• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.430-434
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• 2018

In this study, an effective diffusion coefficient and mass transfer coefficient were investigated in microwave-assisted drying of paclitaxel for removal of residual methylene chloride. At all the temperatures (35, 45, and $55^{\circ}C$), a large amount of the residual methylene chloride was initially removed during the drying, and the drying efficiency increased when increasing the drying temperature. The effective diffusion coefficient ($1.299{\times}10^{-13}{\sim}2.571{\times}10^{-13}m^2/s$) and mass transfer coefficient ($1.625{\times}10^{-11}{\sim}4.857{\times}10^{-11}m/s$) increased with increasing drying temperature. The small Biot number (0.0100~0.0151) indicated that the process of mass transfer was externally controlled.

• Journal of Korean Society on Water Environment
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• v.30 no.2
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• pp.166-174
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• 2014

Velocity gradient, G, a measure of the average velocity gradient in the fluid has been applied for complete mixing of chemicals in mechanical mixing devices. G values were calculated by the power input transferred to fluid in turbulent and transient range. Chemical reactions occur so fast that total mass transfer time required for even distribution of the chemicals determine the overall reaction time. The total mass transfer time is composed of the time for complete mixing through the reactor and for diffusion of the chemicals into the eddy. Complete mixing time was calculated by CFD (computer fluid dynamics) and evaluated by tracer tests in 2 liter jars at different rotating speeds. Turbulent range, Reynolds number above 10,000 in regular 2 liter jars occurred at revolution speed above 100 rpm (revolution per minute), while laminar range occurred at revolution speed below 10 rpm. A typical range of rotating speed used in jar tests for water and wastewater treatment was between 10 and 300 rpm, which covered both transient and turbulent range. G values supplied from a commercial jar test apparatus showed big difference from those calculated with power number specially in turbulent range. Diffusion time through eddy decreased 1.5 power-law of rotating speed. Complete mixing time determined by pumping number decreased increases in rotating speed. Total mass transfer time, finally, decreases as rotating speed increases, and it becomes 1 sec at rotating speed of 1,000 rpm. Complete mixing times evaluated from tracer tests showed higher than those calculated by power number at higher rotating speed. Complete mixing times, however, calculated by CFD showed similar to those of experimentally evaluated ones.

• Journal of ILASS-Korea
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• v.1 no.1
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• pp.63-75
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• 1996

The purpose of this study is to investigate the break-up characteristics by taking advantage of a two-phase coaxial nozzle. Air and water are utilized as working fluids and the mass ratio air/water has been controlled to characterize the atomization, diffusion and development of mixing process. By way of a photographic technique, conventional developing structures and diffusion angles have been analyzed systematically with variations of mass ratios. The turbulent flow components of the atomized particles were measured by a two channel LDV system and the data were treated by an on-lined measurement equipment. According to the photographic results the spreading angles decreased because the axial inertia moment was relatively higher than the lateral one with respect to the increase of mass ratio. It is found the jet flow diffuses linearly in a certain limit region while the atomizing characteristics, in terms of the distributions of particle diameters did not show particular differences. It may be expected that these fundamental results can be used as reference data in studying the atomization, breakup and diffusions.

• Journal of Digital Convergence
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• v.6 no.2
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• pp.55-64
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• 2008

The Internet possesses not only features of mass media but also features of word of mouth communication. Communication channel is considered as one of most important variables in diffusion process. In this paper, we examined functionality of technology diffusion on the Internet through the use of meta tags. We have measured the coefficients of the Bass diffusion model which has been well-established in new product diffusion. This research shows that the Bass model is appropriate for describing technology diffusion on the Internet. The external influence as represented by the coefficient of innovation was found to be much smaller while the internal influence dominates in all meta tag diffusion. In meta tag diffusion, the internal influence as represented by the coefficient of imitation was increased at least twice bigger than that of consumer durables and information technology. Collecting necessary data in social sciences research can be a burden. This research shows that it can be alleviated through the use of software agents over the Internet. The research made use of software agents for collecting longitudinal data from publicly accessible archive such as Archive.org.

• Journal of Soil and Groundwater Environment
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• v.13 no.6
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• pp.40-49
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• 2008

Matrix diffusion from planar fractures was studied mathematically and through physical model experiments. Mathematical models were developed to simulate diffusion from 2D and 3D instantaneous disk sources and a 3D continuous disk source. The models were based on analytical solutions previously developed by Carslaw and Jaeger (1959). The mathematical simulations indicated that the 2D scenario produces significantly different results from the 3D scenario, the time for mass disappearance is significantly larger for continuous sources than for instantaneous sources, the normalized concentration generally decreased over time for instantaneous sources while it increased over time for continuous sources, diffusion rates decrease significantly over time and space, and the normalized mass loss from the source zone never reaches 1 for continuous sources due to the semi-infinite integral. The simulations also showed that disappearance times increase exponentially with increasing source radii and matrix porosity, and decrease with increasing aqueous-phase NAPL solubilities.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1310-1315
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• 2004

The present study deals with the unique characteristics of hydrogen jet diffusion flames, such as split flames and reignition phenomenon. The split flames are composed of a small flamelet on the nozzle rim and a lifted main flame at downstream. When mass flow rates of fuel reach a critical point, a small-sized flamelet is found to remain in the vicinity of the nozzle exit and the flame reignition subsequent to blowout of main flame occurs repeatedly. In this study, the non-luminous hydrogen jet diffusion flames are visualized by using schlieren technique in order to analyze the combustion characteristics of hydrogen jet diffusion flames with focus on the flame reignition phenomenon.

• Progress in Superconductivity and Cryogenics
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• v.9 no.3
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• pp.72-82
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• 2007

This paper relates to reducing the temperature of a cryogenic liquid by contacting it with gas bubbles, which can be characterized by diffusion-driven evaporative cooling, The characteristic of diffusion-driven evaporative cooling is thoroughly examined by theoretical. analytical and experimental methods specifically for the case of helium injection into liquid oxygen. The results reveal that if the gaseous oxygen partial pressure in helium bubbles is lower than the liquid oxygen vapor pressure, cooling occurs autonomously due to diffusion mass transfer. The method of lowering the injected helium temperature turns out to be very effective for cooling purpose.

• Bulletin of the Korean Chemical Society
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• v.17 no.3
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• pp.217-219
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• 1996

• Nuclear Engineering and Technology
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• v.5 no.2
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• pp.115-131
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• 1973

L.S. Pontryagin's maximum principle is applied to the minimum critical mass problem without any restriction on the ranges of uranium enrichment. For the analysis, two group diffusion equation is adopted for a cylindrical reactor neglecting the vertical axis consideration. The result shows that the three-zoned reactor turns out to be most optimal: the inner and outer zones with the minimum enrichment ; whereas the middle 3one with the maximum enrichment. With the given three-zoned reactor, critical condition is derived, which leads to the calculation of the determinant. By finding the roots of the determinant the numerical calculation of the minimum critical mass is carried out for the case of Kori reactor geometry changing the minimum or the maximum enrichment. It is found from many computed values that the least possible critical mass turns out to be the case of 1.2% maximum enrichment for the middle zone and 0.65% minimum enrichment for the inner and out zones.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.2
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• pp.279-285
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• 1993

It is important to understand the interrelationship between adsorption, equilibrium and mass transport in efficient design and operation of the granular activated carbon(GAC) adsorption systems. In this study, the micro-diameter-depth adsorption system(MIDDAS) technique was developed to estimate equilibrium and mass transport parameters, which were utilized to simulate adsorption and mass transport phenomena dynamically and mathematically. The homogeneous surface diffusion model(HSDM) utilizing the estimated equilibrium and mass transport parameters including the film transfer coefficients and surface diffusivities from the MIDDAS technique, successfully predicted competitive adsorption, desorption and chromatographic displacement effects. In the binary solute system of p-chlorophenol(PCP) and p-nitrophenol(PNP), PCP was displaced by PNP and the HSDM could predict successfully. While the HSDM described the desorption breakthrough curves for PCP, PNP and PTS well when complete reversible adsorption was assumed, the desorption breakthrough curves for DBS could be predicted after subsequent incorporation of the degree of irreversibility into the model simulations.