• Title/Summary/Keyword: Mass and heat transfer

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Numerical simulation of VOC decomposition in an arc plasma reactor (수치해석 기법을 이용한 아크 플라즈마 반응기의 VOCs 분해성능 평가연구)

  • Park, Mi-jeong;Jo, Young-min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.1-7
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    • 2016
  • A range of techniques have been being developed to remove the volatile organic compounds from paining processes. High temperature decomposition of harmful VOCs using arc plasma has recently been proposed, and this work analyzed the extreme hot process by computer-aided fluid dynamics prior to the reactor design. Numerical simulations utilized the conservation equations of mass and momentum. The simulation showed that the fluid flowed down along the inner surface of the centrifugal reactor by forming intensive spiral trajectories. Although the high temperature gas generated by plasma influences the bottom of the reactor, no heat transfer in radial direction appeared. The decomposition efficiency of a typical VOCs, toluene, was found to be a maximum of 67% across the reactor, which was similar to the value (approximately 70%) for the lab-scale test.

Effect of hydrothermal processing on ginseng extract

  • Ryu, Jebin;Lee, Hun Wook;Yoon, Junho;Seo, Bumjoon;Kwon, Dong Eui;Shin, Un-Moo;Choi, Kwang-joon;Lee, Youn-Woo
    • Journal of Ginseng Research
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    • v.41 no.4
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    • pp.572-577
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    • 2017
  • Background: Panax ginseng Meyer is cultivated because of its medicinal effects on the immune system, blood pressure, and cancer. Major ginsenosides in fresh ginseng are converted to minor ginsenosides by structural changes such as hydrolysis and dehydration. The transformed ginsenosides are generally more bioavailable and bioactive than the primary ginsenosides. Therefore, in this study, hydrothermal processing was applied to ginseng preparation to increase the yields of the transformed ginsenosides, such as 20(S)-Rg3, Rk1, and Rg5, and enhance antioxidant activities in an effective way. Methods: Ginseng extract was hydrothermally processed using batch reactors at $100-160^{\circ}C$ with differing reaction times. Quantitative analysis of the ginsenoside yields was performed using HPLC, and the antioxidant activity was qualitatively analyzed by evaluating 2,2'-azino-bis radical cation scavenging, 2,2-diphenyl-1-picrylhydrazyl radical scavenging, and phenolic antioxidants. Red ginseng and sun ginseng were prepared by conventional steaming as the control group. Results: Unlike steaming, the hydrothermal process was performed under homogeneous conditions. Chemical reaction, heat transfer, and mass transfer are generally more efficient in homogeneous reactions. Therefore, maximum yields for the hydrothermal process were 2.5-25 times higher than those for steaming, and the antioxidant activities showed 1.6-4-fold increases for the hydrothermal process. Moreover, the reaction time was decreased from 3 h to 15-35 min using hydrothermal processing. Conclusion: Therefore, hydrothermal processing offers significant improvements over the conventional steaming process. In particular, at temperatures over $140^{\circ}C$, high yields of the transformed ginsenosides and increased antioxidant activities were obtained in tens of minutes.

Experimental Study on Coefficient of Flow Convection (유수대류계수에 관한 실험적 연구)

  • Jeon, Sang-Eun;Kim, Kook-Han;Kim, Jin-Keun;Yang, Joo-Kyoung
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.314-322
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    • 2003
  • Pipe cooling method is widely used for reduction of hydration heat and control of cracking in mass concrete structures. However, in order to effectively apply pipe cooling systems to concrete structures, the coefficient of flow convection relating the thermal transfer between inner stream of pipe and concrete must be estimated. In this study, a device measuring the coefficient of flow convection was developed. Since a variation of thermal distribution caused by pipe cooling has a direct effect on internal forced flows, the developed testing device is based on the internal forced flow concept. Influencing factors on the coefficient of flow convection are mainly flow velocity, pipe diameter and thickness, and pipe material. Using experimental results from the developed device, the coefficient of flow convection was calculated. Finally, a general prediction model was proposed by theoretical procedures. The proposed prediction model is able to estimate the coefficient of flow convection with flow velocity and material properties of pipe. From comparison with experimental results, the coefficient of flow convection by this model was well agreed with those by experimental results.

Dynamic modeling of LD converter processes

  • Yun, Sang Yeop;Jung, Ho Chul;Lee, In-Beum;Chang, Kun Soo
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10b
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    • pp.1639-1645
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    • 1991
  • Because of the important role LD converters play in the production of high quality steel, various dynamic models have been attempted in the past by many researchers not only to understand the complex chemical reactions that take place in the converter process but also to assist the converter operation itself using computers. And yet no single dynamic model was found to be completely satisfactory because of the complexity involved with the process. The process indeed involves dynamic energy and mass balances at high temperatures accompanied by complex chemical reactions and transport phenomena in the molten state. In the present study, a mathematical model describing the dynamic behavior of LD converter process has been developed. The dynamic model describes the time behavior of the temperature and the concentrations of chemical species in the hot metal bath and slag. The analysis was greatly facilitated by dividing the entire process into three zones according to the physical boundaries and reaction mechanisms. These three zones were hot metal (zone 1), slag (zone 2) and emulsion (zone 3) zones. The removal rate of Si, C, Mn and P and the rate of Fe oxidation in the hot metal bath, and the change of composition in the slag were obtained as functions of time, operating conditions and kinetic parameters. The temperature behavior in the metal bath and the slag was also obtained by considering the heat transfer between the mixing and the slag zones and the heat generated from chemical reactions involving oxygen blowing. To identify the unknown parameters in the equations and simulate the dynamic model, Hooke and Jeeves parttern search and Runge-Kutta integration algorithm were used. By testing and fitting the model with the data obtained from the operation of POSCO #2 steelmaking plant, the dynamic model was able to predict the characteristics of the main components in the LD converter. It was possible to predict the optimum CO gas recovery by computer simulation

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Implementation of Fuzzy Controller for MFC (MFC의 퍼지제어기 구현)

  • Lee, Seok-Ki;Lee, Yun-Jung;Lee, Seung-Ha
    • Journal of the Korean Institute of Intelligent Systems
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    • v.14 no.5
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    • pp.648-654
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    • 2004
  • The Mass Flow Controller(MFC) has become crucial in semiconductor manufacturing equipments. It is an important element because the quality and the yield of a semiconductor process are decided by the accurate flow control of gas. Therefore, the demand for implementing the high speed and the highly accurate control of MFCs has been increasing. It is hard to find an article of the control algorithm applied to MFCs. But, it is known that commercially available MFCs adopt PID control algorithms. Particularly, when the system detects the flow by way of heat transfer, the MFC control problem includes the slow response and the nonlinearity. In this paper, MFC control algorithm with a superior performance to the conventional PID algorithm is discussed and the superiority is demonstrated through the experiment. A fuzzy controller was utilized in order to compensate the nonlinearity and the slow response, and the performance is compared with that of an MFC currently available in the market. The control system, in this paper, consists of a personal computer, the data acquisition board and the control algorithm carried out by LabWindows/CVI program on the PC. In addition, a method of estimating the actual flow from the sensor output with the slow response is presented. In conclusion, according to the result of the experiment, the proposed algorithm shows better accuracy and is faster than the conventional controller.

A study on the Optimization of Activated carbon Adsorbent Preparation condition and Evaluation of Application Supporting of K-Fe-Li ternary metal ions for Improving Adsorption Capacity of Hydrogen Sulfide (H2S) (황화수소(H2S) 흡착성능 증진을 위한 K-Fe-Li 3원계 금속이온물질이 담지된 활성탄 흡착제 제조조건 최적화 및 적용성 평가 연구)

  • Choi, Sung Yeol;Han, Dong hee;Kim, Sung Su
    • Clean Technology
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    • v.25 no.3
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    • pp.189-197
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    • 2019
  • In this study an optimization of the preparation conditions of activated carbon with a ternary metal ion material to treat $H_2S$, which is classified as a representative odor substance, was carried out. For a metal ion material for enhancing the adsorption performance of hydrogen sulfide, performance enhancement was confirmed by combining Li and Fe or a ternary combination (K, Li, Fe) based on KI, which is a substance promoting hydrogen sulfide adsorption performance. Also, it was determined by XRD analysis that the reaction of each active substance with $H_2S$ was because of binding. The adsorption performance increased more than 3 times with heat treatment of the adsorbent with nitrogen compared with heat treatment with air. The maximum adsorption constant ($q_m$) value of the optimum adsorbent was 97.07, which is 6 times higher than that of the existing K-based impregnated activated carbon. It was confirmed that the objective adsorption amount ($0.3g\;g^{-1}$) was secured by an equilibrium between the mass transfer rate and adsorption rate. From the results, it was confirmed that the performance improvement was noticeable even when activated carbon with a reagent grade activated carbon particle size was modified. It was confirmed that the adsorption performance exists at high relative humidity levels of 60 and 100%, and the optimized preparation can be applied to a wet process such as a scrubber downstream.

Barrier Techniques for Spinal Cord Protection from Thermal Injury in Polymethylmethacrylate Reconstruction of Vertebral Body : Experimental and Theoretical Analyses (Polymethylmethacrylate를 이용한 척추체 재건술에서 척수의 열 손상을 방지하기 위한 방어벽 기법 : 실험적 및 이론적 분석)

  • Park, Choon Keun;Ji, Chul;Hwang, Jang Hoe;Kwun, Sung Oh;Sung, Jae Hoon;Choi, Seung Jin;Lee, Sang Won;Park, Sung Chan;Cho, Kyeung Suok;Park, Chun Kun;Yuan, Hansen;Kang, Joon Ki
    • Journal of Korean Neurosurgical Society
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    • v.30 no.3
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    • pp.272-277
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    • 2001
  • Objective : Polymethylmethacrylate(PMMA) is often used to reconstruct the spine after total corpectomy, but the exothermic curing of liquid PMMA poses a risk of thermal injury to the spinal cord. The purposes of this study are to analyze the heat blocking effect of pre-polymerized PMMA sheet in the corpectomy model and to establish the minimal thickness of PMMA sheet to protect the spinal cord from the thermal injury during PMMA cementation of vertebral body. Materials & Methods : An experimental fixture was fabricated with dimensions similar to those of a T12 corpectomy defect. Sixty milliliters of liquid PMMA were poured into the fixture, and temperature recordings were obtained at the center of the curing PMMA mass and on the undersurface(representing the spinal cord surface) of a prepolymerized PMMA sheet of variable thickness(group 1 : 0mm, group 2 : 5mm, or group 3 : 8mm). Six replicates were tested for each barrier thickness group. Results : Consistent temperatures($106.8{\pm}3.9^{\circ}C$) at center of the curing PMMA mass in eighteen experiments confirmed the reproducibility of the experimental fixture. Peak temperatures on the spinal cord surface were $47.3^{\circ}C$ in group 2, and $43.3^{\circ}C$ in group 3, compared with $60.0^{\circ}C$ in group 1(p<0.00005). So pre-polymerized PMMA provided statistically significant protection from heat transfer. The difference of peak temperature between theoretical and experimental value was less than 1%, while the predicted time was within 35% of experimental values. The data from the theoretical model indicate that a 10mm barrier of PMMA should protect the spinal cord from temperatures greater than $39^{\circ}C$(the threshold for thermal injury in the spinal cord). Conclusion : These results suggest that pre-polymerized PMMA sheet of 10mm thickness may protect the spinal cord from the thermal injury during PMMA reconstruction of vertebral body.

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Numerical Study on the Performance Assessment for Defrost and De-Icing Modes (승용차의 제상 및 성에 제거 성능 평가를 위한 수치해석적 연구)

  • Kim, Yoon-Kee;Yang, Jang-Sik;Kim, Kyung-Chun;Ji, Ho-Seong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.2
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    • pp.161-168
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    • 2011
  • The heating, ventilating, air conditioning (HVAC) system is a very important part of an automotive vehicle: it controls the microclimate inside the passenger's compartment and removes the frost or mist that is produced in cold/rainy weather. In this study, the numerical analysis of the defrost duct in an HVAC system and the de-icing pattern is carried out using commercial CFX-code. The mass flow distribution and flow structure at the outlet of the defrost duct satisfied the duct design specification. For analyzing the de-icing pattern, additional grid generation of solid domain of ice and glass is pre-defined for conductive heat transfer. The flow structure near the windshield, streakline, and temperature fields clearly indicate that the de-icing capacity of the given defrost duct configuration is excellent and that it can be operated in a stable manner. In this paper, the unsteady changes in temperature, water volume fraction, and static enthalpy at four monitoring points are discussed.

Basic Studies in Improvement of Freeze Concentration -(II) The Growth Rate and the Variety in Diameters of Ice Crystals- (동결농축(凍結濃縮)의 개선(改善)을 위한 기초적연구(基礎的硏究) -II. 빙결정(氷結晶)의 성장속도(成長速度)와 입경분포(粒徑分布)-)

  • Kong, Jai-Yul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.4
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    • pp.359-364
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    • 1985
  • Being used the three kinds of aqueous solution of tobacco extracts as a new experimental material, experiment and theoretical analysis are performed. Measurements are made with a apparatus designed and constructed by the author.The average diameter of the ice crystals is 0.04-0.1cm between 0.2 and $0.6^{\circ}C$ of the subcooling temperature of the solution. The growth rate of ice crystals in direction of axies A, $V_a$ is in proportion to the subcooling temperature, viz; $v_a=0.058{\Delta}t_b,\;where\;{\Delta}t_b<0.1^{\circ}C$ The growth rate of ice crystal have to be considered not only the mass diffusion and the heat transfer of rate controlling but also the process in ice crystallization. The growth rate of ice crystal is found to be independent on the concentration of the solution and a diameter of ice crystal.

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A Reaction Kinetic for Selective Catalytic Reduction of NOx with NH3 over Manganese Oxide (NMO, MnO2, Mn2O3) at Low Temperature (망간산화물(NMO, MnO2, Mn2O3)을 이용한 저온에서의 NH3-SCR의 반응속도 연구)

  • Kim, Min Su;Hong, Sung Chang
    • Clean Technology
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    • v.24 no.4
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    • pp.307-314
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    • 2018
  • In this study, NMO (Natural Manganese Ore), $MnO_2$, and $Mn_2O_3$ catalysts were used in the selective catalytic reduction process to remove nitrogen oxides (NOx) using $NH_3$ as a reducing agent at low temperatures in the presence of oxygen. In the case of the NMO (Natural Manganese Ore), it was confirmed that the conversion of nitrogen oxides in the stability test did not change even after 100 hours at 423 K. The Kinetics experiments were carried out within the range where heat and mass transfer were not factors. From a steady-state Kinetics study, it was found that the low-temperature SCR reaction was zero order with the respect to $NH_3$ and 0.41 ~ 0.57 order with the respect to NO and 0.13 ~ 0.26 order with the respect to $O_2$. As temperature increases, the reaction order decreases as a result of $NH_3$ and oxygen concentration. It was confirmed that the reaction between the $NH_3$ dissociated and adsorbedon the catalyst surface and the gaseous nitrogen monoxide (E-R model) and the reaction with the adsorbed nitrogen monoxide (L-H model) occur.