• Korea-Australia Rheology Journal
• /
• v.16 no.1
• /
• pp.35-45
• /
• 2004

Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.4
• /
• pp.318-323
• /
• 2004

When a strong electric field is applied between a sharply curved electrode and a blunt surface, the corona may result in a gas movement in the electrode gap which is directed toward the blunt surface. That is called the corona wind. It enhances heat and mass transfer between the surface and the surrounding gas. Moreover such enhancement causes no noise or vibration, which can be applied in complex, isolated geometries, and allows simple control of surface temperatures. This paper examines the relationship between the corona wind and the relative humidity. The facility consists of high voltage power supply thin tungsten wire, plate electrode, multimeter, microammeter and flow meter. Gas velocity is a linear function of voltage, relative humidity and is proportional to the square root of the current. The maximum velocities for the positive and negative corona discharge are 1.9 m/s (2.74 CMM/m), 1.5 m/s(2.15 CMM/m), respectively.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2003.05a
• /
• pp.351-357
• /
• 2003

In absorption system, the performance of the absorber is critical the overall system performance, size, and first-cost. The objective of this paper is to provide a comprehensive review of the significant effects that researchers have made to numerically analysis model the coupled heat and mass transfer process that occur during falling-film absorption and experimental researches. This study includes experimental work in the enhancement of absorption performance, the effect of the geometry of a vertical absorber, and the effect of configuration of absorption system. This paper is used to highlight key areas which need attention such as film ans vapor hydrodynamics, especially the non-periodicity, instability, and recirculatory motion of waves in the vertical absorber case.

• Proceedings of the SAREK Conference
• /
• 2005.11a
• /
• pp.335-340
• /
• 2005

Nonlinear and forced oscillations of supported viscous droplet were focused in the present study. The droplet has a free contact line with solid plate and inviscid fluid. Natural frequencies of a pendant droplet have been investigated experimentally by imposing the acoustic wave while the frequency is being increased at a fixed amplitude. The evaporation was observed at atmosphere pressure. The droplet was recorded throughout the entire evaporation process and transient variations of the volume was measured. The evaporation process of oscillating droplet with thermofoil has been also observed to investigate analyzing the resonance effect on the thermal characteristics of droplet. It is found that a pendant droplet shows the resonant behaviors at each mode similar to the theoretical analysis. During imposing the acoustic wave, the pendant droplet makes a rotating motion in its longitudinal axis which is a new shape oscillation mode. The evaporation rate of a pendant droplet at resonant frequency is significantly enhanced.

• International Journal of Air-Conditioning and Refrigeration
• /
• v.13 no.3
• /
• pp.158-166
• /
• 2005

The present study investigated experimentally and numerically the enhancement of absorption performance due to the waviness of falling film in the vertical absorber tube. The momentum, energy and mass diffusion equations were utilized to find out temperature and concentration profiles at both the interfaces of liquid solution and refrigerant vapor and the wall. Flow visualization was performed to find out the wetting characteristics of the falling film. The maximum heat transfer coefficient was obtained for the wavy flow using spring as an insert device through both numerical and experimental studies. Based on the numerical and experimental results, the maximum absorption rate was found for the wavy-flow using spring as the insert device. The differences between experimental and analytical results ranged from $5.0\;to\;25\%\;when\;Re_j>100$.

• Korea-Australia Rheology Journal
• /
• v.17 no.4
• /
• pp.199-205
• /
• 2005

Carbon dioxide was absorbed into aqueous polyethylene oxide (PEO) solution containing AMP in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior of PEO on the rate of chemical absorption of $CO_2$, where the reaction between $CO_2$ and AMP was assumed to be a first-order reaction with respect to the molar concentration of $CO_2$ and AMP respectively. The liquid-side mass transfer coefficient, which was obtained from the dimensionless empirical equation containing the properties of viscoelasticity of the non-Newtonian liquid, was used to estimate the enhancement factor due to chemical reaction. PEO with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid based on the same viscosity of the solution.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 1999.05a
• /
• pp.185-191
• /
• 1999

An air-conditioning system based on the chemical heat storage principle was considered. $H_2O$ was chosen as the reaction gas and the working fluid as well. Na$_2$S, CaCl$_2$, MnCl$_2$, BaCl$_2$, MgCl$_2$, Fe$_2$(SO$_4$)$_3$ and MnSO$_4$ were tested as the solid reactants by using Cahn pressure balance. Na$_2$S was superior to other salts in respect of high capability of absorption of water gas, 5 moles of $H_2O$ per unit mole of Na$_2$S, and adequate temperature of adsorption, $65^{\circ}C$ at 7torr, and of desorption, 13$0^{\circ}C$ at 76torr. Clausius-Clapeyron diagram of Na$_2$S was obtained via adsorption experiments at several vapor pressures of water gas. To enhance heat and mass transfer characteristics, usually below 1W/m K, of the reactor bed of general adsorption systems, expanded graphite block was adapted as the support of Na$_2$S salt. Expanded graphite blocks had thermal conductivity values of 20~80W/mK with respect to 100~400kg/㎥ of block bulk density. Permeability values of expanded graphite blocks were 10$^{-13}$ ~ 10$^{-14}$ $m^2$ with respect to 100~300kg/㎥ of block bulk density showing highly decreasing values of permeability, below 10$^{-l4}$$m^2$, in the range of above 150kg/㎥ of block bulk density.y.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.12
• /
• pp.1234-1268
• /
• 2004

A review on the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering in 2002 and 2003 has been carried out. Focus has been put on current status of research in the aspect of heating, cooling, air-conditioning, ventilation, sanitation and building environment/design. The conclusions are as follows. (1) Most of fundamental studies on fluid flow were related with heat transportation in diverse facilities. Drop formation and rivulet flow on solid surfaces were interesting topics related with condensation augmentation. Research on micro environment considering flow, heat transfer, humidity was also interesting to promote comfortable living environment. It can be extended considering biological aspects. Development of fans and blowers of high performance and low noise were continuing research topics. Well developed CFD technologies were widely applied for analysis and design of various facilities and their systems. (2) Heat transfer characteristics of enhanced finned tube heat exchangers and heat sinks were extensively investigated. Experimental studies on the boiling heat transfer, vortex generators, fluidized bed heat exchangers, and frosting and defrosting characteristics were also conducted. In addition, the numerical simulations on various heat exchangers were performed and reported to show heat transfer characteristics and performance of the heat exchanger. (3) A review of the recent studies shows that the performance analysis of heat pump have been made by various simulations and experiments. Progresses have been made specifically on the multi-type heat pump systems and other heat pump systems in which exhaust energy is utilized. The performance characteristics of heat pipe have been studied numerically and experimentally, which proves the validity of the developed simulation programs. The effect of various factors on the heat pipe performance has also been examined. Studies of the ice storage system have been focused on the operational characteristics of the system and on the basics of thermal storage materials. Researches into the phase change have been carried out steadily. Several papers deal with the cycle analysis of a few thermodynamic systems which are very useful in the field of air-conditioning and refrigeration. (4) Recent studies on refrigeration and air-conditioning systems have focused on the system performance and efficiency enhancement when new alternative refrigerants are applied. Heat transfer characteristics during evaporation and condensation are investigated for several tube shapes and new alternative refrigerants including natural refrigerants. Efficiency of various compressors and performance of new expansion devices are also dealt with for better design of refrigeration/air conditioning system. In addition to the studies related with thermophysical properties of refrigerant mixtures, studies on new refrigerants are also carried out. It should be noted that the researches on two-phase flow are constantly carried out. (5) A review of the recent studies on absorption refrigeration system indicates that heat and mass transfer enhancement is the key factor in improving the system performance. Various experiments have been carried out and diverse simulation models have been presented. Study on the small scale absorption refrigeration system draws a new attention. Cooling tower was also the research object in the respect of enhancement its efficiency, and performance analysis and optimization was carried out. (6) Based on a review of recent studies on indoor thermal environment and building service systems, it is noticed that research issues have mainly focused on several innovative systems such as personal environmental modules, air-barrier type perimeterless system with UFAC, radiant floor cooling system, etc. New approaches are highlighted for improving indoor environmental conditions and minimizing energy consumption, various activities of building energy management and cost-benefit analysis for economic evaluation.

• KSBB Journal
• /
• v.9 no.2
• /
• pp.211-223
• /
• 1994

In fermentations with a 4-liter stirred tank bioreactor, a better than two-fold enhancement of the gas-liquid mass transfer coefficient$(k_La)$ in the celite-immobilized fungal cultures of Tolypocladium in flatum over the parallel conventional free-cell was observed at identical biomass concentrations, despite the higher specific oxygen uptake rate of the immobilized fungi during exponential growth. As a result oxygen sufficient conditions, i. e., dissolve oxygen(D.O.) concentrations exceeding 75% air saturation, could be maintained throughout exponential growth period of the immobilized culture, in contrast to the suspended fungal culture, whose D.O. levels fell below 50% air saturation. A linear monotonic dependence of $k_La$ upon impeller agitaion rate was found for both immobilized and conventional cultivation modes over a range of 250 to 550rpm, the slope being a function of biomass concentration for the free but not for the immobilized cell system In contrasts oxygen transfer rate was a much weaker function of aeration rate up to about 2.5 vvm for both culture configurations. Above this level, aeration rate had no further effect on the mass transfer. In addition, the immobilized cultures sustained good morphological and physiological states, leading to almost two times higher cyclosporln A (CyA) productivity overt the parallel free cell system. These experiments suggest that the celite-immobilized fungal system in a stirred tank reactor has considerable promise for scaling up cyclosporin A production in terms of high-density cultivation.

• International Journal of Air-Conditioning and Refrigeration
• /
• v.13 no.2
• /
• pp.99-106
• /
• 2005

Falling film heat transfer has been widely used in many applications in which heat and mass transfer occur simultaneously, such as evaporative coolers, cooling towers, absorption chillers, etc. In such cases, it is desirable that the falling film spreads widely on the surface to form a thin liquid film to enlarge contact surface and to reduce the thermal resistance across the film and/or the flow resistance to the vapor stream over the film. In this respect, hydrophilic treatment of the surface has been tried to improve the surface wettability by decreasing the contact angle between the liquid and the surface. However, the hydrophilic treatment was found not very effective to increase the surface wettedness of inclined surfaces, since the liquid flow forms rivulet patterns instead of a thin film as it flows down the inclined surface and accelerates gradually by the gravity. In this work, a novel method is suggested to improve the surface wettedness enormously. In this work, the surface is treated to have a thin hydrophilic porous layer on the surface. With this treatment, the liquid can spread widely on the surface by the capillary force resulting from the porous structure. In addition to this, the liquid can be held within the porous structure to improve surface wettedness regardless of the surface inclination. The experiment on the evaporative cooling of inclined surfaces has been conducted to verify the effectiveness of the surface treatment. It is measured that the latent heat transfer increases almost by $80\%$ at the hydrophilic porous layer coated surface as compared with the untreated surface.