• Title/Summary/Keyword: Mass absorption efficiency

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Chemical and Absorption Characteristics of Water-soluble Organic Carbon and Humic-like Substances in Size-segregated Particles from Biomass Burning Emissions

  • Yu, Jaemyeong;Yu, Geun-Hye;Park, Seungshik;Bae, Min-Suk
    • Asian Journal of Atmospheric Environment
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    • v.11 no.2
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    • pp.96-106
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    • 2017
  • In this study, measurements of size-segregated particulate matter (PM) emitted from the combustion of rice straw, pine needles, and sesame stem were conducted in a laboratory chamber. The collected samples were used to analyze amounts of organic and elemental carbon (OC and EC), water-soluble organic carbon (WSOC), humic-like substances (HULIS), and ionic species. The light absorption properties of size-resolved water extracts were measured using ultraviolet-visible spectroscopy. A solid-phase extraction method was first used to separate the size-resolved HULIS fraction, which was then quantified by a total organic carbon analyzer. The results show that regardless of particle cut sizes, the contributions of size-resolved HULIS ($=1.94{\times}HULIS-C$) to PM size fractions ($PM_{0.32}$, $PM_{0.55}$, $PM_{1.0}$, and $PM_{1.8}$) were similar, accounting for 25.2-27.6, 15.2-22.4 and 28.2-28.7% for rice straw, pine needle, and sesame stem smoke samples, respectively. The $PM_{1.8}$ fraction revealed WSOC/OC and HULIS-C/WSOC ratios of 0.51 and 0.60, 0.44 and 0.40, and 0.50 and 0.60 for the rice straw, pine needle, and sesame stem burning emissions, respectively. Strong absorption with decreasing wavelength was found by the water extracts from size-resolved biomass burning aerosols. The absorption ${\AA}ngstr{\ddot{o}}m $ exponent values of the size-resolved water extracts fitted between 300 and 400 nm wavelengths for particle sizes of $0.32-1.0{\mu}m$ were 6.6-7.7 for the rice straw burning samples, and 7.5-8.0 for the sesame stem burning samples. The average mass absorption efficiencies of size-resolved WSOC and HULIS-C at 365 nm were 1.09 (range: 0.89-1.61) and 1.82 (range: 1.33-2.06) $m^2/g{\cdot}C$ for rice straw smoke aerosols, and 1.13 (range: 0.85-1.52) and 1.83 (range: 1.44-2.05) $m^2/g{\cdot}C$ for sesame stem smoke aerosols, respectively. The light absorption of size-resolved water extracts measured at 365 nm showed strong correlations with WSOC and HULIS-C concentrations ($R^2=0.89-0.93$), indicating significant contribution of HULIS component from biomass burning emissions to the light absorption of ambient aerosols.

Temperature-dependent Electrical Characteristics of Traveling Wave Electro-absorption Modulator (온도 변화에 따른 진행파 전극형 광 변조기의 전기적 특성 변위에 관한 연구)

  • Rhew, Keun-Ho;Yun, Il-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.63-64
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    • 2006
  • Recently, researches for high-speed optical devices have been increased to provide mass data transmission and high-speed optical communication. Optical modulator in the transmission link is one of the crucial devices in total optical network system and it can affect a great effect to the whole transmission properties. In this paper, traveling wave electro-absorption modulator (TWEAM) is examined to ensure high efficiency in the RF range and wide bandwidth. In addition, the temperature-dependence electrical characteristics of TWEAM is investigated. Temperature dependent property variations were characterized using I-V and C-V measurement.

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Analysis of Falling-film Generator in Ammonia-water Absorption System (암모니아-물 흡수식 시스템에서 유하액막식 발생기의 해석)

  • 김병주;손병후;구기갑
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.5
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    • pp.422-430
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    • 2001
  • In the present study, an evaporative generation process of ammonia-water solution film on the vertical plate was analysed. For the utilization of waste heat, hot water of low temperature was used as the heat source. The continuity, momentum, energy and diffusion equations for the solution film and vapor mixture were formulated in integral forms and solved numerically. Counter-current solution-vapor flow resulted in the refrigerant vapor of the higher ammonia concentration than that of co-current flow. Eve the rectification of refrigerant vapor was observed near the inlet of solution film in counter-current flow. For the optimum operation of generator using hot water, numerical experiments, based on the heat exchange and generation efficiencies. revealed the inter-relationships among the Reynolds number of the solution film and hot water, and the length of generator. Enhancement of heat and mass transport in the solution film was found to be very effective for the improvement of generation performance, especially at high solution flow rate.

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The effect of dry matter allocation at the early seedling stare on the growth of two grass species (두 초본 종의 생장에 있어서 실생 초기의 물질분해 효과)

  • Park, Young-Mok
    • The Korean Journal of Ecology
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    • v.15 no.3
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    • pp.297-309
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    • 1992
  • The growth of digitaria adscendens and eleusine indica, annual weeds common in japan, was experimentally analyzed under varying untrient conditions. compared with e. indica, d. adscendensshowed a higher the two under high nitrogen availability. Higher net assimilation rate(nar) in d. adscendens than e. india was responsible for high RGR in D. adscendens under the low nitrogen availability. The different of NAR in the two species was induced not by leaf nitrogen content but by nitrogen use efficiency. Under unfertilized conditions nitrogen uptake rate(nur) was greater in d. adscendens than e. indica. Specific absorption rate in two species was similar, but root mass was greater in d. adscendens than e. indica.d. adscendens allocated more dry matter to roots than e. india earlier stage of seedlings. The contributed to higher rot mass and in turn resulted in higher nur in d. adscendens than that in e. india. It is concluuded that the larger allocation of dry matter to roots at early seedling stage in d. adscendens plays an important role in obtaining nitrogen for the continuation of growth under low nitrogen availability.

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Numerical Simulation of Transport Phenomena for Laser Full Penetration Welding

  • Zhao, Hongbo;Qi, Huan
    • Journal of Welding and Joining
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    • v.35 no.2
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    • pp.13-22
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    • 2017
  • In laser full penetration welding process, full penetration hole(FPH) is formed as a result of force balance between the vapor pressure and the surface tension of the surrounding molten metal. In this work, a three-dimensional numerical model based on a conserved-mass level-set method is developed to simulate the transport phenomena during laser full penetration welding process, including full penetration keyhole dynamics. Ray trancing model is applied to simulate multi-reflection phenomena in the keyhole wall. The ghost fluid method and continuum method are used to deal with liquid/vapor interface and solid/liquid interface. The effects of processing parameters including laser power and scanning speed on the resultant full penetration hole diameter, laser energy distribution and energy absorption efficiency are studied. The model is validated against experimental results. The diameter of full penetration hole calculated by the simulation model agrees well with the coaxial images captured during laser welding of thin stainless steel plates. Numerical simulation results show that increase of laser power and decrease of welding speed can enlarge the full penetration hole, which decreases laser energy efficiency.

Preparation of PVDF Hollow Fiber Membrane and Absorption of SO2 from Flue Gas Using Bench Scale Gas-Liquid Contactor (PVDF 중공사막 제조 및 벤치규모 기-액 접촉기를 이용한 SO2 흡수특성)

  • Park, Hyun-Hee;Jo, Hang-Dae;Kim, In-Won;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.521-528
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    • 2008
  • The micro-porous asymmetric PVDF hollow fiber membranes for gas-liquid contactor were prepared by the dry-jet wet phase inversion process and the characteristics of hollow fiber membranes were evaluated by the gas permeation method and scanning electron microscope. The chemical absorbent for removal of $SO_2$ gas was sodium hydroxide at bench scale hollow fiber membrane contactor. The experiments were performed in a counter-current mode of operation with gas in the shell side and liquid in the fiber lumen of the module to examine the effect of various operating variables such as concentration of absorbent, gas flow rate, L/G ratio and concentration of inlet $SO_2$ gas on the $SO_2$ removal efficiency using PVDF hollow fiber membrane contactor. Membrane mass transfer coefficient($k_m$) was calculated by mathematical modeling. The volumetric overall mass transfer coefficient increased with increasing the concentration of absorbent and L/G ratio. The increase of the absorbent concentration and L/G ratio not only provides more sufficient alkalinity but also decreases liquid phase resistance. The volumetric overall mass transfer coefficient increased with increasing gas flow rate due to decreasing the gas phase resistance.

STARBURST AND AGN CONNECTIONS AND MODELS

  • SCOVILLE NICK
    • Journal of The Korean Astronomical Society
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    • v.36 no.3
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    • pp.167-175
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    • 2003
  • There is accumulating evidence for a strong link between nuclear starbursts and AGN. Molecular gas in the central regions of galaxies plays a critical role in fueling nuclear starburst activity and feeding central AGN. The dense molecular ISM is accreted to the nuclear regions by stellar bars and galactic interactions. Here we describe recent observational results for the OB star forming regions in M51 and the nuclear star burst in Arp 220 - both of which have approximately the same rate of star formation per unit mass of ISM. We suggest that the maximum efficiency for forming young stars is an Eddington-like limit imposed by the radiation pressure of newly formed stars acting on the interstellar dust. This limit corresponds to approximately 500 $L_{\bigodot} / M_{\bigodot}$ for optically thick regions in which the radiation has been degraded to the NIR. Interestingly, we note that some of the same considerations can be important in AGN where the source of fuel is provided by stellar evolution mass-loss or ISM accretion. Most of the stellar mass-loss occurs from evolving red giant stars and whether their mass-loss can be accreted to a central AGN or not depends on the radiative opacity of the mass-loss material. The latter depends on whether the dust survives or is sublimated (due to radiative heating). This, in turn, is determined by the AGN luminosity and the distance of the mass-loss stars from the AGN. Several AGN phenomena such as the broad emission and absorption lines may arise in this stellar mass-loss material. The same radiation pressure limit to the accretion may arise if the AGN fuel is from the ISM since the ISM dust-to-gas ratio is the same as that of stellar mass-loss.

Comparative Study of Mass Transfer and Bubble Hydrodynamic Parameters in Bubble Column Reactor: Physical Configurations and Operating Conditions

  • Sastaravet, Prajak;Chuenchaem, Chomthisa;Thaphet, Nawaporn;Chawaloesphonsiya, Nattawin;Painmanakul, Pisut
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.345-354
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    • 2014
  • In this paper, effects of physical configurations and operating conditions on bubble column performance were analyzed in terms of bubble hydrodynamic and mass transfer parameters. Bubble column with 3 different dimensions and 7 gas diffusers (single / multiple orifice and rigid / flexible orifice) were applied. High speed camera and image analysis program were used for analyzing the bubble hydrodynamic parameters. The local liquid-side mass transfer coefficient ($k_L$) was estimated from the volumetric mass transfer coefficient ($k_La$) and the interfacial area (a), which was deduced from the bubble diameter ($D_B$) and the terminal bubble rising velocity ($U_B$). The result showed that the values of kLa and a increased with the superficial gas velocity (Vg) and the size of bubble column. Influences of gas diffuser physical property (orifice size, thickness and orifice number) can be proven on the generated bubble size and the mass transfer performance in bubble column. Concerning the variation of $k_L$ coefficients with bubble size, 3 zones (Zone A, B and C) can be observed. For Zone A and Zone C, a good agreement between the experimental and the predicted $K_L$ coefficients was obtained (average difference of ${\pm}15%$), whereas the inaccuracy result (of ${\pm}40%$) was found in Zone B. To enhance the high $k_La$ coefficient and absorption efficiency in bubble column, it was unnecessary to generate numerous fine bubbles at high superficial gas velocity since it causes high power consumption with the great decrease of $k_L$ coefficients.

Hydrogen Absorption by Crystalline Semiconductors: Si(100), (110) and (111)

  • Jeong, Min-Bok;Jo, Sam-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.383-383
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    • 2010
  • Gas-phase hydrogen atoms create a variety of chemical and physical phenomena on Si surfaces: adsorption, abstraction of pre-adsorbed H, Si etching, Si amorphization, and penetration into the bulk lattice. Thermal desorption/evolution analyses exhibited three distinct peaks, including one from the crystalline bulk. It was previously found that thermal-energy gaseous H(g) atoms penetrate into the Si(100) crystalline bulk within a narrow substrate temperature window(centered at ~460K) and remain trapped in the bulk lattice before evolving out at a temperature as high as ~900K. Developing and sustaining atomic-scale surface roughness, by H-induced silicon etching, is a prerequisite for H absorption and determines the $T_s$ windows. Issues on the H(g) absorption to be further clarified are: (1) the role of the detailed atomic surface structure, together with other experimental conditions, (2) the particular physical lattice sites occupied by, and (3) the chemical nature of, absorbed H(g) atoms. This work has investigated and compared the thermal H(g) atom absorptivity of Si(100), Si(111) and Si(110) samples in detail by using the temperature programmed desorption mass spectrometry (TPD-MS). Due to the differences in the atomic structures of, and in the facility of creating atom-scale etch pits on, Si(100), (100) and (110) surfaces, the H-absorption efficiency was found to be larger in the order of Si(100) > Si(111) > Si(110) with a relative ratio of 1 : 0.22 : 0.045. This intriguing result was interpreted in terms of the atomic-scale surface roughening and kinetic competition among H(g) adsorption, H(a)-by-H(g) abstraction, $SiH_3(a)$-by-H(g) etching, and H(g) penetraion into the crystalline silicon bulk.

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Polybenzimidazole (PBI) Coated CFRP Composite as a Front Bumper Shield for Hypervelocity Impact Resistance in Low Earth Orbit (LEO) Environment

  • Kumar, Sarath Kumar Sathish;Ankem, Venkat Akhil;Kim, YunHo;Choi, Chunghyeon;Kim, Chun-Gon
    • Composites Research
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    • v.31 no.3
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    • pp.83-87
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    • 2018
  • An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.