• Title/Summary/Keyword: Mass Transport Mechanism

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LARGE EDDY SIMULATION OF FLOW AND MASS EXCHANGE PROCESSES BETWEEN A CHANNEL AND AN OPEN CAVITY (LES를 이용한 열린 공동 유동과 공동 내 물질 확산의 수치적 모사)

  • Chang K.S.;Park S.O.;Constantinescu G.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.239-243
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    • 2005
  • Fully three-dimensional Large Eddy Simulation calculations of the flow past 2D cavity are conducted to study the purging of neutrally buoyant or dense miscible contaminants introduced instantaneously inside the cavity. The length to depth ratio(L/D) is 2 and Reynolds number based on the depth is 3,360. Fully developed turbulent inflow are fed at the inlet from precursor simulation of channel flow. Mean flow pattern and unsteady features are investigated based on the experimental data of Pereira and Sousa. From the study of mass exchange processes, it is found that the mechanism of removal of the contaminant is very different between the non-buoyant and buoyant cases. In the buoyant case, internal wave motion which interacts with a strong cavity vortex is dominant in the ejection mechanism of the contaminants.

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Numerical Assessment for Coastal Water Purification Utilizing a Tidal Jet System (조석분류를 이용한 연안해역의 수질정화에 관한 수치적 평가)

  • Park, Jong-Chun
    • Journal of Ocean Engineering and Technology
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    • v.20 no.4 s.71
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    • pp.58-63
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    • 2006
  • When the costal zone surrounded by a breakwater has a narrow vertical opening, currents in the vicinity of a narrow entrance can result in a jet flow, coinciding with the tide. Such a Tidal-Jet Generator(TJG) can change the water mass distribution and transport processes in the domain of influence of the jet. Also, it can decrease the residual time of them. In the present study, the water purification utilizing tidal jets in the coastal zone over constant bathymetry are estimated numerically, using a finite-difference numerical scheme, named the NS-MAC-TIDE method, which isbased on the fully 3D Navier-stokes(NS) equations. The shear velocity near the inlet of the TJG are predicted from the flow field simulation, and are assessed qualitatively with the development of scouring or sediment that is caused by the change of diffusion or sweeping flowup from the seabed of sediment particles. Finally, through solving a transport equation of concentration, the residual time related on mass transport processes and the flushing mechanism for water purification are investigated.

Modeling As(III) and As(V) adsorption and transport from water by a sand coated with iron-oxide colloids

  • Ko, Il-Won;Lee, Cheol-Hyo;Kim, Kyoung-Woong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.243-247
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    • 2004
  • Tile development of a porous iron-oxide coated sand filter system can be modelled with the analytical solution of tile transport equation in order to obtain the operating parameters and investigate the mechanism of arsenic removal. The adsorbed amount from the model simulation showed the limitation of adsorption removal during arsenic transport. A loss reaction term in the transport equation plays a role in the mass loss in column conditions, and then resulted into the better model fitting, particularly, for arsenate. Further, the competitive oxyanions delayed the breakthrough near MCL (10 $\mu$g/L) due to the competitive adsorption. This is the reason why arsenate can be strongly attracted in tile interface of an iron-oxide coated sand, and competing oxyanions can occupy the adsorption sites. Therefore, arsenic retention was regulated by non-equilibrium of arsenic adsorption in a porous iron-oxide coated sand media. The transport-limited process seemed to be affect the arsenic adsorption by coated sand.

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Unsteady Flow in a Cavity Induced by An Oscillatory External Flow (외부유동에 의한 캐버티 내의 비정상 유동특성)

  • 서용권;박준관;문종춘
    • Journal of Ocean Engineering and Technology
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    • v.10 no.3
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    • pp.105-116
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    • 1996
  • In this paper, we report the experimental results for the flow pattern and the material transport around a cavity subject to a sinusoidal external flow at the far region to ward the open side of the cavity. A tilting mechanism is used to generate a oscillatory flow inside a shallow rectangular container having a cavity at one side. The surface flow visualization is performed to obtain the unsteady behavior of vortices generated at two edges situated at the entrance of the cavity. It was found that at the period 4.5 sec., the behavior of the vortices is asymmetric, and there exists a steady residual flow in the cavity. The bottom flow patterns are also visualized. There are two regions outside of the cavity where the bottom fluid particles concentrate. The material transport in this flow model is very peculiar; fluid particles in the cavity flows outward through the passage along the walls starting from the edges, and particles in the outer region approach the cavity from the central region.

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A Study on the Modeling of Pt-Catalyzed Reaction and the Characteristics of Mass Transfer in a Micro-Scale Combustor (마이크로 스케일 연소기의 백금 촉매 반응 모델링과 물질 전달 특성에 대한 연구)

  • Lee, Gwang-Goo;Suzuki, Yuji
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.11
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    • pp.870-877
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    • 2008
  • Numerical analysis is applied to model Pt-catalyzed reaction in a micro-scale combustor fueled by butane. The reaction constants of catalytic oxidation are determined from plug flow model with the experimental data. Orders of magnitude between the chemical reaction rate and the mass transfer rate are carefully compared to reveal which mechanism plays a dominant role in the total fuel conversion rate. For various conditions of fuel flow rate and surface temperature, the profiles of Sherwood number are investigated to study the characteristics of the mass transport phenomena in the micro-tube combustor.

Interpretation of Permeation Characteristics and Membrane Transport Models Through Polyamide Reverse Osmosis Membrane (Polyamide 역삼투막의 투과성능과 막 이동 모델의 해석)

  • 김노원;김영길;이용택
    • Membrane Journal
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    • v.14 no.1
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    • pp.75-84
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    • 2004
  • In this study, we present a noble study far membrane transport models using chlorine resistance of polyamide RO membranes. Membrane transport mechanism is investigated by the comparison of membrane permeation performance under the continuous and Intermittent operation modes with mixed feed solution containing NaOCl and NaCl. Analysis of permeation performance indicates that solution-diffusion model and preferential adsorption-capillary flow model are relatively efficient according to operation mode. Under the continuous flow state, mass transfer depends on preferential adsorption-capillary flow model rather than solution-diffusion model. On the other hand, it prefers solution-diffusion model to preferential adsorption-capillary flow model under the stationary state. SEM images of NaOCl treated membrane surfaces strongly support these conclusions. These surface images reveal that NaOCl treated membrane in continuous operation mode exhibits ridge and valley structure in some fraction of the surface area, whereas that in intermittent operation mode shows surface degradation entirely.

Sediment Erosion and Transport Experiments in Laboratory using Artificial Rainfall Simulator

  • Regmi, Ram Krishna;Jung, Kwansue;Nakagawa, Hajime;Kang, Jaewon;Lee, Giha
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.4
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    • pp.13-27
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    • 2014
  • Catchments soil erosion, one of the most serious problems in the mountainous environment of the world, consists of a complex phenomenon involving the detachment of individual soil particles from the soil mass and their transport, storage and overland flow of rainfall, and infiltration. Sediment size distribution during erosion processes appear to depend on many factors such as rainfall characteristics, vegetation cover, hydraulic flow, soil properties and slope. This study involved laboratory flume experiments carried out under simulated rainfall in a 3.0 m long ${\times}$ 0.8 m wide ${\times}$ 0.7 m deep flume, set at $17^{\circ}$ slope. Five experimental cases, consisting of twelve experiments using three different sediments with two different rainfall conditions, are reported. The experiments consisted of detailed observations of particle size distribution of the out-flow sediment. Sediment water mixture out-flow hydrograph and sediment mass out-flow rate over time, moisture profiles at different points within the soil domain, and seepage outflow were also reported. Moisture profiles, seepage outflow, and movement of overland flow were clearly found to be controlled by water retention function and hydraulic function of the soil. The difference of grain size distribution of original soil bed and the out-flow sediment was found to be insignificant in the cases of uniform sediment used experiments. However, in the cases of non-uniform sediment used experiments the outflow sediment was found to be coarser than the original soil domain. The results indicated that the sediment transport mechanism is the combination of particle segregation, suspension/saltation and rolling along the travel distance.

Simulated Experiments on High Pressure Melt Ejection in the Reactor Cavity During Severe Accident (원자로 가상사고시(노심) 용융물 고압 분출 모의 실험 연구)

  • Jeong, Han-Won;Kim, Do-Hyeong;Lee, Gyu-Jeong;Kim, Sang-Baek;Park, Rae-Jun;Kim, Hui-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.11
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    • pp.1447-1456
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    • 2000
  • Simulated experiments of high pressure melt ejection(HPME) are performed to measure the released fraction of corium simulant from the French type PWR cavity. The experiments are carried out on a 1/20th linear scaled model of the Ulchin 1&2 cavity. Water or woods metal and nitrogen is used as simulant of molten corium and steam, respectively. Experimental parameters are water mass, annulus area and breach size. It is shown that only breach size effects is very important while the mass and the annulus area do not affect the released fraction. It is found that the liquid film transport is much more dominant mechanism than the entrainment droplet transport, especially in linear scale down simulated HPME experiment.

Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode with Different Dopants (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기화학적 특성)

  • 김현철;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.141-146
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    • 2002
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte, KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior, was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the oxidation potential of the PPy was about -02 V vs Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. The falloff of the oxidation potential gave a sign of an improvement in the electron hopoing mechanism on the backbone. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS improved in mass transport or diffusion. That was because the PPy doped with p-TS was more porous than PPy with KCl. We attained an effect of good kinetic parameters, in the case of PP-GOx enzyme electrodes doped with p-TS, which were determined by 58 mmol dm$\^$-3/ for apparent Michaelis constant and by 581 ㎂ for maximum current respectively.

A Study on the Low Temperature Growth of SiC Film with a 1,3-DSB Precursor (단일전구체(1,3-DSB)에 의한 저온 SiC박막 성장에 관한 연구)

  • 양재웅;노대호;윤진국;김재수
    • Journal of the Korean institute of surface engineering
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    • v.36 no.2
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    • pp.141-147
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    • 2003
  • Silicon carbide thin film was deposited in APCVD and LPCVD system with 1,3-DSB precursor 1,3-DSB is the single precursor to deposit SiC on Si at low temperature. SiC film was deposited at $850^{\circ}C$ lower than ordinary temperature ($1000~1200^{\circ}C$) in CVD process. SiC thin film glowed to high oriented (111) plane in APCVD system. In LPCVD system, SiC film groved to preferred (220) plane at same temperature. This discrepancy between preferred planes can be described by the difference of deposition mechanism. Amorphous phase and crystal defect were observed in APCVD system with the main growth mechanism of mass transport limited region. But in LPCVD system, we got the SIC film of uniform, faceted structure and high quality.