• The Korean Journal of Ceramics
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• v.5 no.3
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• pp.265-269
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• 1999

Polyethylene was modified with silanol groups on its surface by photografting of vinyltrimethoxysilane in vapor phase by using benzophenon as a polymerization initiator and by hydrolyzing the methoxysilane groups into the silanol groups with HCI solution. The modified polyethylene formed a dense and homogeneous apatite layer on its surface in a solution with ion concentrations 1.5 times those of human blood plasma within 21 days. This kind of biomimetic process could provide techniques for fabricating apatite-polymer composites with three dimensional structure analogous to the natural bone.

• KSBB Journal
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• v.9 no.2
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• pp.98-103
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• 1994

A bed configuration wherein sheets of modified fibrous polyethylene are potted within a Millipore Filter Cartridge matrix has been developed. Polyethylene fibers form sturdy beds but the native hydrophobicity and inertness of polyethylene have precluded their use in protein chromatography The polyethylene fibers used in this system were modified by plasma oxidation and further derivatization. The resulting fibers are hydrophilic, bind protein reversibly and serve as an anion-exchange stationary phase. Separation of Bovine Serum Albumin on this bed, as well as results of basic studies on capacity and reversibility of binding within a fibrous bed and experimental data handling system are shown.

• Journal of the Korean Vacuum Society
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• v.6 no.3
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• pp.200-205
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• 1997

Surface of polyethylene film was modified by ion assisted reaction in which ion beam is irradiated on polymer in reactive gas environments. Ion (argon and oxygen) beam energy was 1 keV, doses were varied from $1{\times}10^{14}$ to $1{\times}10^{17}$ inons/ $\textrm{cm}^2$, and amount of blowing oxygen from 0 to 4 sccm(ml/min). Wettability was measured by water contact angle measurement, and the surface functionality was analyzed by x-ray photoelectron spectroscopy. The contact angles of water to polyethylene modified by oxygen ion beam only decrease from 95 to degrees, and surface energy was not changed much. The contact angles remarkably decrease to 28 degrees and surface energy increase to 67 erg/ $\textrm{cm}^2$ when the films were modified by argon ion with various ion doses with blowing oxygen gases near the polyethylene surface. Improvement of wettability and surface energy are mainly due to the new functional group formation such as C-O or C=O, which are known as hydrophilic groups from the XPS analysis, and the assisted reaction is very effective to attach oxygen atoms to form functional groups on C-C bond chains of polyethylene.

• Fibers and Polymers
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• v.6 no.3
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• pp.200-205
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• 2005

Celite powder surface-modified with cationic surfactant was used to make polyethylene (PE) specialty film that can be contrasted with ordinary film in having high odor storing capacity and long odor lasting period. Mechanical properties of the films were sacrificed as more celite particles were included, whether celite surface was modified or not. The film with CTAS-modified celite showed the best odor storing and lasting properties for five different flavors of odor, three artificial and two natural ones, among the kinds of films developed. Comparisons among the different films are made, together with brief discussion about the reason for differences in odor lasting period and possible application to packaging industry.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.10a
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• pp.403-406
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• 2003

Poyethylene(PE) films could be modified by radiation grafting of N-vinyl pyrollidone(NVP) using radiation. FTIR spectra was used to confirm the modification of PE films. The modified films were activated by one-step or two-step methods for electroless Cu plating. Morphology of metallized films has been investigated. Electroless Cu plating onto the modified films depends mainly on the grafting degree and activation type. The electrical conductivity and adhesion of the metallized films has been investigated and tested in regard of grafting degree of samples.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.541-546
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• 2011

In this study, conjugate fibers were prepared from 1,4-cyclohexanedimethanol-modified polyethylene terephthalate (PET) resin using side by side conjugate spinning, sea-island type conjugate spinning, and split type conjugate spinning methods, and the properties of the conjugate fibers were investigated via several techniques. When viscosity increased, the tenacity of side by side conjugate fibers was increased, whereas elongation decreased. The sea-island conjugate fibers showed lower weight loss and surface color difference (K/S) values relative to that of regular PET fibers at the same conditions. The SEM results indicate that orange type spilt readily produced at a temperature range of 120 - 140$^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1054-1059
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• 1998

Fluorescence and dynamic light scattering measurements were applied to the study of formation and structure of aggregated colloidal particles in modified poly(ethylene-co-methylacrylate) ionomers in aqueous solution. Both 8-anillino-l-naphthalene-sulfonic acid (ANS) and pyrene were used as fluorescence probe to obtain the information on the structure of particle surface and inside, respectively. Three different ionomers used in this study started to aggregate at very dilute concentration, 3-8 x 10-6 g/mL. In this study, we demonstrate that the polyethylene ionomers can form stable nanoparticles. The hydrophobic core made of the polyethylene backbone chains is stabilized by the ionic groups on the particle surface. Such a formed stable nanoparticles have a relatively narrow size distribution with an average radius in the range of 27-48 nm, depending on the kind of ionic groups. Once the stable particles are formed, the particle size distributions were nearly constant. This study shows another way to prepare surfactant-free polyethylene nanoparticles.

• Applied Chemistry for Engineering
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• v.5 no.3
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• pp.537-546
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• 1994

The physical characteristics of polymer modified asphalt depend on many parameters, such as, the polymer nature, polymer content and the asphalt properties. The objective of this study is to investigate the temperature susceptibility of polymer modified asphalt. The asphalts employed in this study were two different grades : a soft(200/300) grade and a hard(85/100) grade. And chlorinated polyethylene of two different characteristics were used : plastomer(Tyrin 2552) and elastomer(Tyrin CM0730). Temperature susceptibility of asphalt is a fundamental feature for characterizing asphalt and modified asphalt. It can be quantified by the penetration index(PI) and pen-vis number(PVN). These indices were obtained from the measurements of penetration and viscosity of the asphalt samples. For both of asphalts, the addition of the polymers increases the value of PI and PVN. Plastomer modified asphalt shows higher value of PI and PVN than elastomer modified asphalt. Soft grade shows more temperature susceptibility than hard grade at elevated temperatures.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.40 no.4
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• pp.27-33
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• 2008

Polyethylene terephtahalate has been used in several areas such as fiber, film, bottle, and disposable products. Production of PET has been rapidly increasing these days. Since PET is a semi-permanent material, it has a non-biodegradable character in itself. Wasted PET products can cause serious environmental problems. Many countries around the world impose environmental legal restrictions over their abandonments. Many researches on the enviromental influence factors and treatment techniques of the wasted PET have been carried out. The main objective of this study is to develop a new sizing agent using recycling PET and improve its internal sizing effect. Dried powder of PET was used to make the modified PET. After extracting water-dispersible PET by subcritical hydrolysis, polyester resins have been extracted and triphenyl phosphate(TPP) has been added to obtain optimal internal sizing agent. It was found that the optimum dosage of TPP was 2% (per PET weight) and the hydrolysis temperature was independent on making the modified PET.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.2
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• pp.95-101
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• 2010

For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.