• Title/Summary/Keyword: Magnesium sulfate

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Foliar Nutrients Status of Pinus thunbergii Influenced by Chronic Air Pollution in Yochon Industrial Complex in Korea (여천산업단지(麗川産業團地)의 만성(慢性) 대기오염(大氣汚染)에 의한 해송(海松) 엽중(葉中) 무기양료(無機養料)의 변화(變化))

  • Kim, Joon Sun
    • Journal of Korean Society of Forest Science
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    • v.88 no.3
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    • pp.335-341
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    • 1999
  • To investigate the effect of sulfate deposition un forest tree nutrition, 15 forest stands of Pinus thunbergii were selected throughout Yochon industrial complex, in which is influenced by chronic air pollution. Concentrations of sulfate sulfur, nitrogen, phosphorus, potassium, calcium, and magnesium were analysed fur current and 1-year-old needles of Pinus thunbergii tree. The results obtained were as follows ; 1. Significant higher accumulation of sulfate S, computed with that of unpolluted needles, was observed at all sites, ranging front 0.11% to 0.35% in current needles, and from 0.13% to 0.32% in 1-year-old needles. 2. Ranging from 0.60% to 1.42% in current needles, and from 0.58% to 0.88% 1-year-old needles, respectively, nitrogen concentrations were significantly lower at 7 sites for current needles, and at all sites for 1-year-old needles than at unpolluted site. 3. Phosphorus and potassium levels were significantly lower at very few sites, compared with unpolluted site. 4. Calcium concentrations were significantly lower at 8 sites and 9 sites for current and 1-year old needles than at unpolluted site, ranging from 0.123% to 0.352% and from 0.201% to 0.371% in 1-year old needles, respectively. 5. Ranking from 0.077% to 0.152% in current needles, and from 0.056% to 0.105% in 1-year-old needles, magnesium concentrations were lower at only 2 sites for current needles tut at 12 sites for 1-year-old needles. 6. There were significant declines of concentrations of calcium and magnesium in current needles as sulfate accumulation increased. For 1-year-old needles, there were significant negative correlations-hips between sulfate and nitrogen, potassium, calcium, and magnesium concentration. It is concluded that deposition of sulfuric air pollutant deteriorated nutrients status, resulting in tree decline, in Pinus thunbergii forest in Yochon industrial complex.

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Synthesis and Characteristics of Magnesium Hydroxide Group Flame Retardant for Polymer Addtives (고분자 첨가제인 난연제로서의 수산화마그네슘계 물질의 합성과 특성)

  • Lee, Dong-Kyu;Kang, Kuk-Hyoun;Lee, Jin-Hwa
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.4
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    • pp.385-393
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    • 2009
  • Different types magnesium hydroxide groups have been obtained using the hydrothermal precipitation technique from magnesium sulfate and calcium carbonate solution. The Mg atom coordinated around O atom of ${SO_4}^{2-}$ in another layer to form a multi-layer structure crystal. The influence of synthesis parameters on the morphological characteristics and size of magnesium hydroxide groups precipitated in aqueous were investigated such as different of additive and pH. Magnesium hydroxide groups were decomposed gradually and converted finally to MgO particles after heated in air temperature up to $1050^{\circ}C$. The particle size and it's distribution morphology, crystal phase and thermal behavior of the samples were characterized through XRD, SEM, EDS, and TG/DTA.

Effect of MgO and NH4OH on Formation of 5Mg(OH)2·MgSO4·3H2O Whiskers (침상형 5Mg(OH)2·MgSO4·3H2O 형성에 관한 MgO와 NH4OH 영향)

  • Yu, Ri;Pee, Jae-Hwan;Kim, Hyung-Tae;Kim, Kyung-Ja;Kim, Young-Woong;Kim, Woong;Kim, Yoo-Jin
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.283-289
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    • 2011
  • Magnesium hydroxide sulfate hydrate whiskers ($5Mg(OH)_2{\cdot}MgSO_4{\cdot}3H_2O$, abbreviated 513 MHSH) were prepared using hydrothermal reaction with magnesium oxide (MgO) and magnesium sulfate ($MgSO_4{\cdot}7H_2O$) as the starting materials. The effects of the molar ratio of $MgSO_4$/MgO and amount of $NH_4OH$ were studied. As a result, 513 MHSH whiskers co-existed with hexagonal plate $Mg(OH)_2$ at low concentration of $SO_4^{2-}$. The molar ratio of $MgSO_4{\cdot}7H_2O$/MgO was 7:1, uniform 513 MHSH whiskers were formed without impurity such as $Mg(OH)_2$. Appropriate amount of $NH_4OH$ has affected to formation of high quality MHSH. Their morphologies and structures were determined by powder X-ray diffraction (XRD) scanning electron microscopy (SEM) and thermo-gravimetric analyzer (TGA).

Pain alleviation in patients undergoing cardiac surgery; presternal local anesthetic and magnesium infiltration versus conventional intravenous analgesia: a randomized double-blind study

  • Kamel, Emad Zarief;Abd-Elshafy, Sayed Kaoud;Sayed, Jehan Ahmed;Mostafa, Mohammed Mahmoud;Seddik, Mohamed Ismail
    • The Korean Journal of Pain
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    • v.31 no.2
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    • pp.93-101
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    • 2018
  • Background: Magnesium is one of the effective, safe local anesthetic adjuvants that can exert an analgesic effect in conditions presenting acute and chronic post-sternotomy pain. We studied the efficacy of continuous infusion of presternal magnesium sulfate with bupivacaine for pain relief following cardiac surgery. Methods: Ninety adult patients undergoing valve replacement cardiac surgery randomly allocated into three groups. In all patients; a presternal catheter was placed for continuous infusion of either 0.125% bupivacaine and 5% magnesium sulfate (3 ml/h for 48 hours) in group 1, or 0.125% bupivacaine only in the same rate in group 2, versus conventional intravenous paracetamol and ketorolac in group 3. Rescue analgesia was iv $25{\mu}g$ fentanyl. Postoperative Visual Analog Scale (VAS) and fentanyl consumption during the early two postoperative days were assessed. All patients were followed up over two months for occurrence of chronic post-sternotomy pain. Results: VAS values showed high significant differences during the first 48 hours with the least pain scale in group 1 and significantly least fentanyl consumption ($30.8{\pm}7{\mu}g$ in group 1 vs. $69{\pm}18{\mu}g$ in group 2, and $162{\pm}3$ in group 3 respectively). The incidence of chronic pain has not differed between the three groups although it was more pronounced in group 3. Conclusions: Continuous presternal bupivacaine and magnesium infusion resulted in better postoperative analgesia than both presternal bupivacaine alone or conventional analgesic groups.

Effects of Magnesium on Sulfate Resistance of Alkali-activated Materials (알칼리 활성화 결합재의 황산염 침식에 미치는 마그네슘의 영향)

  • Park, Kwang-Min;Cho, Young-Keun;Ra, Jung-Min;Kim, Hyung-Suk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.109-116
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    • 2017
  • This paper describes the investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0). The tests involved immersions into 10% sodium sulfate solution($Na_2SO_4$), 10% magnesium sulfate solution($MgSO_4$), 10% magnesium nitrate solution($Mg(NO_3)_2$) and 5% magnesium nitrate($Mg(NO_3)_2$+5% sodium sulfate solution+$Na_2SO_4$). The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, in case of immersed in $Na_2SO_4$, $Mg(NO_3)_2$ and $Mg(NO_3)_2+Na_2SO_4$ shows increase in long-term strength. However, for samples immersed in $MgSO_4$, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$) and brucite(MgOH). The results showed that, an additional condition $Mg^{2+}$ in which ${SO_4}^{2-}$ is the presence of a certain concentration, sulfate erosion has to be accelerated.

Effects of Grain Size Distribution in Soil on the Strength Characteristics of Lime-Soil Mixtures (흙의 粒度分捕가 石灰混合土의 强度特性에 미치는 影響)

  • Cho, Seong-Jeong;Kang, Yea-Mook
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.27 no.2
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    • pp.57-71
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    • 1985
  • The characteristics of compaction and unconfined compressive strength were investigated by mixing with lime to all soils adjusted by given percentages of two kinds of clays to sand to obtain the most effective distribution of grain size and the optimum lime content for soil stabilization. In addition, unconfined compressive strength and durability tested by adding of sodium metasilicate, sodium sulfate, sodium carbonate, sodium gydroxide and magnesium oxide to lime-soil mixture mixed with 8 percent lime to adjusted soil having the mixing percentage of 60 percent of cohesive black clay and 40 percent of sand by weight to get the effect and the optimum content of chemicals. The results obtained were as follows; 1.With the addition of more lime, the optimum moisture content was increased, and the maximum dry density was decreased, whereas the more the amount of clay and the less was the maximum drt density. 2. In the soil having more fine grain size the unconfined compressive strength was larger in the earlier stage of curing period, in accordance with the longer period, the mixing percentages of sand to clay showing the maximum unconfined compressive strength, on the basis of 28-day strength, were 60% : 40% (black clay) and 40% : 60% (brown clay) respectively. 3. The reason why the soil adjusted with black clay was remarkably bigger in the unconfined compressive strength than ones adjusted with brown clay for all specimen of lime-soil mixture was the difference in the kind of clay, the amount of chemical compositions the value of pH. Black clay was mainly composed of halloysite that reacted with lime satisfactorily, whereas the main composition of brown clay was kaolinite that was less effect in the enhance of unconfined compressive strength. Also the difference of unconfined compressive strength was because black clay was larger in the amount of composition of calcium oxide and magnesium oxide in the value of pH affecting directly on the unconfined compressive strength of lime-soil mixture than brown clay. 4. In the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40%, on the standard of 7-day strength, the effect of chemical was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium hydroxide and sodium metasilicate. 5. The optimum amount of chemical being applicable to the maximum unconfined compressive strength of lime-chemical-soil mixture was 1 percent by weight for air dry soil in the case of adding sodium carbonated and 0.75 percent on sodium hydroxide, the unconfined compressive strength was increased continuously with increase of the amount of chemical up to 2 percent of chemical content is the lime-chemical-soil mixture added sodium metasilicate, sodium sulfate and magnesium oxide. 6. It was considered that the chemical played and accelerant role of early revelation of strength because the rate of increase of unconfined compressive strength of all of lime-chemical-soil mixtures was largest on the 7-day cured specimen. 7. The effect of test on freezing and thawing after adding suitable amount of chemical on the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40% was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium metasilicate and sodium hydroxide.

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Assessment on the Seawater Attack Resistance of Antiwashout Underwater Concrete (수중불분리성 콘크리트의 해수침식에 대한저항성 평가)

  • 문한영;김성수;안태송;이승태;김종필
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.683-688
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    • 2001
  • In case of constructing the concrete structures under seawater environment, the concrete suffers from deterioration due to penetration of various ions such as chloride, sulfate and magnesium in seawater. Tn the present study, Immersion tests with artificial seawater were carried out to investigate the resistance to seawater attack of antiwashout underwater concrete. From the results of compressive strength, it was found that blended cement concrete due to mineral admixtures such as fly ash(FA) and ground granulated blast-furnace slag(SGC), were superior to ordinary portland cement concrete with respect to the resistance to seawater attack. Moreover, XRD analysis indicated that the formed reactants of ordinary portland cement paste by sulfate and magnesium ions led to the deterioration of concrete. As expected, however, the blended cements with FA or SGC have a good resistance to seawater attack. This paper would discuss the mechanism of seawater deterioration and benefical effects of antiwashout underwater concretes with mineral admixtures.

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Effect of Magnesium Sulfate on Product Inhibition of Sisomicin Production

  • Shin, Chul-Soo;Han, Sang-Hun
    • Journal of Microbiology and Biotechnology
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    • v.5 no.2
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    • pp.96-99
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    • 1995
  • Addition of l00mM $MgSO_4$ to a cell culture after 54 hours resulted in a 2.4-fold increase in the sisomicin titre compared to a control to which no $MgSO_4$ was added, and a considerable amount of intracellular sisomicin was liberated outside the cells. The occurrence of product inhibition in fermentation was confirmed by a reduction in net sisomicin production with increasing amounts of added sisomicin without addition of $MgSO_4$. All added sisomicin was bound to sisomicin-free cells in the absence of $MgSO_4$, whereas approximately 40% of added sisomicin was bound with the addition of l00mM $MgSO_4$. Under conditions of no enzmye synthesis, maintained by adding chloramphenicol to exclude product repression, sisomicin was produced in the presence of 100 mM $MgSO_4$ but little sisomicin was produced in the absence of $MgSO_4$.

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Sulfate Attack on the Cation Type Accompanying $SO_4^{2-}$ (황산이온과 결합하는 양이온의 종류에 따른 황산염침식)

  • Moon, Han-Young;Kim, Seong-Soo;Jung, Ho-Seop;Lee, Seung-Tae;Kim, Jong-Pil;Koh, Joon-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.221-224
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    • 2006
  • This paper reports a study carried out to investigate sulfate attack caused by cation type(sodium, magnesium) accompanying $SO_4^{2-}$ ions in sulfate solutions. The sulfate attack of mortar specimens was evaluate using the visual appearance, compressive strength loss and expansion. In addition, at the end of 360 days, the products of sulfate attack and the mechanism of attack were investigated through x-ray diffraction.

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A Study on Degradation Rate of Carbofuran in Sterilized Soil and Sulfate-added Paddy Soil (Carbofuran의 담수토양중(湛水土壤中) 분해(分解)에 대한 토양(土壤)의 멸균(滅菌)과 황산염(黃酸鹽) 첨가(添加)의 영향(影響)에 관(關)한 연구(硏究))

  • Tu, Ock-Ju
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.11-15
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    • 1998
  • Carbofuran was incubated for four weeks in five types of paddy soil samples at $25^{\circ}C$. The soil samples prepared in the study were as follows : control soil, sterilized soil, 10% cellulose added soil, 10% cellulose and 1% ferrous sulfate added soil, and 10% cellulose and 1% magnesium sulfate added soil. The degradation rate of carbofuran was significantly decreased(p<0.05) in sterilized soil.The degradation rate of carbofuran was significantly decreased by addition of cellulose(p<0.05) in femous sulfate added soil and magnesium sulfate added soil(p<0.01).

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