• 한국초전도ㆍ저온공학회논문지
• /
• 제19권2호
• /
• pp.29-32
• /
• 2017

The use of electronic devices such as mobile phones and tablet PCs has increased of late. However, the power which is supplied through wires has a limitation of the free use of devices and portability. Magnetic-resonance wireless power transfer (WPT) can achieve increased transfer distance and efficiency compared to the existing electromagnetic inductive coupling. A superconducting coil can be applied to increase the efficiency and distance of magnetic-resonance WPT. As superconducting coils have lower resistance than copper coils, they can increase the quality factor (Q-factor) and can overcome the limitations of magnetic-resonance WPT. In this study, copper coils were made from ordinary copper under the same condition as the superconducting coils for a comparison experiment. Superconducting coils use liquid nitrogen to keep the critical temperature. As there is a difference of medium between liquid nitrogen and air, liquid nitrogen was also used in the normal conductor coil to compare the experiment with under the same condition. It was confirmed that superconducting coils have a lower reflection-coefficient($S_{11}$) than the normal conductor coils.

• 한국자기공명학회논문지
• /
• 제22권4호
• /
• pp.107-114
• /
• 2018

In this exploration, the nuclear magnetic resonance of the $^{207}Pb$ nucleus in $PbWO_4:Mn^{2+}$ and $PbWO_4:Dy^{3+}$ Single Crystals using FT-NMR spectrometer is investigated. The line width of the resonance line for the $^{207}Pb$ nucleus decreases as temperature increases due to motional narrowing. The chemical shift of $^{207}Pb$ NMR spectra also increases as temperature decreases for both crystals. The spinlattice relaxation times $T_1$ of $^{39}K$ nucleus were calculated as a function of temperature (180 K~400 K). The $T_1$ of $^{207}Pb$ nucleus decreases as temperature increases. The dominant relaxation mechanism at the studied temperature range can be deduced as the Raman process, which is the coupling between lattice vibrations and the nuclear spins. This deduction is substantiated by the fact that the nuclear spin-lattice relaxation rate $1/T_1$ of the $^{207}Pb$ nucleus in $PbWO_4:Mn^{2+}$ and $PbWO_4:Dy^{3+}$ single crystal is proportional to $T^2$, or temperature squared. The activation energies for the $^{207}Pb$ nucleus in $PbWO_4:Mn^{2+}$ and $PbWO_4:Dy^{3+}$ single crystals are $E_a=49{\pm}1meV$ and $E_a=47{\pm}2meV$, respectively.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2010년도 하계학술대회 논문집
• /
• pp.405-407
• /
• 2010

Simple equivalent circuit model is developed for wireless energy transfer system via coupled magnetic resonances and practical design method is also provided. Node equations for the resonance system are built with the method expanding transformer's equations and the optimum distances of coils in the system is derived analytically for optimum coupling coefficients for high transfer efficiency. Moreover, to calculate the frequency characteristics for a lossy system the equivalent model is established at an electric design automation tool. The model parameters of the actual system are extracted and the results of modeling are compared with the measurement. Through the developed model, we can understand the principles that the system shows higher efficiency than conventional magnetic coupling systems and impedance matching is important to achieve high efficiency.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2001년도 전력전자학술대회 논문집
• /
• pp.90-93
• /
• 2001

This paper suggests the circuit topology to transfer AC power using a detachable transformer The circuit topology for AC output load through the magnetic coupling and its principle of operation are described. It can decrease the size of detachable transformer by employing the high-frequency magnetic coupling. It is shown in this paper that the efficiency of noncontact energy transfer system can be improved by applying both the full bridge converter with PFC function to the 1st side of its and the series resonance to the 2nd side to minimize the effect of the leakage inductance.

• 한국자기공명학회논문지
• /
• 제12권1호
• /
• pp.14-25
• /
• 2008

To investigate the 3-bond connectivity of human brain metabolites by scalar coupling interaction through 2D-correlation spectroscopy (COSY) techniques using high field NMR spectroscopy. All NMR experiments were performed at 298K on Unity Inova 500 or 600 (Varian Inc.) equipped with a triple resonance probe head with z-shield gradient. Human brain metabolites were prepared with 10% $D_2O$. Two dimensional 2D COSY spectra were acquired with 4096 complex data points in $t_2$ and 128 or 256 increments in $t_1$ dimension. The spectral width was 9615.4 Hz and solvent suppression was achieved using presaturation using low power irradiation of the water resonance during 2s of relaxation delay. NMR data were processed using VNMRJ (Varian Instrument) software and all the chemical shifts were referenced to the methyl resonance of N-acetyl aspartate (NAA) peak at 2.0 ppm. Total 10 metabolites such as N-acetyl aspartate (NAA), creatine (Cr), choline (Cho), glutamine (Gln), glutamate (Glu), myo-inositol (Ins), lactate (Lac), taurine (Tau), ${\gamma}$-aminobutyricacid (GABA), alanine (Ala) were included for major target metabolites. Symmetrical 2D-COSY spectra were successfully acquired. Total 14 COSY cross peaks were observed even though there were parallel/orthogonal noisy peaks induced by water suppression. Except for Cr, all of human brain metabolites produced COSY cross peaks. The spectra of NAA methyl proton at 2.02 ppm and Glu methylene proton ($CH_2(3)$) at 2.11 ppm and Gln methylene proton ($CH_2(3)$) at 2.14 ppm were overlapped in the similar resonance frequency between 2.00 ppm and 2.15 ppm. The present study demonstrated that in vitro 2D-COSY represented the 3-bond connectivity of human brain metabolites by scalar coupling interaction. This study could aid in better understanding the interactions between human brain metabolites in vivo 2D-COSY study. Also it would be helpful to determine the molecular stereochemistry in vivo by using two-dimensional MR spectroscopy.

• 한국자기공명학회논문지
• /
• 제10권1호
• /
• pp.59-73
• /
• 2006

Spin-lattice relaxation pathway of $CH_2$ spin system by two dimensional NOESY sequence has been discussed. Two-dimensional spectra governed by dipolar relaxation mechanism were simulated in term of transfer mode, the generalization of conventionally used magnetization mode in one dimension. The transfer matrix directly related to the Redfield relaxation matrix can be constructed by the multiplet of transfer mode. The observable relaxation transfer modes causes to variation of the off-diagonal signal intensity of phase sensitive NOESY spectra from which variable spectral density can be extracted with simple group theoretical calculation. The variation of the J-coupling peak intensity as a function of the mixing time in 2-D spectra for $n-Undecane-5-^{13}C$ and Bromoacetic $2-^{13}C$ acid has been theoretically traced.

• International journal of advanced smart convergence
• /
• 제1권2호
• /
• pp.16-19
• /
• 2012

A modified 4-coil magnetic resonance wireless power transfer (MRWPT) system is proposed. Four coils based on 2-coil system with additional two matching coils were used in this topology. When Tx-Rx distance is changed, the input impedance is changed. However, it can be adjusted by coil parameters of matching coils to maintain impedance matching for maximum efficiency. The equivalent circuit of MRWPT system was analyzed for both transmission function and optimum coupling coefficient of the matching coils. By using four spiral resonant coils, these design considerations was experimentally verified. The measured data agreed well with the calculated data and the transmission function of the proposed system was more efficient than that of conventional 2-coil system.

• 한국자기공명학회논문지
• /
• 제8권1호
• /
• pp.62-69
• /
• 2004

Bicyclolactones obtained from the Diels-Alder cycloaddition of 3,5-dibromo-2-pyrone can undergo various palladium catalyzed cross coupling reactions to afford aryl bicyclolactones. The resulting coupled products can be readily converted into various 3-OH cyclohexenes via lactone ring openings, while those bearing dienyl units underwent highly diastereoselective Diels-Alder cycloadditions with selected dienophiles to funish multiply functionalized polycarbocycles. Bromo-bicyclic diene furnished two different diastereomers endo-form (62%) and exo-form (38%) upon cycloadditions with N-Et maleimide (NEM), and their stereochemistries were identified with NMR.

• 한국자기학회지
• /
• 제25권4호
• /
• pp.117-122
• /
• 2015

고감도 바이오센서용 거대자기저항-스핀밸브(Giant magnetoresistance-spin valve; GMR-SV) 박막소자의 미세패턴 공정으로 인한 교환결합력과 보자력 약화 문제를 해결하고자 전자사이크로트론 공명(Electron Cyclotron Resonance) Ar-이온 밀링을 이용하여 GMR-SV 박막에 지름 $35{\mu}m$인 원형 모양의 홀(Hole)을 패턴닝 하였다. GMR-SV를 4-단자법으로 측정한 자기저항 곡선으로부터 홀 개수가 많아질수록 자기저항비와 자장감응도는 홀이 없을 때 측정된 초기값과 같은 값을 유지하였고, 교환결합세기와 보자력은 120 Oe에서 190 Oe, 10 Oe에서 41 Oe로 크게 향상되었다. 이러한 현상은 GMR-SV 박막내의 자화용이축과 같은 방향을 띄고 센싱 전류의 방향과 수직인 공간에 위치하는 용이 자구영역(Easy magnetic domain; EMD)의 역할에 기인하는 결과를 보여주었다. GMR-SV 바이오 소자 제작시 폭을 넓게 하고 소자내부에 홀의 개수를 증가시켜 발생하는 EMD 효과가 자기저항특성을 향상시킬 수 있었다.

• Bulletin of the Korean Chemical Society
• /
• 제29권6호
• /
• pp.1233-1242
• /
• 2008

The hydration effect on the intrinsic magnetism of natural salmon double-strand DNA was explored using electron magnetic resonance (EMR) spectroscopy and superconducting quantum interference device (SQUID) magnetic measurements. We learned from this study that the magnetic properties of DNA are roughly classified into two distinct groups depending on their water content: One group is of higher water content in the range of 2.6-24 water molecules per nucleotide (wpn), where all the EMR parameters and SQUID susceptibilities are dominated by spin species experiencing quasi one-dimensional diffusive motion and are independent of the water content. The other group is of lower water content in the range of 1.4-0.5 wpn. In this group, the magnetic properties are most probably dominated by cyclotron motion of spin species along the helical π -way, which is possible when the momentum scattering time (${\tau}_k$) is long enough not only to satisfy the cyclotron resonance condition (${\omega}_c{\tau}_k$ > 1) but also to induce a constructive interference between the neighboring double helices. The same effect is reflected in the S-shaped magnetization-magnetic field strength (M-H) curves superimposed with the linear background obtained by SQUID measurements, which leads to larger susceptibilities at 1000 G when compared with the values at 10,000 G. In particular, we propose that the spin-orbital coupling and Faraday's mutual inductive effect can be utilized to interpret the dimensional crossover of spin motions from quasi 1D in the hydrate state to 3D in the dry state of dsDNA.