• Journal of Korean Society of Water and Wastewater
• /
• v.20 no.1
• /
• pp.86-93
• /
• 2006

In the drinking water treatment, the aesthetic and color problem are caused by the manganese which is occurring and present in the surface, lake and ground water. The most common treatment processes for removing manganese are known for oxidation followed by filtration. In this study, the manganese sand process was used for removing manganese with river bank filtrate as a source. In the manganese sand process, the residual chlorine and pH are important factors on the continuous manganese oxidation. In addition, space velocity (SV) and alum dosage are play a role of manganese removal. Even though manganese removal increased with increasing chlorine concentration, the control of residual chlorine is actually difficult in this process As the results of tests, the residual chlorine concentration as well as manganese removal were effectively achieved at pH 7.5. The optimum attached manganese concentration on manganese sand was confirmed to 0.3mg/L by the experimental result of a typical sand converting to manganese sand.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.25 no.4
• /
• pp.472-481
• /
• 2015

Objectives: Welding is a major task in shipbuilding yards that generates welding fumes. A significant amount of welding in shipbuilding yards is done on steel. Inevitably, manganese is present in the base metals being joined and the filler wire being used and, consequently, in the fumes to which workers are exposed. The objective of this work was to characterize manganese exposure associated with work area, total and particle size-selective mass concentration, and compare the mass concentrations obtained using a three-piece cassette sampler, size-selective impactor sampler and blood manganese concentrations. Materials: All samples were collected from the main work areas at one shipbuilding yard. We used a three piece cassette sampler and the eight stage cascade impactor sampler for the airborne manganese mass concentration of total and all size fractions, respectively. In addition, we used the results of health examination of workers sampled for airborne manganese. Results: The oder of high concentration of airborne manganese in shipbuilding processes was as follows; block assembly, block erection, outfitting installation, steel cutting, and outfitting preparation. The percentages of samples that exceeded the OES of the ministry of employment and labor by the cassette sampling method was 12.5%, however 59.1% of sampled workers by the impactor sampling method exceeded the TLV of the ACGIH. Conclusions: Even though the manganese concentrations in blood of workers exposed to higher airborne manganese concentration were higher than among those exposed to lower concentrations, there was no difference in blood manganese concentrations among work duration. The data analyzed here by characterizing size-selective mass concentrations indicates that the inhaled manganese of welders in shipbuilding yards could be mostly manganese-containing respirable particle sizes.

• Journal of Korean Society of Industrial and Systems Engineering
• /
• v.41 no.3
• /
• pp.90-96
• /
• 2018

This paper proposed data driven techniques to forecast the time point of water management of the water reservoir without measuring manganese concentration with the empirical data as Juam Dam of years of 2015 and 2016. When the manganese concentration near the surface of water goes over the criteria of 0.3mg/l, the water management should be taken. But, it is economically inefficient to measure manganese concentration frequently and regularly. The water turnover by the difference of water temperature make manganese on the floor of water reservoir rise up to surface and increase the manganese concentration near the surface. Manganese concentration and water temperature from the surface to depth of 20m by 5m have been time plotted and exploratory analyzed to show that the water turnover could be used instead of measuring manganese concentration to know the time point of water management. Two models for forecasting the time point of water turnover were proposed and compared as follow: The regression model of CR20, the consistency ratio of water temperature, between the surface and the depth of 20m on the lagged variables of CR20 and the first lag variable of max temperature. And, the Box-Jenkins model of CR20 as ARIMA (2, 1, 2).

• Journal of Korean Society on Water Environment
• /
• v.20 no.5
• /
• pp.409-414
• /
• 2004

Pilot-scale experiments were performed for the treatment of bank filtrate contammg high manganese concentration around 2mg/L using rapid manganese sand filtration to investigate effects of oxidant dose and pH control on the removal efficiency of manganese. For theoretical dose ranges of oxidant (sodium hypochlorite) between 3 and 4mg/L, the manganese concentration of effluent was 0.57 mg/L, which corresponded to 72.5% removal and was higher than drinking water quality standards of 0.3mg/L. For excess dose ranges of oxidant between 4 and 8mg/L, the manganese concentration of effluent was reduced to 0.14mg/L, which corresponded to 94.5% removal, but the residual chlorine concentration was over 1.0mg/L. On the other hand, manganese removal efficiency drastically increased up to the value of 98.0%, which is equivalent to the effluent concentration of 0.03mg/L by controling pH to the range between 7 and 8 for the theoretical dose of oxidant. Consequently, these results indicated that appropriate dose of chemicals, such as oxidant and alkali, and continuous monitoring of manganese should be necessary to obtain efficient removal of manganese and to optimize the maintenance of treatment facilities for the treatment of bank filtrate with high concentration of manganese.

• Journal of Korean Society of Water and Wastewater
• /
• v.20 no.6
• /
• pp.813-822
• /
• 2006

Soluble manganese removal was analyzed as a function of filter media, filter depth, presence or absence of chlorination, and surface manganese oxide concentration in water treatment processes. Sand, manganese oxide coated sand (MOCS), sand+MOCS, and granular activated carbon(GAC) were used as filter media. Manganese removal, surface manganese oxide concentration, turbidity removal, and regeneration of MOCS in various filter media were investigated. Results indicated that soluble manganese removal in MOCS was rapid and efficient, and most of the removal happened at the top of the filter. When filter influent (residual chlorine 1.0mg/L) with an average manganese concentration of 0.204mg/L was fed through a filter column, the sand+MOCS and MOCS columns can remove 98.9% and 99.2% of manganese respectively on an annual basis. On the other hand, manganese removal in sand and the GAC column was minimal during the initial stage of filtration, but after 8 months of filter run they removed 99% and 35% of manganese, respectively. Sand turned into MOCS after a certain period of filtration, while GAC did not. In MOCS, the manganese adsorption rate on the filter media was inversely proportional to the filter depth, while the density of media was proportional to the filter depth.

• Journal of Korean Society of Water and Wastewater
• /
• v.21 no.4
• /
• pp.503-508
• /
• 2007

Small scale D-water treatment plant(WTP) where has slow sand filtration was using raw water containing high concentration of manganese (> 2mg/l). The raw water was pre-chlorinated for oxidation of manganese and resulted in difficulty for filtration. Thus, sometimes manganese concentration and turbidity were over the water quality standard. Two stage rapid manganese sand filtration pilot plant which can treat $200m^3/d$ was operated to solve manganese problem in D-WTP. The removal rate of manganese and turbidity were about 38% and 84%, respectively without pH control of raw water. However, when pH of raw water was controlled to average 7.9 with NaOH solution, the removal rate of manganese and turbidity increased to 95.0% and 95.5%, respectively and the water quality of filtrate satisfied the water quality standard. Manganese content in sand was over 0.3mg/g which is Japan Water Association Guideline. The content in upper filter was 5~10 times more than that of middle and lower during an early operation but the content in middle and lower filter was increased more and more with increase of operation time. This result means that the oxidized manganese was adsorbed well in sand. Rapid manganese sand filter was backwashed periodically. The water quality of backwash wastewater was improved by sedimentation. Thus, turbidity and manganese concentration decreased from 29.4NTU to 3.09NTU and from 1.7mg/L to 0.26mg/L, respectively for one day. In Jar test of backwash wastewater with PAC(Poly-aluminum chloride), optimum dosage was 30mg/L. Because the turbidity of filtrate was high as 0.76NTU for early 5 minute after backwash, filter-to-waste should be used after backwash to prevent poor quality water.

• Journal of Korean Society of Water and Wastewater
• /
• v.22 no.6
• /
• pp.633-640
• /
• 2008

In this research, the $3.6m^3/day$ scale pilot plant consisting preozonation, coagulation, flocculation, and ceramic membrane processes was operated for long term period to evaluate the validity of ceramic membrane filtration process for treating lake water containing high concentration manganese. The higher concentration of dissolved manganese($Mn^{2+}$) was effectively oxidized to the bigger insoluble colloidal manganese ($MnO^2$) by 1~2 mg/L ozone. The colloidal manganese reacted with coagulant (poly aluminium chloride, PAC) and then formed the big floc. Ceramic membrane rejected effectively manganese floc during membrane filtration. Dissolved organic carbon(DOC) removal was dependent upon $Mn^{2+}$ concentration. While average $Mn^{2+}$ concentration was 0.43 and 0.85 mg/L in raw water, DOC removal rate in preozonation was 26.5 and 13.5%, respectively. The decrease rate of membrane permeability was faster without preozonation than with preozonation while membrane fouling decreased with NOM oxidation by ozone. In conclusion, raw water containing high concentration of manganese can be effectively treated in preozonation-coagulation-ceramic membrane filtration system.

• Journal of Preventive Medicine and Public Health
• /
• v.28 no.2 s.50
• /
• pp.406-420
• /
• 1995

To study the health hazards and exposure status of manganese among female manganese workers, authors conducted airborne, blood and urine manganese concentration measurements, questionnaire and neurological examinations on 80 manganese-handling productive female workers(exposed group) in a manganese manufacturing facto in Pohang city and 127 productive female workers not handling manganese(control group) in other factories in the Pohang city. The results are; 1. Geometric mean concentrations of manganese in air and urine were $0.98mg/m^3\;and\;4.12{\mu}g/l$ and arithmetic mean concentration of manganese in blood was $6.94{\mu}g/dl$ in exposed group, significantly higher than those of control group(p<0.05). However, clinical and laboratory findings in exposed group were not statistically different from those of control group. 2. As age increase, positive rates of clinical symptoms also increased in the exposed group. However, in older aged group, the positive rates of symptoms and signs were statistically different from those of control group. We observed the same tendency in the positive rates of the neurological examinations. 3. There was statistically significant correlation between airborne and urine manganese concentrations(r=0.61, p<0.01) while there was no statistically significant correlation between airborne and blood manganese concentrations(r=0.29, p>0.05). The results suggest that urine manganese concentration was the best appropriate biomarker to estimate the exposure to manganese in respect to clinical symptoms and signs. In the analysis of correlation between urine and airborne manganese concentrations, it is required to adjust the present permissible exposure level(PEL) of airborne manganese.

• Journal of Korean Society of Water and Wastewater
• /
• v.25 no.4
• /
• pp.547-554
• /
• 2011

In small-scale water systems, the measurement of quality of raw water in running water is generally implemented when the quality of water is stable and frequency of measurement is low. However, units such as water temperature and pH, which are easily monitored, are frequently measured. In establishing an improvement plan for a water treatment system, the range of concentration of the target material present in the raw water of the running water provides relevant information. If the concentration of target material can be specified by the quality of water of data items that are measured daily, inverse estimation of the range of concentration is possible as well. In this paper, we took note of manganese in the raw water from Ogasawara-mura, Tokyo, and estimated the manganese concentration in the raw water of the running water for the past five years. Based on the results obtained, we have proposed a manganese removal system, considering the current situation and geographical conditions of Ogasawara-mura.

• Journal of Korean Society of Water and Wastewater
• /
• v.24 no.3
• /
• pp.341-349
• /
• 2010

It is well known that manganese is hard to oxidize under neutral pH condition in the atmosphere while iron can be easily oxidized to insoluble iron oxide. The purpose of this study is to identify removal mechanism of manganese in the D water treatment plant where is treating bank filtered water in aeration and rapid sand filtration. Average concentration of iron and manganese in bank filtered water were 5.9 mg/L and 3.6 mg/L in 2008, respectively. However, their concentration in rapid sand filtrate were only 0.11 mg/L and 0.03 mg/L, respectively. Most of the sand was coated with black colored manganese oxide except surface layer. According to EDX analysis of sand which was collected in different depth of sand filter, the content of i ron in the upper part sand was relatively higher than that in the lower part. while manganese content increased with a depth. The presence of iron and manganese oxidizing bacteria have been identified in sand of rapid sand filtration. It is supposed that these bacteria contributed some to remove iron and manganese in rapid sand filter. In conclusion, manganese has been simultaneously removed by physicochemical reaction and biological reaction. However, it is considered that the former reaction is dominant than the latter. That is, Mn(II) ion is rapidly adsorbed on ${\gamma}$-FeOOH which is intermediate iron oxidant and then adsorbed Mn(II) ion is oxidized to insoluble manganese oxide. In addition, manganese oxidation is accelerated by autocatalytic reaction of manganese oxide. The iron and manganese oxides deposited on the surface of the sand and then are aged with coating sand surface.