• 한국환경과학회지
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• 제18권10호
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• pp.1103-1114
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• 2009

In this study, the environmental behavior of malodor pollutants (MPs: $H_2S$, $CH_3SH$, DMS, and DMDS) was investigated around areas influenced by strong anthropogenic processes based on observations and modeling study (a CALPUFF dispersion model). The MP emission concentrations were measured from 8 industrial source regions (tire plants (S1-S3), waste water disposal plant (S4), and oil refinery (S5) in an urban center area and paper mill/incineration plant (S6) and livestock feedlots (S7-S8) in Ungsang area) in Yangsan city during a fall period in 2008 (21 October 2008). Overall, the most MPs emitted from the urban center area were found to affect the malodor pollution in their downwind areas during early morning (06:00 LST) and nighttime (18:00 and 21:00 LST), compared with those in the Ungsang area. For malodor intensity, the most MPs in the urban center area (especially S1 and S2) were found to be a significant contributor, whereas $CH_3SH$ and $H_2S$ in the Ungsnag area (especially S6) were the dominant contributor. The model study showed agreement in the spatial distributions of simulated MPs with those of the observations. The largest impact of MPs in the urban center area on the malodor pollution in its residential areas occurred at S1, S2, and S3 sites during nighttime, while that of MPs in the Ungsang area occurred at S6 and S8 sites. This may be caused mainly by the high MP emissions and in part by wind conditions (prevailing northeasterly winds with low wind speeds of 2-3 m/s).

• 한국대기환경학회지
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• 제23권1호
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• pp.110-124
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• 2007

In this study, the control efficiency of odorous compounds was measured from diverse control process units of 14 individual companies located within the Ban-Wall industrial complex of Ansan city, Korea (January to July 2005), To quantify the control efficiency levels of major odorous compounds, we collected odor samples from both the front and rear side of 17 control process units ($N=17{\times}2=34$). If the control efficiency is compared for each of 32 compounds between different process units, wet scrubber (WS) was found to be the most effective unit in terms of the sum of pollutants showing the positive control signals. Although the WS system shows generally a good control pattern for VOC, it is not the case for most index odorous pollutants; only 3 out of 12 index compounds were found to show positive control efficiencies. The results of the study also indicated that the control efficiency differ greatly between different industrial sectors and/or control process types. In the case of leather industry, carbonyl compounds were found to exhibit the highest control efficiency with its values varying from 19 to 90%. On the other hand, in the case of metal production sector, VOC recorded the maximum control efficiency with values varying from 18 to 79%. According to this study, most air pollution control facilities operated in most companies show fairly poor control efficiencies for most malodor compounds. Hence, to obtain best control efficiency of odorous pollutant emission, acquisition of better information on source characteristics and establishment of effective control technologies are highly demanding.

• 한국환경과학회지
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• 제25권11호
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• pp.1555-1562
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• 2016

Concentrations of hydrogen sulfide in ambient air have been measured from January 2014 to June 2016 in a coastal area near the Ulsan National Industrial Complex. The measurement sites were 1 km, 2.6 km, 5.6 km, and 20 km away from a kraft pulp mill, which is located at the most southern edge of the complex. Concentrations above 0.4 ppb were monitored every 5 min and the highest concentration of the day was determined. From a total of 775 measurement days, hydrogen sulfide concentrations > 20 ppb were recorded on 36 and 38 days at the measurement site closest to the mill and the residential area 2.6 km away from the mill, respectively. At the site farthest from the mill, the concentrations were always 20 ppb lower than the malodor regulation for the residential area but sometimes higher than the odor recognition threshold for hydrogen sulfide. Although several emission sources of hydrogen sulfide have been published in the Pollutant Release and Transfer Register of Korea, the kraft pulp mill is considered to be the biggest contributor of atmospheric hydrogen sulfide in the southern coastal area of Ulsan.

• 한국대기환경학회지
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• 제21권1호
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• pp.107-118
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• 2005

In this study, the concentrations of major odorous compounds including reduced sulfur compounds (OMS, CS$_2$, and DMDS) and aromatic VOC (benzene, toluene, xylene, etc.) were measured continuously using an on-line GC analytical system. Our measurements were made from a residential area of Ansan sity during about two week period of October, 2004. The highest mean concentrations of Sand VOC were found as 56.9 pbb of DMS and 21.7 ppb of toluene, respectively. The results of this study generally show that the pollution levels for both types of chemicals are significant relative to previous measurement results reported from comparable sites, if the results are compared simply in terms of the magnitude of the measured concentration data. Moreover, when the relative importance of different compounds is compared in terms of the odor strength, it indicated that the contribution of reduced S compounds may be much more important than that of VOC in the study area.