• Title/Summary/Keyword: Magma

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Behavior of Pt, Sb, Te during Crystallization of Ore Magma (광화마그마에서의 백금, 안티모니, 테루리움 거동에 관한 연구 (II))

  • 김원사
    • Korean Journal of Crystallography
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    • v.9 no.2
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    • pp.153-158
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    • 1998
  • 백금족 원소의 광화 마그마 내에서의 지화학적·결정학적 거동을 밝히기 위하여 백금, 안티모니, 테루리움계를 선택하여 800℃에서 안정한 광물 또는 화합물의 종류와 이들의 공생군, 원소간의 고용한계 등에 대해 실험적으로 연구하였다. 순도가 높은 각 원소를 초기 반응 물질로 하였으며, 고순도 석영관을 용기로 사용하였으며, 화학 반응 생성물은 반사현미경의, X선회절분석기, 전자현미분석기 등을 사용하여 분석하였다. 800℃에서 안정한 화합물로는, 백금(Pt), PtSb(stumpflite), PtSb2(geversite), PtTe, Pt3Te4, Pt2Te3, PtTe2(moncheite)이다. 이 연구 결과로부터 800℃에서의 상평형다이아그램을 정립하였다. 이 온도에서는 stumpflite와 geversite 및 moncheite가 현저히 치환고용체를 이루는데 그 한계는 각각 10 at.% Te, 28.5 at.% Te, 19.5 at.% Sb이다. 특히 원소광물인 백금과 stumpflite 및 moncheite는 화학성분은 이들 광물을 포함하고 있는 광상의 생성온도를 제시해 주는 지질온도계 역할을 할 수 있다.

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Tectonic History of the Tertiary Basins of the Southern Korean Peninsula (한반도 남부의 제3기 분지 발달사)

  • Yoon, Sun;Chang, Ki-Hong;You, Hoan-Su;Lee, Young-Gil
    • Economic and Environmental Geology
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    • v.24 no.3
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    • pp.301-308
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    • 1991
  • Four Tertiary basins are distributed on the eastern coast of the southern Korean Peninsula, that is, Bugpyeong, Yeonghae, Pohang and Yangnam basins from north to south. The Yangnam and Pohang basins are the largest ones and have been well studied on their stratigraphies, paleoenvironments and geologic ages, and their tectonic history is representative on the tectogenesis of the Tertiary basins of the southern Korean Peninsula. The geologic events occurred in the Yangnam and Pohang basins from the Early-Middle Eocene through the Middle Miocene suggest that the Yangnam and Pohang basins resulted from the volcanism and rifting caused by the uprising magma, that is, by the diapiric tectogenesis.

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Evaluation of Microstructure and Formability of Rheocasting Aluminum Alloy by Inclined Cooling Plate (경사냉각판을 이용한 반응고 알루미늄 합금의 미세조직 및 성형성 평가)

  • Hwang, Bum-Kyu;Kim, Soon-Kook;Kim, Duck-Hyun;Lim, Su-Gun
    • Journal of Korea Foundry Society
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    • v.39 no.5
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    • pp.94-101
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    • 2019
  • This study investigated the microstructure properties of A356 and AC8A alloys with a rheocasting mold using an inclined cooling plate. In addition, a formability evaluation was performed according to the solid fraction. Regardless of the position, the overall microstructure was shown to be uniform and a finer crystal structure was obtained as the solid fraction increased. The study confirmed that the molding pattern changed according to the solid fraction and that the spherical α-Al and eutectic α were identified. The results of the formability according to the solid fraction of A356 and AC8A alloys were similar to the simulation results.

A prediction of mold temperature distribution and lifetime with different spray process of mold release agent in high pressure diecasting mold using computer simulation (컴퓨터 시뮬레이션을 이용한 고압다이캐스팅 금형의 이형제 분사공정에 따른 금형온도분포 및 금형수명 예측)

  • Kim, Dong-Hyun;Yoon, Sang-Il;Chang, Dae-Jung
    • Design & Manufacturing
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    • v.13 no.2
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    • pp.49-53
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    • 2019
  • The temperature distribution and lifetime of molds were predicted by computer simulation analysis with various spraying and blowing process of high pressure die casting. After varying the spraying angle and time, the mold temperature, heat exchange and mold life were predicted. As the spraying angle increases, the maximum temperature of the mold decreases, which is because the spraying area increases and the heat exchange with the mold increases. Heat exchange occurs more actively in the blowing process than in the spraying process. This is because the cooling is not performed due to the steam generation. When the spraying angle is 50 degree, the minimum life of the mold is analyzed 200 times. After adjusting the blowing time from 5s to 3s, the minimum lifetime of the mold has been increased almost twice.

A Study on the Roll Manufacturing Technology Applying Powder Flame Spray Coating Technology of Ni-Based Alloy Powder (Ni계 합금분말 용사 코팅기술을 적용한 롤 제조기술 연구)

  • Park, Ji Woong;Kim, Soon Kook;Ban, Gye Bum
    • Journal of Powder Materials
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    • v.29 no.2
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    • pp.123-131
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    • 2022
  • The purpose of this study is to improve the mechanical properties and develop manufacturing technology through self-soluble alloy powder flame spray coating on the surface of a run-out table roller for hot rolling. The roller surface of the run-out table should maintain high hardness at high temperatures and possess high wear, corrosion, and heat resistances. In addition, sufficient bonding strength between the thermal spray coating layer and base material, which would prevent the peel-off of the coating layer, is also an important factor. In this study, the most suitable powder and process for roll manufacturing technology are determined through the initial selection of commercial alloy powder for roll manufacturing, hardness, component analysis, and bond strength analysis of the powder and thermal spray coating layer according to the powder.

Nd, Sr and Noble Gas Isotopic Compositions of Alkali Basaltic Rocks and Mantle Xenoliths in the Baegryongdo (백령도에 분포하는 알칼리 현무암과 맨틀 포획암의 Nd-Sr과 영족기체 동위원소 조성)

  • ;Nagao Keisuke;;Sumino Hirochika
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.523-532
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    • 2002
  • The rare earth elements (REE) and Nd, Sr and noble gas isotopic compositions eHer'He, 4$^{\circ}$Arp6Ar) for the Quaternary alkali basaltic rocks and mantle xenoliths in the basaltic rocks from the Baegryongdo were investigated to decipher the origin of alkali basaltic magma and xenolith beneath the Sino-Korean craton. Analytical results are summarized as follows; (1) The alkali volcanic rocks with voluminous xenoliths which are represented by the Mg-olivine and clinopyroxene dominant spinel-lherzolite in the Baegryongdo consist mainly of the basalt-mugearite and basaltic andesite. (2) The REE pattern of alkali basaltic rocks characterized by high HREE is similar to that of oceanic island basalt (OlB). Relatively concordant REE patterns of the basaltic rocks suggest that the alkali basaltic magma be formed by the identical source materials. (3) The Nd-Sr isotopic data of the alkali basaltic rocks suggest that the alkali basaltic magma be originated from the depleted mantle source with a little contamination of the continental crustal materials. (4) The $^3$He/ $^4$He ratios in olivines of xenoliths ranging from 5.0${\pm}$1.lRa to 6.7${\pm}$1.3Ra are lower than that of MORB (ca. 8.0Ra). It suggest that the xenolith be derived from the subcontinental lithospheric mantle. However, the high $^3$Her'He value of 16.8${\pm}$3.IRa at 1800$^{\circ}$C fraction (sample no OL-7) might be resulted from the post-eruptive cosmogenic $^3$He. The 4OAr/ 36 Ar ratios in olivines of mantle xenoliths are comparable to that of atmospheric argon, and are much lower than that of the MORB type mantle. These facts can lead to conclusion that the olivine of the xenolith in the Baegryongdo is affected by the post-eruptive atmospheric contamination during the slow degassing process.

Petrology of Host Body of Feldspar Deposits in Jechon Ganites (장석광상 모암인 제천반상화강암의 암석학적 특성)

  • Lee, Han-Yeang;Kim, Dai-Oap;Park, Joong-Kwon
    • Journal of the Korean earth science society
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    • v.22 no.5
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    • pp.405-414
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    • 2001
  • Jecheon granite can be divided into two types; porphyritic granite (K-feldspar megacryst bearing) and medium-grained biotite granite. Porphyritic granite, host body of feldspar deposits, is 8${\sim}$11 km in diameter and about 80 $km^{2}$ in area. It mainly contains K-feldspar, plagioclase, biotite and quartz, and magnetite, zircon, sphene and apatite are accessary minerals. Enclosed minerals in K-feldspar megacryst with 3${\sim}$10 cm in diameter are hornblende, plagioclase, quartz, magnetite, apatite, sphene and zircon. Mafic enclaves mainly consisting of hornblende, plagioclase and quartz are frequently observed in porphrytic granite. Medium-grained biotite granite consists of K-feldspar, plagioclase, biotite and hornblende as main, and hematite, muscovite, apatite and zircon as accessary minerals. Core and rim An contents of plagioclase from porphyritic granite, medium biotite granite, K-feldspar megacryst, and mafic enclave are 36 and 21, 40 and 32, 37 and 32, and 43 and 36, respectively. $X_{Fe}$ values of hornblende are 0.57 at biotite granite, 0.51 at K-feldspar mehacryst and 0.45 at mafic enclave. $X_{Fe}$ values of biotite and hornblende are homogeneous without chemical zonation. K-feldspar megacryst shows end member of pure composition with exsolved thin lamellar pure albites. Characteristics of mineral compositions and petrography indicate porphyritic granite is igneous origin and medium-grained biotite granite comes from the same source of magma; biotite granite is initiated to solidly and from residual melt porphyritic granite can be formed. Possibly K-feldspar megacrysts are formde under H$_{2}$O undersaturation condition and near K-feldspar solidus curve temperature; growth rate is faster than nucleation rate. Mafic enclaves are thought to be mingled mafic magma in felsic magma, which is formed from compositional stratigraphy. Estimated equilibrium temperature and pressure for medium-grained biotite granite are about $800^{\circ}C$ and 4.83${\sim}$5.27 Kb, respectively.

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The Formation of the Cenozoic Volcanic Edifice in the Goseong-Ganseong Area, Gangwondo, Korea (강원도 고성-간성일대의 신생대 화산체의 형성과정)

  • Kim, Hwa Sung;Kil, Youngwoo;Lee, Moon Won
    • Journal of the Korean earth science society
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    • v.33 no.7
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    • pp.627-636
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    • 2012
  • In the Obongri-Goseong area of Gangwondo, South Korea, there are six densely distributed volcanic edifices i.e., Duibaejae, Oeumsan, Galmibong, 249 m height, 166 m height, and 102 m height, and two other volcanic edifices including Goseongsan and Unbongsan volcanic edifice that are separately located from a distance. A previously undiscovered 249m volcanic edifice in Obongri was found in this investigation, and the six volcanic edifices distributed in Obongri will be referred to as the Obongri volcanic edifice group. Volcanic edifices in this area were interpreted by other researchers as being volcanic plug, plug dome, and cylindrical volcanic pipe type edifices. The aim of this study is to investigate the aspect of volcanic activity in the Obongri-Goseong area and the formation of volcanic edifices by examining of the shape of volcanic edifices, stratigraphy, and characterization of volcanic products. All the volcanic edifices in the area are composed of basaltic rocks on the Mesozoic granite basement, and the prevalence of the dome shape increased towards the upper part of the mountain. Three volcanic edifices (Duibaejae, 166 m height, 102 m height) include intercalated pyroclastic deposits between the basaltic rocks and the basement. The pyroclastic deposit in the Duibaejae volcanic edifice is composed of quartz, feldspar, granite fragments originated from the basement, and scoria fragments originated from the volcanic eruption. In addition to angular olivine, plagioclase, and pyroxene xenocrysts, all the basaltic rocks contained mantle xenolith, gabbroic xenolith originated from the lower crust, and granitic xenolith originated from the basement. This fact indicates that magma rapidly rose to the surface and that the volcanic activity was explosive. It is also interpreted that, as the basaltic magma became highly viscous due to the large amount of xenocrysts, the erupted magma formed a dome structure on the surface. The original dome structure was then severely eroded out leaving a plug dome formation on the basement.

Study of Crustal Structure in North Korea Using 3D Velocity Tomography (3차원 속도 토모그래피를 이용한 북한지역의 지각구조 연구)

  • So Gu Kim;Jong Woo Shin
    • The Journal of Engineering Geology
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    • v.13 no.3
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    • pp.293-308
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    • 2003
  • New results about the crustal structure down to a depth of 60 km beneath North Korea were obtained using the seismic tomography method. About 1013 P- and S-wave travel times from local earthquakes recorded by the Korean stations and the vicinity were used in the research. All earthquakes were relocated on the basis of an algorithm proposed in this study. Parameterization of the velocity structure is realized with a set of nodes distributed in the study volume according to the ray density. 120 nodes located at four depth levels were used to obtain the resulting P- and S-wave velocity structures. As a result, it is found that P- and S-wave velocity anomalies of the Rangnim Massif at depth of 8 km are high and low, respectively, whereas those of the Pyongnam Basin are low up to 24 km. It indicates that the Rangnim Massif contains Archean-early Lower Proterozoic Massif foldings with many faults and fractures which may be saturated with underground water and/or hot springs. On the other hand, the Pyongyang-Sariwon in the Pyongnam Basin is an intraplatform depression which was filled with sediments for the motion of the Upper Proterozoic, Silurian and Upper Paleozoic, and Lower Mesozoic origin. In particular, the high P- and S-wave velocity anomalies are observed at depth of 8, 16, and 24 km beneath Mt. Backdu, indicating that they may be the shallow conduits of the solidified magma bodies, while the low P-and S-wave velocity anomalies at depth of 38 km must be related with the magma chamber of low velocity bodies with partial melting. We also found the Moho discontinuities beneath the Origin Basin including Sari won to be about 55 km deep, whereas those of Mt. Backdu is found to be about 38 km. The high ratio of P-wave velocity/S-wave velocity at Moho suggests that there must be a partial melting body near the boundary of the crust and mantle. Consequently we may well consider Mt. Backdu as a dormant volcano which is holding the intermediate magma chamber near the Moho discontinuity. This study also brought interesting and important findings that there exist some materials with very high P- and S-wave velocity annomoalies at depth of about 40 km near Mt. Myohyang area at the edge of the Rangnim Massif shield.

Plagioclase Composition of Feldspar Trachybasalt in Jeju Island (제주도 장석 조면현무암의 장석 성분에 대한 연구)

  • Yea, Nam Hee;Yun, Sung-Hyo;Koh, Jeong Seon
    • The Journal of the Petrological Society of Korea
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    • v.21 no.3
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    • pp.309-333
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    • 2012
  • Basalt having lots of feldspar phenocryst occurred at the northern and southern slope of the Mt. Halla, Jejudo. Among them, the Sioreum trachybasalt in southern slope consists of abundant phenocrysts of plagioclase in aphanitic groundmass. And the number of plagioclase grains are about 20 per $10cm^2$, and based on 667 grains the sizes are 13~0.7 mm (average 4.23 mm) in length and 8.6~0.5 mm (average 2.3 mm) in width. In according to modal analyses, Sioreum basaltic rock consists mainly of plagioclase (16~28%), olivine, clinopyroxene (1.5~6%) and opaque minerals (~0.1%) of magnetite and ilmenite as phenocryst and microphenocryst and groundmass (60~82%). The compositions of plagioclase, olivine and clinopyroxene are bytownite~andesine, chrysolite~hyalosiderite, augite respectively. Plagioclase phenocrysts show different type of zoning, namely, normal, reversal, patchy, oscillatory type. The An contents of zoned plagioclase mainly increase from core to rim. Those of oscillatory type from core to rim show variations of increase following decrease or decrease following increase, being more enriched in rim or almost same to core. Under the microscope, some plagioclase phenocrysts are especially melted in core part or marginal part, or found as only the remnant remain which resulted from reaction with melt. Some clinopyroxene are also corroded in margin part or found as irregular shape resulted from melting. The characteristics of petrography and compositional variation from core to rim of plagioclase and clinopyroxene, indicate that they are disequilibrium with melt and has been undergone geological environmental changes in magma batch during crystallization including magma mixing with replenishment of more mafic and high temperature melt.