• 제목/요약/키워드: Marine Corrosion

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알루미늄 합금 및 스테인리스강의 해수 농도 변화에 따른 전기화학적 부식 손상 특성 (Electrochemical Corrosion Damage Characteristics of Alumium Alloy and Stainless Steel with Sea Water Concentration)

  • 박일초;김영복;김성종
    • 한국표면공학회지
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    • 제50권4호
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    • pp.259-265
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    • 2017
  • 5000 series aluminium alloys and austenitic stainless steels have excellent corrosion resistance and sufficient strength, which are widely used as materials for marine equipment and their parts in the marine environment. The corrosion characteristics of materials are important factors for selecting the appropriate material due to fluid component changes in the estuarine and coastal areas where seawater and fresh water are mixed. Therefore, for 5083 Al alloy, STS304 and STS316L widely used in the marine environment, anodic polarization experiments were performed to compare the corrosion damage characteristics of each material by three kinds of solutions of 100 % tap water, 50 % tap water+50 % natural seawater and 100 % natural seawater. As a result of the anodic polarization experiments, aluminum alloy (5083) caused locally corrosion on the surface in the tap water, and corrosion damage occurred all over the surface when the seawater was included. Stainless steels (STS304 and STS316L) presented almost no corrosion damage in tap water, but they grew pitting corrosion damage with increasing seawater concentration. STS316L showed better corrosion resistance than STS304.

알루미늄 용융 도금된 304 스테인리스강의 해수 내 전기화학적 부식 특성 평가 (Evaluation of Electrochemical Corrosion Characteristics for Hot-Dip Aluminized 304 Stainless Steel in Seawater)

  • 정상옥;박일초;한민수;김성종
    • 한국표면공학회지
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    • 제48권6호
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    • pp.354-359
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    • 2015
  • Stainless steel has poor corrosion resistance in marine environment due to the breakdown of a passive film caused by chloride. It suffers electrochemical corrosion like pitting corrosion, crevice corrosion, and stress corrosion crack (SCC) in marine environment. In general, it indicates that the passive film of $Al_2O_3$ has better corrosion resistance than that of $Cr_2O_3$ in seawater. This paper investigated the damage behavior 304 stainless steel and hot-dip aluminized 304 stainless steel in seawater solution. Various electrochemical experiments were carried out including potential measurement, potentiodynaimic experiment, Tafel analysis and galvanostatic experiment. As a result of anodic polarization experiment, higher pitting damage depth was indicated at 304 stainless steel than hot-dip aluminized 304 stainless steel. In addition, relatively higher corrosion current density was shown at hot-dip aluminized stainless steel as a result of Tafel analysis.

철근 콘크리트 시험편의 철근방식에 관한 측정법 (Corrosion Measurements on Reinforcing Rebars in Reinforced Concrete Specimen)

  • 이강균;장지원;한기훈;정영수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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    • pp.281-286
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    • 1997
  • Recent construction activities and maintenance of marine facilities have been accelerating to keep up with rapid economic growth in Korea. Marine concrete structures are exposed to salts an chloride from ocean environments. The corrosion of reinforcement steel caused by chloride-penetration into concrete may severely effect the durability of concrete structures. The objective of this research is to develop a durable concrete by investigating the corrosion resistance of various corrosion protection systems utilizing different water/cement ratio, silica fumes, corrosion inhibitors and etc. A tow-year verification test on various corrosion protection systems has been doing in the laboratory and at the seaside. Corrosion investigations on reinforcement steel are now under progress for more than 180 concrete specimen. Corrosion-related measurements include macrocell corrosion current, instant-off voltage between corroding and noncorroding reinforcement, chloride contents, the corroded surface areas on the reinforcement steel, and etc. A low level of corrosion is investigated on reinforcement steels in concrete specimen made with corrosion inhibitors or applied aqueous impregnating corrosion inhibitors into their surface, even though high chloride contents of concrete specimen.

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Corrosion Behaviour of Some Alloys in Tropical Urban and Marine Atmospheres

  • Dang, Vu Ngoan;Bui, Ba Xuan;Nguyen, Nhi Tru
    • Corrosion Science and Technology
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    • 제7권2호
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    • pp.125-129
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    • 2008
  • Results of corrosion testing for different grades of titanium, copper, zinc, alluminium alloys and steels after two years of outdoor exposure under humid tropical urban and marine conditions have been presented and discussed. Mass loss and corrosion product characteristics for the exposed specimens at Hanoi testing site with high humidity and Nhatrang marine stations (at 100 and 1,000 meters distances from sea) with different airborne salinities (35.9 and $90.0mg/m^2.d$ respectively) have been selected for investigation. From time dependence of the specimen mass loss and corrosion product characteristics, the strong influence of environmental parameters upon durability for the investigated metals and alloys has been demonstrated. Only titanium alloys show high resistance to the marine conditions. All the other specimens (copper, zinc, alluminium alloys and steels) have been underwent strong deterioration under influence of aerosol salinity. Results of corrosion products analysis have been also presented for characterization of environmental impact on the metal degradation processes.

알루미늄 용사코팅의 불소실리콘 봉공재 적용에 따른 전기화학적 및 캐비테이션 특성 평가 (Electrochemical and Cavitation Characteristics of Al Thermal Spray Coating with F-Si Sealing)

  • 한민수;이승준;장석기;김성종
    • Corrosion Science and Technology
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    • 제9권6호
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    • pp.317-324
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    • 2010
  • Marine transportation by ships is characterized by remote, large-volume and lower rates than the others carry system. Ships account for over 80% of all international trading, and marine transportation is an internationally competitive, strategic, and great national important industry. The construction of larger and faster ships has brought about many problems such as cavitations and erosion corrosion. Cavitations and erosion corrosion make damages on materials and leads to break down members due to continuous physical contacts with shock waves and fluids from the generation and extinction of air bubbles in sea water vortex. The steel used for ship constructions was spray-coated with Al wire, and additionally sealed with fluorine silicone sealing material. Results of experiment, corrosion resistance of sealed thermal spray coating was improved, however in cavitation resistance, the large effect was not appeared. Accordingly, this study applied for thermal spray coating to provide better electrochemical characteristics and corrosion resistance in marine environment.

베어링 합금재의 캐비테이션 침식-부식거동에 미치는 유화 윤활유의 영향 (Influence of Lubricating Oil Emulsified on the Behaviour of Cavitation Erosion - Corrosion at Bearing Metals)

  • 임우조;이진열
    • Journal of Advanced Marine Engineering and Technology
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    • 제17권3호
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    • pp.42-49
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    • 1993
  • Recently, because the lubricating oil showed a tendency to be emulsified and oxidized by high speed, high output and the extension of maintenance & conservation of marine engine, the cavitation erosion-corrosion at such an environment became a big problem on effective performance of engine. Therefore, there was a need to study the behavior and protection of erosion-corrosion damage, and then applied inhibitor to a protective method of cavitation erosion- corrosion damage. At this time, test environments were marine lubricating oil & various emulsified oil that mixed distilled water and sea water etc., and also used 20KHz, 24.mu.m piezoelectric vibrator as an experimental apparatus of cavitation erosion. With this apparatus, we investigated an influence of the emulsified oil on characteristics of erosion-corrosion and protection for erosion-corrosion by inhibitor at slide bearing metals.

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해양환경중에서 SS400강재의 간극부식거동에 관한 연구 (Study on the Crevice Corrosion Behavior of SS 400 in Marine Environment)

  • 임우조;정기철;안석환;윤병두
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2000년도 추계학술대회 논문집(Proceeding of the KOSME 2000 Autumn Annual Meeting)
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    • pp.1-6
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    • 2000
  • This paper was studied on the crevice corrosion behavior of SS 400 in marine environment. In 0%, 2%, 3.5%, 5% NaCl solution, the aspect of the crevice corrosion and polarization behavior under the crevice corrosion was investigated. And Weight loss rate of SS 400 with crevice and non-crevice was measured according to the NaCl concentration. The main results obtained are as follows : 1) Under crevice corrosion, the corrosion potential become less noble as the concentration of NaCl solution increased. 2) The current density under open circuit potential was high drained as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, the current density was low drained. 3) The weight loss rate of SS400 was increased as concentration of NaCl solution increased by 3.5% but the concentration increased over 3.5%, that of SS400 was decreased.

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화학제염공정에서 환원공정조건에 따른 Inconel 600의 부식손상 특성 (Corrosion Damage Characteristics of Inconel 600 with Reduction Conditions in Chemical Decontamination Process)

  • 한민수;정광후;양예진;박일초;이정형;김성종
    • 한국표면공학회지
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    • 제50권5호
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    • pp.332-338
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    • 2017
  • In this study, we evaluated tendency and degree of corrosion damages of Inconel 600 after chemical decontamination treatments under three different conditions. In the decontamination processes, the oxidation and reduction were performed as one cycle. Each process was continued up to 5 cycles. Characteristics of corrosion under decontamination processes were evaluated by Tafel analysis and weight loss. Characteristics of surface damage were observed by scanning electron microscope(SEM) and three-dimensional(3D) microscope. As the cycle proceeded, weight loss and corrosion current density increased. Intergranular corrosion damage occurred on the surface of the materials. The result revealed that the surface of Inconel 600 was attacked by the strong acid solution under all chemical decontamination processes, but the degree of the corrosion damage was different depending on the processes.

해양환경 중에서 Ni-Cr 용사피복재의 침식-부식 억제에 관한 연구 (Study on the Control of the Erosion-Corrosion for Ni-Cr Alloy Sprayed Coating in the Marine Environment)

  • 임우조;이상열;윤병두
    • 수산해양교육연구
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    • 제11권2호
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    • pp.139-149
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    • 1999
  • Thermal sprayed Ni-Cr alloy coating on the carbon steel was carried out erosion-corrosion test and electrochemical corrosion test in the marine environment. The erosion-corrosion behavior and electrochemical corrosion characteristics of substrate(SS400) and thermal sprayed Ni-Cr coating was investigated. The erosion-corrosion control efficiency of Ni-Cr coating to substrate was also estimated quantitatively. The main results obtained are as follows : 1) The weight loss rate of Ni-Cr coating layer by the erosion-corrosion compared with substrate was smaller. With the lapse of time, the weight loss rate of substrate was linearly increased in $25{\Omega}{\cdot}cm$ solution, but that of Ni-Cr coating became stable. 2) The corrosion potential of substrate became less noble than that of Ni-Cr coating layer, and the corrosion current density of Ni-Cr coating became lower than that of substrate. 3) The control efficiency of erosion-corrosion of Ni-Cr coating compared to substrate became more dull than that of corrosion in $25{\Omega}{\cdot}cm$ and $5000{\Omega}{\cdot}cm$ solution.

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Compressive behavior of circular hollow and concrete-filled steel tubular stub columns under atmospheric corrosion

  • Gao, Shan;Peng, Zhen;Wang, Xuanding;Liu, Jiepeng
    • Steel and Composite Structures
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    • 제33권4호
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    • pp.615-627
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    • 2019
  • This paper aims to study the compressive behavior of circular hollow and concrete-filled steel tubular stub columns under simulated marine atmospheric corrosion. The specimens after salt spray corrosion were tested under axial compressive load. Steel grade and corrosion level were mainly considered in the study. The mechanical behavior of circular CFST specimens is compared with that of the corresponding hollow ones. Design methods for circular hollow and concrete-filled steel tubular stub columns are modified to consider the effect of marine atmospheric corrosion. The results show that linear fitting curves could be used to present the relationship between corrosion rate and the mechanical properties of steel after simulated marine atmospheric corrosion. The ultimate strength of hollow steel tubular and CFST columns decrease with the increase of corrosion rate while the ultimate displacement of those are hardly affected by corrosion rate. Increasing corrosion rate would change the failure of CFST stub column from ductile failure to brittle failure. Corrosion rate would decrease the ductility indexes of CFST columns, rather than those of hollow steel tubular columns. The confinement factor ${\xi}$ of CFST columns decreases with the increase of corrosion rate while the ratio between test value and nominal value shows an opposite trend. With considering marine atmospheric corrosion, the predicted axial strength of hollow steel tubular and CFST columns by Chinese standard agree well with the tested values while the predictions by Japanese standard seem conservative.