• Environmental Engineering Research
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• 제20권2호
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• pp.191-197
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• 2015

The first objective of this study was to discuss the applicability of the $CO_2/CH_4$ ratio method in order to assess $CH_4$ oxidation efficiency. To achieve this objective, a comparison between $CO_2/CH_4$ ratios and the mass balance method was conducted. The second objective of this study was to estimate the $CH_4$ oxidation efficiency in an interim landfill soil cover and assess how a $CH_4$ influx influences the $CH_4$ oxidation efficiency. The results showed that despite the $CO_2$ problems brought by respiration, the $CH_4$ oxidation efficiencies obtained by the $CO_2/CH_4$ ratio method led to similar results compared to the mass balance method. In this respect, the $CO_2/CH_4$ ratio method can be an indicator of the $CH_4$ oxidation efficiencies for landfill cover soils. The $CH_4$ oxidation efficiencies derived in this study through the $CO_2/CH_4$ ratio method ranged between 46% and 64%, and between 41% and 62% through the mass balance method. The results imply that the Intergovernmental Panel on Climate Change's (IPCC) default value of 10% for the $CH_4$ oxidation efficiency is an underestimation for landfill cover soils. $CH_4$ oxidation efficiency tends to be negatively correlated with $CH_4$ influx. Therefore, $CH_4$ influx reaching a landfill cover should be limited in order to increase the $CH_4$ oxidation efficiency.

• 분석과학
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• 제30권5호
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• pp.226-233
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• 2017

In general, quantitative chemical analysis in various areas including food, the environment, in vitro diagnostics, etc., requires traceability in order to increase the reliability of the measurements. Measurement traceability is a property of an unbroken chain of comparisons relating an instrument's measurements to SI units. Purity analysis is the first process for establishing traceability to SI units in chemical measurements. The purpose of this study is to develop and validate a method of purity assignment for establishing the traceability of $17{\beta}$-estradiol measurements in an in vitro diagnostics field. The establishment of this method is very important as it can be applied to the development of CRM and to the analysis of the purity of other hormones. The method of assignment of the purity of $17{\beta}$-estradiol was developed using the mass balance method and was validated through participation in an International comparison. In the mass balance method, impurities are categorized into four classes as follows: total related structure impurities, water, residual organic solvents, and nonvolatiles/inorganics. In this study, total related structure impurities were characterized by a gas chromatography-flame ionization detector (GC-FID) and a high-performance liquid chromatography-ultraviolet (HPLC-UV) detector, water content was determined by a Karl-Fisher coulometer, and total residual solvents and nonvolatiles/inorganics were checked simultaneously by thermogravimetric analysis (TGA). The purity of the $17{\beta}$-estradiol was 985.6 mg/g and the expanded uncertainty was 2.1 mg/g at 95% confidence. The developed method can be applied to the development of certified reference materials, which play a critical role in traceability.

• 해양환경안전학회지
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• 제24권5호
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• pp.545-552
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• 2018

본 연구에서는 갈대군락의 영양염 물질수지 모델 구축을 위한 기초연구로서, 갈대군락 Mesocosm 실험을 통해 수층-갈대(뿌리, 잎, 줄기)-토양의 영양염(DIN, DIP) 농도의 춘계 및 하계 모니터링 결과를 이용하여 물질수지를 산정하였으며, 결과는 다음과 같다. 1) 갈대의 생체량은 춘계에는 지하경이 지상경에 비해 약 6.3~9.7 % 높으며, 하계에는 지상경이 지하경에 비해 약 19.2~21.2 % 높게 나타났으며, 갈대의 성장속도는 Mesocosm Tank A가 Mesocosm Tank D에 비해 지상경과 지하경 모두 2~3배 정도 빠르게 나타났다. 2) Mesocosm Tank에서의 갈대의 영양염(DIN, DIP) 농도는 춘계와 하계 모두 각각 2~3 %로 차이가 적었다. 3) Mesocosm Tank별 생체량의 차이는 최대 23 %로 나타나지만, 갈대가 흡수하는 영양염의 농도는 최대 3 % 정도로 차이가 적었다.

• Earthquakes and Structures
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• 제25권6호
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• pp.417-427
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• 2023

If the center of mass and center of stiffness or strength of a structure plan do not coincide, the structure is considered asymmetric. During an earthquake, in addition to lateral vibration, the structure experiences torsional vibration as well. Lateraltorsional coupling in asymmetric structures in the plan will increase lateral displacement at the ends of the structure plan and, as a result, uneven deformation demand in seismically resistant frames. The demand for displacement in resistant frames depends on the magnitude of transitional displacement to rotational displacement in the plan and the correlation between these two. With regard to the inability to eliminate the asymmetrical condition due to various reasons, such as architectural issues, this study has attempted to use supplemental viscous dampers to decrease the correlation between lateral and torsional acceleration or displacement in the plan. This results in an almost even demand for lateral deformation and acceleration of seismic resistant frames. On this basis, using the concept of Torsional Balance, adequate distribution of viscous dampers for the decrease of this correlation was determined by transferring the "Empirical Center of Balance" (ECB) to the geometrical center of the structure plan and thus obtaining an equal mean square value of displacement and acceleration of the plan edges. This study analyzed stiff and flexible torsional structures with one-way and two-way mass asymmetry in the Opensees software. By implementing the Particle Swarm Optimization (PSO) algorithm, the optimum formation of dampers for controlling lateral displacement and acceleration is determined. The results indicate that with the appropriate distribution of viscous dampers, not only does the lateral displacement and acceleration of structure edges decrease but the lateral displacement or acceleration of the structure edges also become equal. It is also observed that the optimized center of viscous dampers for control of displacement and acceleration of structure depends on the amount of mass eccentricity, the ratio of uncoupled torsional-to-lateral frequency, and the amount of supplemental damping ratio. Accordingly, distributions of viscous dampers in the structure plan are presented to control the structure's torsion based on the parameters mentioned.

• 대한기계학회논문집A
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• 제26권8호
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• pp.1585-1590
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• 2002

This paper reports on the balance weight effect on the lubrication and friction characteristics of crankshaft system. To determine the main bearing loads, the crankshaft was treated as statically determinate system. Four and eight-balance weight crankshafts were considered, and minimum oil film thickness and friction loss were calculated. The main bearing loads were increased in the four-balance shaft due to the increasing of unbalanced rotating mass at No. 1 and 3 main bearing sides. The minimum oil film thickness of four-balance shaft became thinner than eight-balance, and friction loss was increased.

• Design & Manufacturing
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• 제7권1호
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• pp.19-22
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• 2013

Almost all injection molds have multi-cavity runner system for mass production, which are designed with geometrically balanced runner system in order to accomplish filling balance between cavity to cavity during processing. However, even though geometrically balanced runner is used, filling imbalances have been observed. So, many studies for improving filling balance in the multi-cavities molds are worked up. In this study, the Melt-Buffer which is a new runner system for filling balance has been suggested, and a series of experiment about degree of filling balance in cavity-to-cavity was conducted in the mold with the Melt-Buffer. From the experiment, the filling balance was increased up to 5~6% by using the Melt-Buffer.

• 한국금형공학회:학술대회논문집
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• 한국금형공학회 2008년도 하계 학술대회
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• pp.95-98
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• 2008

Almost all injection molds have multi-cavity runner system for mass production, which are designed with geometrically balanced runner system in order to accomplish filling balance between cavity to cavity during processing. However, even though geometrically balanced runner is used, filling imbalances have been observed. So, many studies for improving filling balance in the multi-cavities molds are worked up. In this study, the Melt-Buffer which is a new runner system for filling balance has been suggested, and a series of experiment about degree of filling balance in cavity-to-cavity was conducted in the mold with the Melt-Buffer. From the experiment, the filling balance was increased up to $5^{\sim}6%$ by using the Melt-Buffer.

• 한국도로학회논문집
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• 제17권5호
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• pp.1-10
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• 2015

PURPOSES : A finite difference model considering snow melting process on porous asphalt pavement was derived on the basis of heat transfer and mass transfer theories. The derived model can be applied to predict the region where black-ice develops, as well as to predict temperature profile of pavement systems where a de-icing system is installed. In addition, the model can be used to determined the minimum energy required to melt the ice formed on the pavement. METHODS : The snow on the porous asphalt pavement, whose porosity must be considered in thermal analysis, is divided into several layers such as dry snow layer, saturated snow layer, water+pavement surface, pavement surface, and sublayer. The mass balance and heat balance equations are derived to describe conductive, convective, radiative, and latent transfer of heat and mass in each layer. The finite differential method is used to implement the derived equations, boundary conditions, and the testing method to determine the thermal properties are suggested for each layer. RESULTS: The finite differential equations that describe the icing and deicing on pavements are derived, and we have presented them in our work. The framework to develop a temperature-forecasting model is successfully created. CONCLUSIONS : We conclude by successfully creating framework for the finite difference model based on the heat and mass transfer theories. To complete implementation, laboratory tests required to be performed.

• 약학회지
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• 제57권6호
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• pp.412-419
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• 2013

Drug discovery and development processes are time consuming and costly endeavors. It has been reported that on average it takes 10 to 15 years and costs more than $ 1billion to bring a molecule from discovery to market. Compounds fail for various reasons but one of the significant reasons that accounts for failures in clinical trials is poor prediction/understanding of pharmacokinetics and drug metabolism in human. In an effort to improve the number of compounds that exhibit optimal absorption, distribution, metabolism, elimination (ADME), and pharmacokinetic properties in human, drug metabolism, pharmacokinetic scientists have been continually developing new technologies and compound screening strategies. Over the last few years, accelerator mass spectrometry (AMS) and its applications to preclinical/clinical pharmacokinetics and ADME studies have significantly increased, particularly for new chemical/biological entities that are difficult to support with conventional radiolabel studies. In this review, the application of AMS for micro-dosing, micro-tracer absolute bioavailability, mass balance and metabolite profiling studies will be discussed.

• 대한토목학회논문집
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• 제28권5B호
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• pp.475-483
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• 2008

사고 등으로 인해 하천에 순간적으로 주입되는 오염물질의 2차원 이송-확산을 모의하기 위하여 SUPG법에 의한 2차원 유한요소 모형을 개발하고 주입된 질량과 모의 질량간의 오차를 산정하였다. 지배방정식으로부터 질량 오차 산정식을 유도하고 이를 간단한 예제에 적용하였다. 적용 예제로는 단순 직선수로에서 선원을 통한 질량주입과 일방향의 등질 유속장을 가지는 2차원 공간에서 점원을 통한 질량주입 문제를 가정하였으며, 기존의 Galerkin법과의 비교를 위하여 두가지 수치기법에 대한 모의 검증을 실시하였다. 검증결과 기존의 Galerkin법에 의한 모의 결과에 비하여 SUPG법을 통한 수치모형의 구성이 모의의 정확성뿐만 아니라 주입 질량의 보존에 있어서도 보다 정확한 방법임을 확인하였다.