• 한국자기학회:학술대회 개요집
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• 한국자기학회 2011년도 임시총회 및 하계학술연구발표회
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• pp.129-129
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• 2011

The limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of properties and electronic structures of seven layered $Pt_3Ni$ (001), (110), and (111) surfaces. The first principle method based on density functional theory (DFT) is carried out. It is found that the bulk $Pt_3Ni$ has a ferromagnetic ground state with the ordered fcc type L12 structure, which is in good agreement with other results. Non magnetic Pt has the induced magnetic moment due to the strong hybridization between 3d Ni and 5d Pt. The magnetic moment of Pt and Ni enhanced on the surface of each due to surface effect however the magnetic moment of surface Pt in the Pt-segregated Pt3Ni (111) decreased and the magnetic moment of Ni in Ni rich subsurface increased significantly. The calculated d band centers of Pt explain the possibilities for oxygen absorption and play the important roles in altering the catalytic properties. The spin polarized densities of states are presented in order to understand physical properties of Pt in different surfaces in detail.

• Investigative Magnetic Resonance Imaging
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• 제4권1호
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• pp.20-26
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• 2000

Gradient moment nulling techniques require the introduction of an additional gradient on each axis for each order of motion correction to be applied. The additional gradients introduce new constraints on the sequence design and increase the demands on the gradient system. The purpose of this paper is to demonstrate techniques for optimization of gradient echo gradient moment nulling sequences within the constraints of the gradient hardware. Flow compensated pulse sequences were designed and implemented on a clinical magnetic resonance imaging system. The design of the gradient moment nulling sequences requires the solution of a linear system of equations. A Mathematica package was developed that interactively solves the gradient moment nulling problem. The package allows the physicist to specify the desired order of motion compensation and the duration of the gradients in the sequence with different gradient envelopes. The gradient echo sequences with first, second, and third order motion compensation were implemented with minimum echo time. The sequences were optimized to take full advantage of the capabilities of the gradient hardware. The sequences were used to generate images of phantoms and human brains. The optimized sequences were found to have better motion compensation than comparable standard sequences.

• Journal of Magnetics
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• 제13권4호
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• pp.124-127
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• 2008

The magnetic and electronic properties of Ni impurity in bcc Fe ($Ni_1Fe_{26}$) are investigated using the full potential linearized augmented plane wave (FLAPW) method based the generalized gradient approximation (GGA). We found that the Ni impurity in bcc Fe increases both the lattice constant and the magnetic moment of bcc Fe. The calculated equilibrium lattice constant of $Ni_1Fe_{26}$ in the ferromagnetic state was 2.84 A, which is slightly larger than that of bcc Fe (2.83 ${\AA}$). The averaged magnetic moment per atom of $Ni_1Fe_{26}$ unit cell was calculated to be $2.24{\mu}_B$, which is greater than that of bcc Fe (2.17 ${\mu}_B$). The enhancement of magnetic moment of $Ni_1Fe_{26}$ is mainly contributed by the nearest neighbor Fe atom of Ni, i.e., Fe1, and this can be explained by the spin flip of Fe1 d states. The density of states shows that Ni impurity forms a virtual bound state (VBS), which is contributed by Ni $e_{g{\downarrow}}$ states. We suggest that the VBS caused by the Ni impurity is responsible for the spin flip of Fe1 d states.

• 한국자기공명학회논문지
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• 제7권1호
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• pp.16-24
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• 2003

Nuclei with the spin quantum number not smaller than unity have not only the nuclear magnetic moment but also the electric quadrupole moment. The quadrupole moment couples with the electric field gradient (EFG) to produce the nuclear quadrupole interaction. It is well known that two independent parameters, i.e. the quadrupole coupling constant (QCC) and the asymmetry parameter ($\eta$) together with the principal axis directions can fully describe the interaction and are very sensitive to the local symmetry and structure of the solid. In order to obtain quantitative estimates of the EFG tensor for various simple ionic configurations surrounding the nucleus under consideration, we employ the simple point charge approximation and apply the calculated results to some real crystals. General agreement is rather satisfactory.

• 한국초전도ㆍ저온공학회논문지
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• 제25권3호
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• pp.28-33
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• 2023

Magnetic relaxation properties of pure MgB₂ powder samples and diluted water-treated MgB₂ powder samples were investigated. The magnetic field H-dependence, m(H), and the time t-dependence, m(t), of the magnetic moment m were measured and analyzed using the PPMS-VSM magnetometer equipment, respectively. The m(t) reduction rates of pure MgB₂ powder samples and diluted water-treated MgB₂ powder samples decreased to about 0.7 ~ 1.8% and 0.6 ~ 1.0% for about 7200 s, respectively, at temperature T = 15 K. The magnetic relaxation properties of the two types of MgB₂ powders were analyzed by calculating the magnetic relaxation rate S = -dln(M_irr)/dln(t) values according to Anderson-Kim theory. The magnetic relaxation ratio S values of the two types of MgB₂ powder samples were almost similar. As a result of the quantum creep effect, the constant magnetic relaxation rate S characteristic was confirmed at a temperature range of T = 10 K or less.

• 한국자기학회지
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• 제5권5호
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• pp.767-771
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• 1995

The atomic structure and magnetic properties of $LaCo_{13}$ amorphous alloy have been investigated and compared with those of its crystalline counterpart. It has been confirmed that the amorphous alloy is composed of the icosahedral clusters with a $NaZn_{13}$-type structure. The magnetic moment and the spin- wave stiffness constant obtained from the magnetic measurements in the amorphous state are larger than those in the crystalline state. The Curie temperature estimated from the reduced magnetization curve for the former is much higher than the value for the latter. The localized magnetic moment character in the amorphous state is stronger than that in the crystalline state.

• 한국자기학회지
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• 제3권2호
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• pp.94-100
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• 1993

신소재 희토류 영구자석인 $Sm_{2}Fe_{17}N_{3}$ 화합물에 대한 자체충족적 국재밀도함수 근사 전자구조 계산을 수행하여 이 물질의 전자기적 물성을 연구하였다. LMTO(Linearized Muffin-Tin Orbital) 에너지 띠 방법을 사용하여 상자성, 강자성상 $Sm_{2}Fe_{17}N_{3}$ 화합물의 에너지 띠 구조를 결정 하고 이를 토대로 이화합물의 전기적, 자기적 구조와 Sm, Fe, N원자들간의 결합효과등을 고찰하였다. N원자는 근접 Fe원자와의 혼성 상호작용을 통하여 Fe원자의 자기모멘트를 많이 줄이는 효과를 주며 또한 구조 안정성에 기여한다는 결과를 얻었다. 강자성상 $Sm_{2}Fe_{17}N_{3}$에서의 Fe원자들의 평균 자기모멘트는 $Sm_{2}Fe_{17}$의 $2.16{\mu}_B$에 비해 약 8% 증가한 $2.33{\mu}_B$로 계산되었는데 이중 N원자로 부터 가장 멀리 떨어져 있으며 12개의 Fe원자들로 둘러싸인 Fe I (c) 원자가 가장 큰 값($2.65{\mu}_B$)의 자기모멘트르 갖고 N원자와의 혼성 상호작용이 가장 큰 Fe III(f)원자가 가장 작은 값($1.96{\mu}_B$)의 자기모멘트를 갖는다.

• 한국자기학회지
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• 제16권4호
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• pp.193-196
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• 2006

제일원리적 국소 스핀밀도 근사에 의한 계산방법을 이용하여 Ni 나노와이어에 대한 전자구조와 자기적 성질을 연구하였다. 단위 세포당 Ni 원자의 개수(n = 1 − 4)에 따른 구조적 특성에 따라 각각의 나노와이어에 대한 결합에너지와 자기모멘트를 계산하였다. 계산결과 지그재그-사각형 $Ni_4$ 나노와이어가 에너지적으로 가장 안정하였다. 또한 Ni 나노와이어의 자기모멘트는 선형 나노와이어 Ni1가 $1.34 {\mu_B}/atom$ 로 가장 큰 값을 나타냈으며, 단위 세포당 원자 개수가 증가될수록 자기모멘트는 감소하여 사각형 나노와이어 $Ni_4$의 자기모멘트가 $0.91 {\mu_B}/atom$ 로 가장 작은 값을 나타냈다. $Ni_n$(n = 1 − 4)의 각각의 구조들에 대한 상태밀도, 에너지 띠 등의 전자구조 계산결과를 제시하고 논의 검토하였다.

• 한국분말재료학회지
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• 제21권4호
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• pp.256-259
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• 2014

A magnetic powder, M-type barium hexaferrite (BaFe12O19), was consolidated with the spark plasma sintering process. Three different holding temperatures, $850^{\circ}C$, $875^{\circ}C$ and $900^{\circ}C$ were applied to the spark plasma sintering process with the same holding times, heating rates and compaction pressure of 30 MPa. The relative density was measured simultaneously with spark plasma sintering and the convergent relative density after cooling was found to be proportional to the holding temperature. The full relative density was obtained at $900^{\circ}C$ and the total sintering time was only 33.3 min, which was much less than the conventional furnace sintering method. The higher holding temperature also led to the higher saturation magnetic moment (${\sigma}_s$) and the higher coercivity ($H_c$) in the vibrating sample magnetometer measurement. The saturation magnetic moment (${\sigma}_s$) and the coercivity ($H_c$) obtained at $900^{\circ}C$ were 56.3 emu/g and 541.5 Oe for each.

• Progress in Superconductivity
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• 제11권2호
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• pp.135-140
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• 2010

We propose a variational wave function for the ground state of the magnetic heavy fermion (HF) systems, in which both the Kondo and the RKKY interactions are variationally incorporated and the local f-orbital state exists as a linear combination of a full local moment state and a fully compensated state (mixed wave state). We describe the mechanism for the mixed wave ground state based on the large-N treatment of the Kondo lattice Hamiltonian added with RKKY interaction. With the mixed wave ground state we can explain several puzzling experiments in magnetic HF compounds such as a small value of local moment, coexistence of the antiferromagnetic (AFM) and the paramagnetic (PM) phases, local quantum criticality, etc.