• Title/Summary/Keyword: Mass loss rate

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Burning Behavior of Flooring Materials in the Cone Calorimeter and Evaluation of Toxic Smoke (콘 칼로리미터를 이용한 건축 바닥재의 연소거동과 가스유해성 평가)

  • Lee, Jang-Won;Lee, Bong-Woo;Kwon, Seong-Pil;Lee, Byoung-Ho;Kim, Hee-Soo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.1
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    • pp.45-53
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    • 2008
  • The burning behaviors of board for flooring materials were investigated using cone calorimetry at an incident heat flux of $50kWm^{-2}$. Seven domestic flooring materials were used to observe the burning behavior of maximum heat release rate, total heat release and average heat release rate. The experimental data indicated that the medium density fiberboard (MDF) flooring had higher release rate than the other flooring materials. Also, the mass loss of MDF flooring was higher than the other floors. When measuring the smoke production from burning, PE fiberboard flooring and PVC Plastic Resin Sheet showed higher carbon monoxide and carbon dioxide yield than the others. The average smoke release of both carbon dioxide and carbon monoxide through specific extinction area was similar. Toxic smoke measurement from flooring materials were determined by the mouse stop motion, and the results indicated that MDF flooring contains more toxic material than the other flooring materials.

Biosurfactant as a microbial pesticide

  • Lee, Baek-Seok;Choi, Sung-Won;Choi, Ki-Hyun;Lee, Jae-Ho;Kim, Eun-Ki
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.40-44
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    • 2003
  • Soil-borne infectious disease including Pythium aphanidermatum and Rhizoctonia solani causes severe damage to plants, such as cucumber. This soil-borne infectious disease was not controlled effectively by chemical pesticide. Since these diseases spread through the soil, chemical agents are usually ineffective. Instead, biological control, including antagonistic microbe can be used as a preferred control method. An efficient method was developed to select an antagonistic strain to be used as a biological control agent strain. In this new method, surface tension reduction potential of an isolate was included in the ‘decision factor’ in addition to the other factors, such as growth rate, and pathogen inhibition rate. Considering these 3 decision factors by a statistical method, an isolate from soil was selected and was identified as Bacillus sp. GB16. In the pot test, this strain showed the best performance among the isolated strains. The lowest disease incidence rate and fastest seed growth was observed when Bacillus sp. GB16 was used. Therefore this strain was considered as plant growth promoting rhizobacteria (PGPR). The action of surface tension reducing component was deduced as the enhancement of wetting, spreading, and residing of antagonistic strain in the rhizosphere. This result showed that new selection method was significantly effective in selecting the best antagonistic strain for biological control of soil-borne infectious plant pathogen. The antifungal substances against P. aphanidermatum and R. solani were partially purified from the culture filtrates of Bacillus sp. GB16. In this study, lipopeptide possessing antifungal activity was isolated from Bacillus sp. GB16 cultures by various purification procedures and was identified as a surfactin-like lipopeptide based on the Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), high performance liquid chromatography mass spectroscopy (HPLC-MS), and quadrupole time-of-flight (Q-TOF) ESI-MS/MS data. The lipopeptide, named GB16-BS, completely inhibited the growth of Pythium aphanidermatum, Rhizoctonia solani, Penicillium sp., and Botrytis cineria at concentrations of 10 and 50 mg/L, respectively. A novel method to prevent the foaming and to provide oxygen was developed. During the production of surface active agent, such as lipopeptide (surfactin), large amount of foam was produced by aeration. This resulted in the carryover of cells to the outside of the fermentor, which leads to the significant loss of cells. Instead of using cell-toxic antifoaming agents, low amount of hydrogen peroxide was added. Catalase produced by cells converted hydrogen peroxide into oxygen and water. Also addition of corn oil as an oxygen vector as well as antifoaming agent was attempted. In addition, Ca-stearate, a metal soap, was added to enhance the antifoam activity of com oil. These methods could prevent the foaming significantly and maintained high dissolved oxygen in spite of lower aeration and agitation. Using these methods, high cell density, could be achieved with increased lipopeptide productivity. In conclusion to produce an effective biological control agent for soil-borne infectious disease, following strategies were attempted i) effective screening of antagonist by including surface tension as an important decision factor ii) identification of antifungal compound produced from the isolated strain iii) novel oxygenation by $H_2O_2-catalase$ with vegetable oil for antifungal lipopeptide production.

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Optimization Strategies for Amine Regeneration Process with Heat-Stable Salt Removal Unit (열 안정성 염 제거장치를 고려한 아민 재생 공정 최적화 전략)

  • Lee, Jesung;Lim, Jonghun;Cho, Hyungtae;Kim, Junghwan
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.575-580
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    • 2020
  • In this study, we simulated an amine regeneration process with heat-stable salts removal unit. We derived the optimal operating conditions considering the flow rate of waste, the removal rate of heat-stable salts, and the loss rate of MDEA (methyl diethanolamine). In the amine regeneration process that absorbs and removes acid gas, heat-stable salt impairs the absorption efficiency of process equipment and amine solution. An ion exchange resin method is to remove heat-stable salts through neutralization by using a strong base solution such as NaOH. The acid gas removal process was established using the Radfrac model, and the equilibrium constant of the reaction was calculated using Gibbs free energy. The removed amine solution is separated and flows to the heat-stable salts remover which is modeled by using the Rstoic model with neutralization reaction. Actual operation data and simulation results were compared and verified, and also a case study was conducted by adjusting the inflow mass of removal unit followed by suggesting optimal conditions.

Optimal flammability and thermal buckling resistance of eco-friendly abaca fiber/ polypropylene/egg shell powder/halloysite nanotubes composites

  • Saeed Kamarian;Reza Barbaz-Isfahani;Thanh Mai Nguyen Tran;Jung-Il Song
    • Advances in nano research
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    • v.16 no.2
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    • pp.127-140
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    • 2024
  • Upon direct/indirect exposure to flame or heat, composite structures may burn or thermally buckle. This issue becomes more important in the natural fiber-based composite structures with higher flammability and lower mechanical properties. The main goal of the present study was to obtain an optimal eco-friendly composite system with low flammability and high thermal buckling resistance. The studied composite consisted of polypropylene (PP) and short abaca fiber (AF) with eggshell powder (ESP) and halloysite clay nanotubes (HNTs) additives. An optimal base composite, consisting of 30 wt.% AF and 70 wt.% PP, abbreviated as OAP, was initially introduced based on burning rate (BR) and the Young's modulus determined by horizontal burning test (HBT) and tensile test, respectively. The effects of adding ESP to the base composite were then investigated with the same experimental tests. The results indicated that though the BR significantly decreased with the increase of ESP content up to 6 wt.%, it had a very destructive influence on the stiffness of the composite. To compensate for the damaging effect of ESP, small amount of HNT was used. The performance of OAP composite with 6 wt.% ESP and 3 wt.% HNT (OAPEH) was explored by conducting HBT, cone calorimeter test (CCT) and tensile test. The experimental results indicated a 9~23 % reduction in almost all flammability parameters such as heat release rate (HRR), total heat released (THR), maximum average rate of heat emission (MARHE), total smoke released (TSR), total smoke production (TSP), and mass loss (ML) during combustion. Furthermore, the combination of 6 wt.% ESP and 3 wt.% HNT reduced the stiffness of OAP to an insignificant amount by maximum 3%. Moreover, the char residue analysis revealed the distinct differences in the formation of char between AF/PP and AF/PP/ESP/HNT composites. Afterward, dilatometry test was carried out to examine the coefficient of thermal expansion (CTE) of OAP and OAPEH samples. The obtained results showed that the CTE of OAPEH composite was about 18% less than that of OAP. Finally, a theoretical model was used based on first-order shear deformation theory (FSDT) to predict the critical bucking temperatures of the OAP and OAPEH composite plates. It was shown that in the absence of mechanical load, the critical buckling temperatures of OAPEH composite plates were higher than those of OAP composites, such that the difference between the buckling temperatures increased with the increase of thickness. On the contrary, the positive effect of CTE reduction on the buckling temperature decreased by raising the axial compressive mechanical load on the composite plates which can be assigned to the reduction of stiffness after the incorporation of ESP. The results of present study generally stated that a suitable combination of AF, PP, ESP, and HNT can result in a relatively optimal and environmentally friendly composite with proper flame and thermal buckling resistance with no significant decline in the stiffness.

A Study on the Carbothermic Reduction of Nb-Oxide and the refining by Ar/Ar-$H_2$ plasma and Hydrogen solubility of Nb metal (Ar/Ar-$H_2$ 플라즈마에 의한 Nb금속제조와 Nb금속의 수소용해)

  • Jeong, Yong-Seok;Hong, Jin-Seok;Kim, Mun-Cheol;Baek, Hong-Gu
    • Korean Journal of Materials Research
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    • v.3 no.6
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    • pp.565-574
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    • 1993
  • The Ar/Ar- $H_{2}$ plasma method Lvas applied to reduce and refine high purity Nb metal. Inaddition, the reaction between molten Nb metal and hydrogen were also analyzed in the Ar-(20%)$H_{2}$plasma. The metallic Nb of 99.5wt% was obtained at the ratio of $C/Nb_{2}O_{5}$=5.00 in the Ar plasma reductionand the $O_2$ loss from the thermal decomposition of niobium oxides did not take place. In the Ar-(20%)Hi plasma the metallic Nb of 99.8wt% was produced at the ratio of $C/Nb_{2}O_{5}$=4.80. It was observedthat a major reaction of the deoxidation was the reaction with H, Hi, and a deoxidation by the evaporationof $NbO_x$ did not occur but a mass loss of Nb did by a "splash" effect. The deoxidation reaction rateobeyed the 1st order reaction kinetics and the reaction rate constant(k') of deoxidation was $7.8 \times 10_{-7}$(m/sec).The solubility of hydrogen in Nb metal was 60ppm and it was larger than the solubility of molecularstate hydrogen by 40ppm in the Ar-(20%)$H_{2}$ plasma method. A saturation was within 60sec anda hydrogen content was reduced below lOppm by a Ar plasma re-treatment.by a Ar plasma re-treatment.

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Modeling of the Cycle Life of a Lithium-ion Polymer Battery (리튬 이온 폴리머 전지의 사이클 수명 모델링)

  • Kim, Ui Seong;Lee, Jungbin;Yi, Jaeshin;Shin, Chee Burm;Choi, Je Hun;Lee, Seokbeom
    • Korean Chemical Engineering Research
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    • v.47 no.3
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    • pp.344-348
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    • 2009
  • One-dimensional modeling was carried-out to predict the capacity loss of a lithium-ion polymer battery during cycling. The model not only accounted for electrochemical kinetics and ionic mass transfer in a battery cell, but also considered the parasitic reaction inducing the capacity loss. In order to validate the modeling, modeling results were compared with the measurement data of the cycling behaviors of the lithium-ion polymer batteries having nominal capacity of 5Ah from LG Chem. The cycling was performed under the protocol of the constant current discharge and the constant current and constant voltage charge. The discharge rate of 1C was used. The range of state of charge was between 1 and 0.2. The voltage was kept constant at 4.2 V until the charge current tapered to 50 mA. The retention capacity of the battery was measured with 1C and 5C discharge rates before the beginning of cycling and after every 100 cycles of cycling. The modeling results were in good agreement with the measurement data.

Prediction and Evaluation of Indoors Noise Level of Exhibition Room in Museum by Road Traffic Noise (도로교통소음으로 인한 박물관 전시실의 실내 소음레벨 예측 및 평가)

  • Lee, Kook-Hyun;Park, Yeong-Ji;Kim, Jae-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.787-794
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    • 2010
  • Recently, with sudden increase of supplying rate of cars and quantity of goods transported, traffic noisy becomes one of important factors obstruct environment of exhibition and view facilities have purpose in calmness and unsatisfaction about this is high now. Therefore, in case of exhibition and view facilities, it has to be grasped that satisfaction degree about the noisy in and out of the exhibition room by performing effect valuation on traffic noisy from design step. However the level of internal noise cannot be measured at the design phrase of the structure due to the noise of traffic. Up until now a walls transmission loss, based on the law of mass, is predicted using this method. However measuring the internal sound level after actual construction reveals that there is a large difference from measurements made at the design stage, and it is very difficult to find a solution after the opening of the structure. From research looking from this perspective the internal sound level was predicted- calculating the internal sound absorption ability, using acoustic simulation and loss prevention of an insulated wall- based on data collected to evaluate the internal sound of an exhibition room at a Folk Museum adjacent to a freeway. The results of this research are considered to provide important data for the prediction of internal sound level at the time of construction of exhibition facilities similar to this.

INTERACTION OF SUPERNOVA REMNANTS WITH STELLAR-WIND BUBBLES (초신성 잔해와 항성풍 공동간의 상호 작용)

  • Lee, Jae-Kwan;Koo, Bon-Chul
    • Publications of The Korean Astronomical Society
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    • v.12 no.1
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    • pp.111-143
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    • 1997
  • We have developed a spherical FCT code in order to simulate the interaction of supernova remnants with stellar wind bubbles. We assume that the density profile of the supernova ejecta follows the Chevalier mode1(1982) where the outer portion has a power-law density distribution($\rho{\propto}\gamma^{-n}$) and the SN ejecta has a kinetic energy of $10^{51}$ ergs. The structure of wind bubble has been calculated with the stellar mass loss rate $\dot{M}=5\times10^{-6}M_{\odot}/yr$ and the wind velocity $\upsilon=2\times10^3$ km/s We have simulated seven models with different initial conditions In the first two models we computed the evolution of SNRs with n=7 and n=14 in the uniform medium The numerical results agree with the Chevalier's similarity solution at early times. When all of the power-law portion of the ejecta is swept up by the reverse shock, the evolution slowly converges to the Sedov-Taylor stage. There is not much difference between the two cases with different n's The other five models simulate SNRs produced inside wind bubbles. In model III, we consider the SN ejecta of 1.4 $M_{\odot}$ and the radius of bubble ~2.76 pc so that ratio of the mass $\alpha(=M_{W.S}/M_{ej}$ is 2. We follow the complex hydrodynamic flows produced by the interaction of SN shocks with stellar shocks and with the contact discontinuities, In the model III, the time scale for the SN shock to cross the wind shell $\tau_{cross}$ is similar to the time scale for the reverse shock to sweep the power-law density profile $\tau_{bend}$. Hence the SN shock crosses the wind shell. At late times SN shock produces another shell in the ambient medium so that we have a SNR with double shell structure. From the numerical results of the remaining models, we have found that when $\tau_{cross}/\tau_{bend}\leq2$, or equivalently when $\alpha\leq50$, the SNRs produced inside wind bubbles have double shell structure. Otherwise, either the SN shock does not cross the wind shell or even if it crosses at one time, the reverse shock reflected at the center accelerates the wind shell to merge into the SN shock Our results confirm the conclusion of Tenorio-Tagle et a1(1990).

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Evaluation of Thermoregulatory Properties of Thermal Underwear Named as 'Heating Underwear' using Thermal Manikin and Human Performance Test ('발열내복'이라 광고되는 시판 기능성 보온내복의 써멀 마네킹과 인체 착용 실험을 통한 체온조절 성능 평가)

  • Lee, Hyo-Hyun;Lee, Young-Ran;Kim, Ji-Eun;Kim, Siyeon;Lee, Joo-Young
    • Fashion & Textile Research Journal
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    • v.17 no.4
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    • pp.657-665
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    • 2015
  • This study evaluated the thermoregulatory properties of functional thermal underwear ('heating underwear') in markets using a thermal manikin and human wear trials. One ordinary thermal underwear (ORD) and two functional thermal underwear (HEAT1 and HEAT2; manufactured goods, HEAT1: moisture absorbing heat release mechanism, HEAT2: heat storage, release mechanism) were chosen. Thermo-physiological and subjective responses were evaluated at an air temperature of $5.0{\pm}0.5^{\circ}C$ and air humidity of $30{\pm}5%RH$ with five male subjects ($21.6{\pm}1.3yr$ in age, $178.0{\pm}5.9cm$ in height, $68.2{\pm}5.9kg$ in body mass). Experimental conditions consisted of four ensembles that included winter clothes (Control: no underwear, ORD, HEAT1, HEAT2). Water-vapor resistance was greater in fabric of HEAT1 than others. The results were: 1) Total thermal insulation (IT) using a thermal manikin were not greater for HEAT1 (0.860clo) and HEAT 2 (0.873clo) than for ORD (0.886clo). 2) There were no significant differences in rectal temperature, mean skin temperature, heart rate and total body mass loss between the four conditions. Microclimate clothing temperature on the back was greater for ORD than for HEAT1 and HEAT2. Subjects felt more comfortable with HEAT1 than for others at rest. HEAT2 was higher in microclimate humidity when compared to other conditions. The results suggest that thermoregulatory properties of 'heating underwear' in market did not differ from those of ordinary thermal underwear in terms of total thermal insulation and thermoregulatory responses in a cold environment.

Basic Analysis of Heat and Mass Transfer Characteristics of Tubular Membrane Humidifier for Proton Exchange Membrane Fuel Cell (이온교환막 연료전지용 원통형 막 가습기의 열 및 물질전달특성 기초 연구)

  • Bae, Ho-June;Ahn, Kook-Young;Lee, Young-Duk;Kang, Sang-Kyu;Yu, Sang-Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.5
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    • pp.473-480
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    • 2011
  • The proton exchange membrane (PEM) fuel cell system is critically dependent on the humidity, which should be properly maintained over the entire operating range. A membrane humidifier is used for the water management in the PEMFC because of the membrane humidifier's reliable performance and zero parasitic power loss. In the PEMFC system, the membrane humidifier is required to provide appropriate humidity for the design point of the fuel cell. Although the performance of the fuel cell depends on the performance of the humidifier, few studies have provided a systematic analysis of the humidifier. We carry out an experimental analysis of the membrane humidifier using a vapor condensation bottle. The dry air pressure, water flow temperature, and air flow rate were chosen as the operating parameters. The results show that the time constant for the dynamic response of the membrane humidifier is relatively short, but additional analysis should be carried out.