute and Kelvin effects. When the hygroscopicity is considered, condensation can occur on hygroscopic seed particles even under subsaturated steam conditions. This study focuses on the effect of hygroscopicity on the evolution of the particle size distribution and decay of the total aerosol concentration. It is found that hygroscopicity causes the particle size distribution to rapidly move upward even in a very short time, resulting in substantially higher decay of the total aerosol concentration than the case without considering hygroscopicity.

• Transactions of the Korean Society of Machine Tool Engineers
• /
• v.12 no.4
• /
• pp.9-16
• /
• 2003

In this study, the decision of dressing time for diamond wheel was analyzed by observing with acoustic emission signals and surface roughness, and also obtained the machining characteristics by weibull distribution plot for the values of bending strength. From the experimental study, it was possible to predict the time of re-dressing for the diamond grinding wheel with the analysis of acoustic emission signals and surface roughness values, and following conclusions were obtained. The root-mem-square values of acoustic emission signals were obtained low as the increased of table speed for different abrasive grain size. This is caused by the lack of grinding power which is not able to get rid of all real grinding mass of depth as the table speed is increased. The values of bending strength for ground $Si_3 N_4$ specimens were decreased for gain size of #400 than that of #60, but it was found that the surface roughness values for gain size of #60 were better than that of #400. As compared the shape parameter of weibull distribution plot for the values of bending strength, it was found that the reliability of bending strength for grain size of #60 increased than that of #400.

• Economic and Environmental Geology
• /
• v.50 no.1
• /
• pp.61-71
• /
• 2017

The effects of joint density and size distribution on the hydrogeologic characteristics of jointed rock masses are addressed through numerical experiments based on the 2-D DFN (discrete fracture network) fluid flow analysis. Using two joint sets, a total of 51 2-D joint network system were generated with various joint density and size distribution. Twelve fluid flow directions were chosen every $30^{\circ}$ starting at $0^{\circ}$, and total of 612 $20m{\times}20m$ DFN blocks were prepared to calculate the directional block conductivity. Also, the theoretical block conductivity, principal conductivity tensor and average block conductivity for each generated joint network system were determined. The directional block conductivity and chance for the equivalent continuum behavior of the 2-D DFN system were found to increase with the increase of joint density or size distribution. However, the anisotropy of block hydraulic conductivity increases with the increase of density discrepancy between the joint sets, and the chance for the equivalent continuum behavior were found to decrease. The smaller the intersection angle of the two joint sets, the more the equivalent continuum behavior were affected by the change of joint density and size distribution. Even though the intersection angle is small enough that it is difficult to have equivalent continuum behavior, the chance for anisotropic equivalent continuum behavior increases as joint density or size distribution increases.

• Toxicological Research
• /
• v.30 no.1
• /
• pp.55-63
• /
• 2014

Objectives: The use of indium compounds, especially those of small size, for the production of semiconductors, liquid-crystal panels, etc., has increased recently. However, the role of particle size or the chemical composition of indium compounds in their toxicity and distribution in the body has not been sufficiently investigated. Therefore, the aim of this study was to examine the effects of particle size and the chemical composition of indium compounds on their toxicity and distribution. Methods: Male Sprague-Dawley rats were exposed to two different-sized indium oxides (average particle sizes under 4,000 nm [IO_4000] and 100 nm [IO_100]) and one nano-sized indium-tin oxide (ITO; average particle size less than 50 nm) by inhalation for 6 hr daily, 5 days per week, for 4 weeks at approximately $1mg/m^3$ of indium by mass concentration. Results: We observed differences in lung weights and histopathological findings, differential cell counts, and cell damage indicators in the bronchoalveolar lavage fluid between the normal control group and IO- or ITO-exposed groups. However, only ITO affected respiratory functions in exposed rats. Overall, the toxicity of ITO was much higher than that of IOs; the toxicity of IO_4000 was higher than that of IO_100. A 4-week recovery period was not sufficient to alleviate the toxic effects of IO and ITO exposure. Inhaled indium was mainly deposited in the lungs. ITO in the lungs was removed more slowly than IOs; IO_4000 was removed faster than IO_100. IOs were not distributed to other organs (i.e., the brain, liver, and spleen), whereas ITO was. Concentrations of indium in the blood and organ tissues were higher at 4 weeks after exposure. Conclusions: The effect of particle size on the toxicity of indium compounds was not clear, whereas chemical composition clearly affected toxicity; ITO showed much higher toxicity than that of IO.

• Journal of Environmental Science International
• /
• v.22 no.3
• /
• pp.347-358
• /
• 2013

The aerosol number concentration have measured with an aerodynamic particle sizer spectrometer(APS) at Gosan in Jeju Island, which is known as background area in Korea, from March 2010 to February 2011. The obtained results of asian dust events and non-asian dust period have been compared. The results show that the entire averaged aerosol number concentration from APS measurement during asian dust events and non-asian dust period are about 341 particles/$cm^3$ and 240 particles/$cm^3$, respectively. During asian dust events, the number concentration in small size ranges(${\leq}0.4{\mu}m$) are similar to non-asian dust period, however, those in large size ranges(${\geq}0.7{\mu}m$) are very higher than non-asian dust period. The contributions of the size resolved number concentration(23 channel in $0.25{\sim}10.0{\mu}m$) to total number concentration in that range are dramatically decreased with increased particle size. The contributions of smaller size ranges(${\leq}0.4{\mu}m$) during asian dust events are very low compared with non-asian dust period, on the other hand, those of larger size ranges(${\geq}0.4{\mu}m$) are higher than non-asian dust period. The number concentration in each size range are strongly correlated with the concentration in adjacent size range. And the total aerosol number concentration are depended on the number concentration in range of smaller than $0.58{\mu}m$ during non-asian dust period and asian dust events. On the other hand, $PM_{10}$ mass concentration has mainly affected with the number concentration in range of smaller than $1.0{\mu}m$ during non-asian dust period, however, during asian dust events, the mass concentration has mainly affected with the number concentration in range of $0.65{\sim}3.0{\mu}m$.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.2
• /
• pp.309-314
• /
• 2002

The ablation dynamics and cluster formation of $C_n^+$ ions ejected from 355 nm laser ablation of a graphite target in vacuum are investigated using a reflectron time-of-flight (RTOF) mass spectrometer. At low laser fluence, odd-numbered cluster ions with $3{\leq}n{\leq}15$ are predominantly produced. Increasing the laser fluence shifts the maximum size distribution towards small cluster ions, implying the fragmentation of larger clusters within the hot plume. The temporal evolution of $C_n^+$ ions was measured by varying the delay time of the ion extraction pulse with respect to the laser irradiation, providing significant information on the characteristics of the ablated plume. Above a laser fluence of $0.2J/cm^2$ , large cluster ions ($n{\geq}30$) are produced at relatively long delay times, indicating that atoms or small carbon clusters aggregate during plume propagation. The dependence of the intensity of ablated $C_n^+$ ions on delay time after laser irradiation shows that the most probable velocity of each cluster ion decreases with cluster size.

• Journal of Korean Society for Atmospheric Environment
• /
• v.11 no.3
• /
• pp.263-272
• /
• 1995

Characteristics of anbient at Korean, Cheju Island have been studied during the intensive field study period on March 11 .sim. 17, 1994 in collaboration with other research organizations from Korea and abroad. The particle size distribution was measured using an Electrical Aerosol Analyzer(EAA) and an Optical particle Counter(OPC). Fine particles(PM1 and PM3) have been collected by filter pack samplers and their ionic compositions have been analyzed. sampling errors inherent to the filter pack sampling method are discussed and the method to analyze those errors are presented. The rine mass concentrations of this study show very similar mass concentrations when Seoul is clear. This is somewhat surprising result, because the most of researchers believe that Kosan is one of the cleanest area in Korea. Bimodal volume size distributions with peak values around 0.1 .sim. 0.2.mu.m and 3.mu.m in particle dimeter were observed for most of the measurement period, particle mass loadings and ionic composition data show a large fraction of particles are from non-sea salt origins. Estimation of water content and acidity of particles based on measurement by a gas/particle equilibrium model, SCAPE, reveals that the pH values of particles are comparable to or lower than those estimated based on measurements in Los Angeles, U.S.A. during the SCAQS study. These findings with the meteorological conditions during the study period suggest that the particles collected during the period have originated from outside Cheju Island.

• Journal of the Korean Vacuum Society
• /
• v.10 no.2
• /
• pp.275-281
• /
• 2001

We used the discrete-sectional model to analyze the particle growth by coagulation of particles in silane plasma reactor, considering the Gaussian distribution function for particle charges. The effects of process conditions such as monomer size and mass generation rate of monomers on particle growth in plasma reactor were analyzed theoretically/ Based on the Gaussian distribution function of particle charges, the large particles of more than 40 nm in size are almost found to be charged negatively, but some fractions of small, tiny particles are in neutral state or even charged positively. As the particle size and surface area increase with time by particle coagulation, the number of charges per particle increases with time. As the large particles are generated by particle coagulation, the particle size distribution become bimodal. The results of discrete-sectional model for the particle growth in silane plasma reactor were in close agreement with the experimental results by Shiratani et al. [3] for the same plasma conditions. We believe the model equations for the particle charge distribution and coagulation between particles can be applied to understand the nano-sized particle growth in plasma reactor.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.36 no.9
• /
• pp.885-894
• /
• 2012

A numerical study of a microchannel steam methane reforming reactor has been performed to understand the characteristics of heat and mass transfer. The integration of Rh-catalyzed steam methane reforming and Pt-catalyzed methane combustion has been simulated. The reaction rates for chemical reactions have been incorporated into the simulation. This study investigated the effect of contact time, flow pattern (parallel or counter), and channel size on the reforming performance and temperature distribution. The parallel and counter flow have opposite temperature distribution, and they show a different type of reaction rate and species mole fraction. As the contact time decreases and channel size increases, mass transfer between the catalyst layer and the flow is limited, and the reforming performance is decreased.

• Atmosphere
• /
• v.26 no.3
• /
• pp.435-444
• /
• 2016

In spite of considerable progress in the recent decades, there still remain large uncertainties in numerical cloud models. In this study, effects of uncertainty in terminal velocity of graupel on cloud simulation are investigated. For this, a two-dimensional bin microphysics cloud model is employed, and deep convective clouds are simulated under idealized environmental conditions. In the sensitivity experiments, the terminal velocity of graupel is changed to twice and half the velocity in the control experiment. In the experiment with fast graupel terminal velocity, a large amount of graupel mass is present in the lower layer. On the other hand, in the experiment with slow graupel terminal velocity, almost all graupel mass remains in the upper layer. The graupel size distribution exhibits that as graupel terminal velocity increases, in the lower layer, the number of graupel particles increases and the peak radius in the graupel mass size distribution decreases. In the experiment with fast graupel terminal velocity, the vertical velocity is decreased mainly due to a decrease in riming that leads to a decrease in latent heat release and an increase in evaporative cooling via evaporation, sublimation, and melting that leads to more stable atmosphere. This decrease in vertical velocity causes graupel particles to fall toward the ground easier. By the changes in graupel terminal velocity, the accumulated surface precipitation amount differs up to about two times. This study reveals that the terminal velocity of graupel should be estimated more accurately than it is now.