• 제목/요약/키워드: Magnesium compounds

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Evaluation of Physical, Mechanical Properties and Pollutant Emissions of Wood-Magnesium Laminated Board (WML Board) for Interior Finishing Materials

  • PARK, Hee-Jun;JO, Seok-Un
    • Journal of the Korean Wood Science and Technology
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    • 제48권1호
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    • pp.86-94
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    • 2020
  • This study serves as basic research for the development of a new wood-based building finishing material that improved the weakness of inorganic materials such as gypsum board and magnesium board widely used as interior finishing materials and brought out the strength of the wood. The results of evaluating the physical and mechanical properties and the environmental effect related to hazardous substance discharge having manufactured a wood-magnesium laminated composite are as follows. The thermal conductivity and thermal resistance of WML board was improved by about 28~109 percent over magnesium board due to the low thermal conductivity of wood. The adhesive strength of WML board showed a similar result to that of plywood as it exceeds 0.7N/㎟, the adhesive standard of wood veneer which is presented by KS F 3101. Bending strength and screw holding strength were more improved by manufacturing WML board than magnesium board. The WML board manufactured in this study satisfied the criteria for emissions of hazardous substances prescribed in the Indoor Air Quality Control Act, and confirmed the possibility of development as a new wood-based composite material that can replace existing inorganic materials.

멜라민이 코팅된 수산화마그네슘 입자의 제조와 그 복합입자의 난연특성 (Preparation of Mg(OH)2-Melamine Core-Shell Particle and Its Flame Retardant Property)

  • 임형미;윤준호;정상옥;이동진;이승호
    • 한국재료학회지
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    • 제20권12호
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    • pp.691-698
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    • 2010
  • Magnesium hydroxide-melamine core-shell particles were prepared through the coating of melamine monomer on the surface of magnesium hydroxide in the presence of phosphoric acid. The melamine monomer was dissolved in hot water but recrystallized on the surface of magnesium hydroxide by quenching to room temperature in the presence of phosphoric acid. The core-shell particle was applied to low-density polyethylene/ ethylene vinyl acetate (LDPE/EVA) resin by melt-compounding at $180^{\circ}C$ as flame retardant. The effect of magnesium hydroxide and melamine content has been studied on the flame retardancy of the core-shell particles in LDPE/EVA resin according to the preparation process and purity of magnesium hydroxide. Magnesium hydroxide prepared with sodium hydroxide rather than with ammonia solution revealed higher flame retardancy in core-shell particles with LDPE/EVA resin. At 50 wt% loading of flame retardant, core-shell particles revealed higher flame retardancy compared to that of the exclusive magnesium hydroxide in LDPE/EVA composite, and it was possible to satisfy the V0 grade in the UL-94 vertical test. The synergistic flame retardant effect of magnesium hydroxide and melamine core-shell particles was explained as being due to the endothermic decomposition of magnesium hydroxide and melamine, which was followed by the evolution of water from the magnesium hydroxide and porous char formation due to reactive nitrogen compounds, and carbon dioxide generated from melamine.

도자기 소지구성 산화철, 산화마그네슘이 유약과의 반응 (Reaction Iron Oxide and Magnesium Oxide in Ceramics Body with Glaze)

  • 정석;황동하;이병하
    • 한국재료학회지
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    • 제24권7호
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    • pp.363-369
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    • 2014
  • This is the study on diffusion of ceramic body oxide compounds to glaze. For ceramic bodies, no ferrous oxides contain white ware, celadon, and 3 wt% iron oxides contained white ware was used in this experiment. These ceramic bodies were glazed by transparency glaze, iron oxides contained glaze, and glaze made by pine tree ash that treated in 1240 degree, under reduction condition for an hour. An electron probe microanalyzer(EPMA) was used to study diffusion of oxides and to calculate distance of ceramics bodies. As a result, only iron oxide and magnesium oxide from the body diffused to glaze, and also made a band which shown very thin layer of iron oxide and magnesium oxide between the body and glaze. The densest band of iron oxide formed 100 to $150{\mu}m$ in the glaze, and the densest band of magnesium oxide was found 50 to $100{\mu}m$ in the glaze. Therefore, it could be concluded that iron oxide in the body is diffused to the glaze and it affects the color of glaze, even though iron oxide exists in the glaze. Furthermore, the thickness of the glaze has an effect on the color of celadon.

복합 황산염 수화물의 열분해에 의한 Mg-Al 스피넬의 생성반응 (Reaction Processes of the Formation of Mg-Al Spinel by a Thermal Decomposition of a Mixed Sulfate Hydrate)

  • 박홍채;오기동
    • 한국세라믹학회지
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    • 제23권6호
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    • pp.71-75
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    • 1986
  • The forming reaction processes of magnesium aluminate spinel by a thermal decomposition of sulfate hydrate were studied with DTA, TG. SEM and X-ray powder diffraction methods. The hydrous salt composed of the mixture of the two compounds of $MgSO_4$ $6H_2O$ and ${AL_2}({SO_4})_17H_2O_3$ in which both sulfates were crystalline. On heating the hydrous slat the crystalline magnesium and aluminum sulfate anhydride to amorphous alumina magnesium sulfate anhydride decomposed to amorphous magnesia and these amorphous oxides reacted completely each other to form a spinel at $1000^{\circ}C$ The apparent activation energy of forming reaction of spinel was 36.5 kcal/mole($900^{\circ}C$~$1000^{\circ}C$) The crystallite size of spinel obtained at $1000^{\circ}C$ after 1 h was 380$\AA$.

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Mechanism and regulation of body malodor generation (2) -Development of a novel deodorant powder and application as an antiperspirant-

  • Miyazaki, M.;Fujihira, K.;Sadaie, M.;Nishikawa, N.;Kon, R.;Sugiyama, K.
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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    • pp.110-116
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    • 2003
  • We have developed a high performance powder, which has a quenching efficacy not only for short-chain fatty acids and amines, but also for vinyl ketones (l-octen-3-one, cis-l,5-octadien-3-one), newly found as other key compounds in axillary malodor. By investigating various powders known to have a quenching efficacy, we finally developed a highly porous silica bead containing magnesium oxide. We found that the superior deodorant effect performed by this powder was the result of multiple effects due to both an excellent physical adsorption capability from its high porosity and a specific adsorption of vinyl ketones by magnesium in the powder. An antiperspirant formulation containing both this powder and a Morus alba extract showed good efficacy as a deodorant.

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Influence of Mechanical Activation on Synthesis of Compounds in B/C-Mg/Al/Ca System

  • Urakaev, F.Kh
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
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    • pp.60-65
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    • 2004
  • The possibility of mechano-chemical synthesis and influence of mechanical activation on thermal synthesis of borides and boron carbides of mass-low metals is investigated. The opportunity of mechanochemical synthesis in the mill AGO-2 of such compounds as Al $B_2$and Ca $C_2$ $B_2$is established. Influence of mechanical activation in the mill SPEX 8000 on synthesis of such compound as $Mg_{0.5}$A $l_{0.5}$ $B_2$is shown. Features of synthesis in systems containing metal magnesium are considered.d.d.

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Aeromonas caviae에 의한 Sodium Dodecyl, Benzene Sulfonate 의 분해조건 (Identification of Aeromonas caviae and the Activity Test for Biodegradation of Sodium Dodecyl Benzene Sulfonate)

  • 권오근;금두희
    • 환경위생공학
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    • 제8권1호
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    • pp.81-91
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    • 1993
  • This paper was carried out to isolate and identify Aeromonas caviae which can degrade Sodium Dodecyl Benzene Sulfonate(SDBS) effectively. And the affecting factors for the ability of bacterial degradation were also studied. Frm October 1991 to February 1992, two hundred samples from sweage in Taegu area and Nakdong river waters in Talsung Gun area were tested. Minimal salt medium which contain SDBS only as a carbon source was used as a culture medium. The isolated new strain was identified as Aeromonas caviae Kim & Kweon. The optimal pH for SDBS degradation were 7.0 and temperature, $32^{\circ}C.$ It was taken 24 hours to degrade SDBS of 20mg/l completely under the optimal pH and temperature. And in the case of 30 mg/l of SDBS, it was taken 36 hours. The nitrogen sources were added to the minimal salt media containing 20mg/l of SDBS, and they were incubated at $32^{\circ}C$ for 14 hours. 86.9% SDBS were degraded after addition of 0.03% peptone as a organic nitrogen source. And 70.5% SDBS after addition of 0.05% ammonium sulfate as a inorganic nitrogen source. In the case of metal compounds(0.015%), the degradation rate for SDBS were 3.5 fold increased in the media containing magnesium chloride and calcium chloride than in the media that were not containing these metal compounds. And where the media containing magnesium chloride was 0.05%, the degradation rate was 65.8%. And above 0.3% NaCI, the degradation rate was decreased slowly.

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Fundamental Structure in Simultaneous Removal for Phytoplankton and Nutrient Salt in Lakes

  • SEKI, Tatsuhiro;ISHII, Yuuichi;ISHII, Toshio;TAKI, Kazuo
    • Environmental Engineering Research
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    • 제14권4호
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    • pp.220-225
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    • 2009
  • The water quality in eutrophic lakes is affected by serious problems, such as abnormal increasing of Cyanobacteria. The purpose of this study was to investigate the possibility of a modified flotation system using a hybrid technique formed by chemical compounds and an electrostatic bridge. Therefore, experiments using the hybrid technique were performed to measure the zeta potential value on the phytoplankton surface and the removal efficiencies of phytoplankton, ammonia nitrogen, nitrate nitrogen and phosphoric acid. The results were as follows: Firstly, the zeta potential of M.aeruginosa was observed to approach charge neutralization due to adhesion of magnesium hydroxide precipitate on the phytoplankton surface in the pH range 10.5 to 11. Secondly, the concentration of chlorophyll-a decreased from about 150 to 20${\mu}g$g/L, with a maximum removal efficiency of 84% due to coagulation with pH values higher than 10. Thirdly, the N$H_4$-N concentration was observed to decrease from 0.62 to 0.54mg-N/L (13%), and the P$O_4$-P concentration, which is a limiting factor to the formation of algae blooms, decreased from 0.27 to 0.02mg-P/L (92%). These findings suggest that the modified flotation system can be applied for the purification of the raw water of numerous lakes containing high phytoplankton populations and elevated pH.

함수(含水) 염화(鹽化)마그네슘의 탈수(脫水) 특성(特性) 고찰(考察) (Dehydration characteristics of Magnesium Chloride Hydrate)

  • 엄형춘;윤호성;박형규;김철주
    • 자원리싸이클링
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    • 제16권5호
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    • pp.8-12
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    • 2007
  • 마그네슘 용융염전해의 원료물질로 무수염화마그네슘이 일반적으로 사용된다. 그러나 함수염화마그네슘으로부터 무수염화마그네슘을 제조하기 위한 탈수과정은 가수분해가 동반되어 마그네슘 산화물들이 생성되므로, 공기 중에서 탈수를 통한 무수염화마그네슘 제조는 어렵다. 본 연구에서는 공기중에서와 염화수소 분위기 하에서 탈수 온도($200{\sim}600^{\circ}C$)에 따른 탈수특성을 비교하였다. 공기중에서는 탈수온도가 증가함에 따라 MgOHCl과 MgO가 생성되었지만, 염화수소 분위기하에서는 $300^{\circ}C$ 이상에서 무수염화마그네슘이 생성되었다. 염화수소 분위기에서 무수염화마그네슘은 약 $300^{\circ}C$에서 생성되기 시작하여 $500^{\circ}C$에서 결정화가 완전히 이루어지는 것을 확인하였다. 탈수실험에 사용된 염화수소는 모두 물에 용해시켜 염산으로 회수되었으며, 수용액 온도 $20^{\circ}C$에서 최대 41%의 염산을 회수할 수 있었다.

전선피복용 컴파운드의 제조에서 난연제의 첨가량에 따른 물성 변화 연구 (Study on Property Modification with Fire Retardant Content in the Manufacture of Compounds for Cable Sheath)

  • 리시앙수;이상봉;조을룡
    • 반도체디스플레이기술학회지
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    • 제18권3호
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    • pp.47-51
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    • 2019
  • The three different polymer compounds were manufactured with the three different fire retardant (silane coated magnesium dihydroxide) contents, 180, 200, 220 phr, for making cable sheath for ship industry. In the research, ethylene-vinylacetate, polyethylene as matrix polymers and ethylene-vinylacetate grafted maleic anhydride as coupling agent were selected for compounding with fire retardant, closslinking agent, plasticizer, and other additives. In the evaluation. ΔT, Mooney viscosity, and tensile strength increased with the content of fire retardant. But it was found that too much fire retardant damaged aging resistance and cold resistance of the polymer compound.