• Journal of the Korean Ceramic Society
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• v.20 no.2
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• pp.99-106
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• 1983

This experiment has been carried out for the purpose of investigating the effect of $Ga_2O_3$ and $GeO_2$ additivies on sintering of magnesium oxide over the temperature range of 130$0^{\circ}C$~150$0^{\circ}C$. The effect of calcining temperature on the bulk densities of fired compacts prepared from this material was observed MgO powder has been obtained by calcining extra reagent grade magnesium carbonate(basic fired) at 90$0^{\circ}C$ for 30 minutes $Ga_2O_3$and GeO2 were added in the ratio of 1, 2, and 3 wt% to MgO and mixed with calcined MgO. The specimens were prepared by compression with pressure of $700kg/cm^2$ than fired at 130$0^{\circ}C$~150$0^{\circ}C$ for 0-5hrs. Sintering behaviour and microstructure of the fired specimens were examined. The optimum calcination temperature of magnesium carbonate was 90$0^{\circ}C$. Densification rates obeyed the equation D=K in t+c. Theoretical density in the case of addition of $Ga_2O_3$ was 23.1 kcal/mole in the case of the additive $GeO_2$ was 14.176kcal/mole. This low value would appear to support a machanism of grain boundatry diffusion The range of average grain size in the case of addition of $Ga_2O_3$ and $GeO_2$ was 21$\mu\textrm{m}$-31$\mu\textrm{m}$.

• Bulletin of the Korean Chemical Society
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• v.24 no.10
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• pp.1437-1443
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• 2003

Thermal decomposition of hydrated surface layer of $Mg(OH)_2$ at $500^{\circ}C$ in vacuum turned non-porous MgO into porous one with high surface area of around $270 m^2$/g. Most of its surface area, 74 %, was from micropores, and rest of it was from mesopores in wedge-shaped slits, exhibiting bimodal size distribution centered around 30 and 90${\AA}$. Rehydration followed by subsequent dehydration at $300 ^{\circ}C$ in dynamic vacuum further raised the surface area to 340 $m^2$/g. Fraction of microporous surface area was increased to 93%, and the shape of the mesopores was modified into parallel slits with a specific dimension of 32 ${\AA}$. Application of $Fe_2O_3$ over MgO via iron complex formation did not alter the pore characteristics of MgO core, except slightly increased pore dimension. Over the course of the modification, $Fe_2O_3$ stayed on the surface possibly via spill-over reaction.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.1
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• pp.888-894
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• 2015

Inorganic composite particles have excellent physical and chemical characteristics and have been applied in various industries. Recently, many studies have examined the optical properties, such as light scattering, refraction, transmission characteristics, by coating organic-inorganic materials on a substrate, such as mica. Mica is widely applied as a pigment, plastics, painted products, and ceramics because of its high chemical stability, durability and non-toxicity. Magnesium oxide has a range of properties, such as high light transmittance, corrosion resistance and non-toxicity, and it is used as an optical material and polymer additives. To use the optical properties of mica and magnesium oxide, mica was coated with magnesium hydroxide by a dissolution and recrystallization process. In this study, the optimal conditions for the haze value of the particles were found by adjusting the amount of precursors and pH. Magnesium hydroxide layers were formed on the surfaces of mica and converted to MgO after calcination at $400^{\circ}C$ for 4 h. The results showed that the value of MgO-coated mica haze can be controlled easily by the amount of the magnesium hydroxide and pH. The optical properties of the inorganic composite powder were analyzed using a hazemeter and the highest haze value was 85.92 % at pH 9. The physicochemical properties of the synthesized composite was analyzed by SEM, XRD, EDS, and PSA.

• Corrosion Science and Technology
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• v.17 no.3
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• pp.91-100
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• 2018

Development of biodegradable implants for treatment of complex bone fractures has recently become one of the priority areas in biomedical materials research. Multifunctional corrosion resistant and bioactive coatings containing hydroxyapatite $Ca_{10}(PO_4)_6(OH)_2$ and magnesium oxide MgO were obtained on Mg-Mn-Ce magnesium alloy by plasma electrolytic oxidation. The phase and elemental composition, morphology, and anticorrosion properties of the coatings were investigated by scanning electron microscopy, energy dispersive spectroscopy, potentiodynamic polarization, and electrochemical impedance spectroscopy. The PEO-layers were post-treated using superdispersed polytetrafluoroethylene powder. The duplex treatment considerably reduced the corrosion rate (>4 orders of magnitude) of the magnesium alloy. The use of composite coatings in inducing bioactivity and controlling the corrosion degradation of resorbable Mg implants are considered promising. We also applied the plasma electrolytic oxidation method for the formation of the composite bioinert coatings on the titanium nickelide surface in order to improve its electrochemical properties and to change the morphological structure. It was shown that formed coatings significantly reduced the quantity of nickel ions released into the organism.

• Proceedings of the KIEE Conference
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• 1993.11a
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• pp.255-257
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• 1993

MgO(Magnesium Oxide) film was deposited by the Ion Plating method and the characteristics of the MgO films were analyzed by XRD and SEM. The MgO films prepared by Ion Plating were used in AC Plasma Display Panel and breakdown voltage, minimum sustain voltage and memory margin of fabricated panel were investigated.

• Proceedings of the KIEE Conference
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• 1996.11a
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• pp.206-208
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• 1996

Thin films of magnesium oxide(MgO) were deposited on glass substrates by RF magnetron sputtering method. The characteristics of MgO thin films were analyzed as a function of various deposition conditions such as substrate temperature, substrate self-bias, input power and pressure. As the substrate temperature and bias voltage were increased, the grain size of MgO thin film increased. XRD peaks of (111) and (222) direction became dominant, as the substrate bias voltage increases and temperature decreases.

• Korean Journal of Materials Research
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• v.11 no.10
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• pp.851-858
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• 2001

One of the important phase of black titanium oxide is $Ti_4O_7$ which has the excellent properties such as the greatest electrical conductivity among the titanium oxides, chemical resistance against acidic and alkalic conditions and electro-wave absorption etc., so it has been considered as a promising material to be used widely all over the parts of industries. In this study, $Ti_4O_7$ phase was successfully synthesized by the reaction of TiO$_2$/ Mg system. With the change of the mole of TiO$_2$to Mg, the most excellent blackness was appeared in the 3.5 mole which was the smaller amount than the stoichiometric 4.0 mole. In addition, we found that the blackness decreased as the mole ratio of reactent increased. With decreasing particle size of magnesium, blackness of titanium oxide increased. The reaction property was changed with the compaction pressure, and optimum pressure was found to be 10 MPa. At 55$0^{\circ}C$ of reduction temperature, the blackness increased as the reaction time increased. The blackness of synthesized black titanium oxide was 14 to 18, and the average particle size was 0.2 $\mu\textrm{m}$.

• Journal of the Korean institute of surface engineering
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• v.46 no.2
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• pp.80-86
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• 2013

Magnesium alloys of AZ31 containing (0.5, 1, 1.5) wt.% of initially added CaO particles were cast in air, and their oxidation behavior was studied at $450-650^{\circ}C$ in air. The initially added CaO particles either decomposed to dissolve in the ${\alpha}$-Mg matrix or precipitated as $Al_2Ca$ along the grain boundaries of the matrix during casting. The ignition temperatures were $565.4^{\circ}C$ for AZ31, $608.6^{\circ}C$ for AZ31+0.5 wt.%CaO, and $689.7^{\circ}C$ for AZ31+1 wt.%CaO. No ignition occurred for AZ31+1.5 wt.%CaO up to $700^{\circ}C$, displaying good oxidation resistance. The CaO-rich oxide scales that formed on the surface of the AZ31+(0.5, 1, 1.5) wt.%CaO alloys improved the oxidation resistance of AZ31 alloys.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.18-20
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• 2006

The panels were fabricated to characterize the contamination of Magnesium Oxide (MgO) thin films by phosphors and ion bombardments in AC-PDPs. Forty-six inch WVGA panels of the surface and vertical discharge type were manufactured. The experiment was designed to investigate the relationship between the MgO thin films and phosphor contamination caused by ion bombardments in a plasma environment to produce a life time test. The contamination of MgO thin films by phosphors was investigated by way of X-ray photoelectron spectroscopy (XPS).

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.1
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• pp.34-41
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• 2004

The chemical heat pump based on the Dehydration/Hydration process with a MgO/$H_2O$ system has been researched. The reactor bed could be expected to store the heat around 200∼37$0^{\circ}C$ by the dehydration reaction and to release the heat around 100∼16$0^{\circ}C$ by the hydration reaction under the heat amplification mode operation. The heat output rate of the heat pump system was evaluated using the experimentally determined parameters. The results show that 6∼50 W/kg of heat output and 0.5∼0.8 of heat recovery ratio are attainable. The heat pump will be applicable for a load leveling in a co-generation system by chemical storage of surplus heat at low heat demand and by supplying heat in the peak load period.