• Title/Summary/Keyword: MOD process

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Effects of organic additives on YBCO coated conductor prepared by MOD-TFA method (유기첨가제가 MOD-TFA법으로 제조된 YBCO에 미치는 영향)

  • 김영국;유재무;고재웅;허순영
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.90-92
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    • 2003
  • Effects of organic additives on YBCO coated conductor prepared by MOD-TFA method were investigated. YBCO thin films were deposited on (100)-oriented single crystalline LaAlO$_3$substrates by conventional MOD-TFA process. The microstructures of YBCO thin films show labyrinth-like patterns. The origin of this microstructure was delineated by compositional inhomogeneity during the pyrolysis process of MOD process and it was shown that organic additives changes the microstructure and texture development of grown YBCO films

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Optimization of process variables in batch-type MOD process (일괄처리방식을 이용한 MOD 공정의 변수 최적화)

  • Chung, Kook-Chae;Yoo, Jai-Moo;Ko, Jae-Woong;Kim, Young-Kuk;Wang, X.L.;Dou, S.X.
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.1
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    • pp.23-25
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    • 2006
  • Optimization of process variables, including oxygen and water partial pressure and also an nesting temperature, was performed in batch-type process to fabricate YBCO films on LaAlO3 single crystal. In this work, YBCO oxide powder was used as a starting precursor for metal-organic deposition(MOD)method. The precursor films were fabricated in batch furnace and they were converted to the epitaxial YBCO films at the same furnace with varying the process variables. The oxygen partial pressure was varied from 100ppm to 2000ppm and the water partial pressure from 1.2% to 12.2%. The window for optimal P(O2) was narrow about 700ppm for batch-type process. YBCO films in bathc-thype MOD process were optimized at 740-770oC and P(H2O) of 2.3%-7.3%.

Batch-type fabrication process of YBCO coated conductor using oxide-precursor-based MOD method (산화물 전구체 기반의 MOD방법을 이용한 YBCO 고온초전도 선재의 batch-type 제조 공정)

  • Chung Kook-chae;Yoo Jai-moo;Ko Jae-Woong;Kim Young-Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.3
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    • pp.9-12
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    • 2005
  • [ $Y_1Ba_2Cu_3O_{7-8}$ ] (YBCO) coated conductor has been fabricated by batch-type process using oxide-precursor-based metal-organic deposition (MOD) method. The batch-type process can be scaled up more simply to Produce long-length YBCO conductor than the reel-to-reel process. Also, it has less handling problems and is adequate to the ambient gas environment. In this work, YBCO oride powder was used as a starting precursor for MOD method. After reel-to-reel dip coating process, me ter-long-buffered metal tape was wound around a cylinder and underwent calcination and annealing processes. Annealed YBCO films showed good c-axis alignment and dense surface morphology with no cracks, but exhibited very low critical current density of $10^5\;A/cm^2$.

MOD-processed YBCO thin films prepared by chemically controlled precursor solution (화학적으로 제어된 전구체용액을 사용하여 MOD법으로 제조된 YBCO 박막)

  • 유재무;김영국;고재웅;허순영;홍계원;이희균;김철진;정경원
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.27-29
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    • 2003
  • Solution-based MOD-TFA deposition technology of YBCO layers offers a route to low-cost YBCO coated conductors. Since the structures and properties of grown thin film by MOD process are strongly influenced by chemistry of precursor solution, the chemical modification of precursor solution for MOD process are important for improvement of the electrical properties of YBCO films. In this study, the precursor solution for MOD process are modified by chemical additives and solvents. The microstructure and texture of YBCO films grown by chemically modified precursor solution were characterized with SEM/EDS, XRD.

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Preparation of YBCO thin films by MOD-TFA process (MOD-TFA법에 의한 YBCO 박막의 제조)

  • 김영국;유재무;고재웅;허순영;이동철
    • Progress in Superconductivity
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    • v.5 no.1
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    • pp.80-83
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    • 2003
  • Superconducting YBCO thin films are fabricated on single-crystalline substrates by Metallo-organic Depostion process employing Trifluoroacetic acid as a chelating agent (MOD-TFA). (100)-oriented single crystalline LaAlO$_3$ substrates were employed to grow superconducting film with high crystallinity. The fully processed YBCO thin films were characterized with XRD, SEM, EDS, etc. The microstructures of YBCO thin films show labyrinth-like patterns. The origin of this microstructure was delineated by compositional inhomogeneity during the MOD process and it was shown that the microstructure may be modified by additives. In this work, effects of additives on the microstructures and electrical properties of YBCO thin films have been investigated.

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High-Ic YBCO thick film fabricated by the MOD process (MOD 공정으로 제조된 고임계전류 YBCO 후막)

  • Shin, Geo-Myung;Song, Kyu-Jung;Moon, Seung-Hyun;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.1
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    • pp.6-9
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    • 2008
  • We have investigated the MOD process successfully for the fabrication of the YBCO thick film on the $LaAlO_3$(001) single crystalline substrate. The cracking problem in YBCO thick film, a serious problem in the conventional TFA-MOD method, could be overcome with a careful control of precursor materials. Thus coating solution was prepared for the YBCO thick film by using fluorine-free precursor material. The precursor solutions were coated on the LAO(001) single crystalline substrate using the dip coating method, calcined at the temperature up to $500^{\circ}C$, and fired at various high temperatures for 2 h in a reduced oxygen atmosphere. Optimally processed YBCO thick film exhibited high critical current($I_c$) over 200 A/cm-width at 77K in self-field.

A Case Study of the Mod: a Developmental Perspective in Game Development Process - Focusing on Customer Involvement - (게임 제작 프로세스의 발전적 측면에서 본 모드게임 예시 연구 - 소비자 참여를 중심으로-)

  • Yoo, Bo-Mee;Ryu, Seoung-Ho
    • Journal of Korea Game Society
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    • v.9 no.1
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    • pp.55-62
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    • 2009
  • User participation, potentiality of modification, and interaction are some of significant features of game, and in the same sense, mod - user-created additions and modifications to an existing game - represents these aspects of game. Therefore, this study shows the possibility of customer involvement in the game development process through a case study of Half-life mod.

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Fabrication of YBCO Coated Conductor by oxide-precursor-based MOD process employing IBAD substrate (IBAD 기판을 적용한 산화물 전구체 MOD 공정에 의한 YBCO Coated Conductor의 제조)

  • Kim Y. K.;Yoo J. M.;Ko J. W.;Heo S. Y.;Hong G. W.;Lee H. G.;Chung H. S.
    • Progress in Superconductivity
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    • v.6 no.2
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    • pp.142-145
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    • 2005
  • YBCO coated conductors have been fabricated with a newly developed oxide-precursor-based MOD process. The precursor solution was synthesized with low cost YBCO powders as starting materials and YBCO coated conductors have been deposited on IBAD substrate ($CeO_2$/IBAD-YSZ/SS). YBCO coated conductor prepared by dip coating shows transport $I_c$ of 15A/cm-w at 77 K. Microstructural and crystallographic analyses indicate that YBCO layer was grown in epitaxy with substrate and exhibited well-developed dense microstructure. Also discussed are processing and analysis of YBCO coated conductor by slot-die web coating method. It was shown that this oxide-based MOD process provides a low cost route to coated conductor with high $J_c$.

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Total pressure dependence of YBCO films in MOD method (MOD 공정에 의해 제조된 YBCO 박막의 압력 의존성)

  • Yoo, Jai-Moo;Chung, Kook-Chae;Ko, Jae-Woong;Kim, Young-Kuk;Wang, Xiao Lin;Dou, Shi Xue
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.1
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    • pp.5-8
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    • 2006
  • The growth properties of MOD-YBCO films were investigated. To enhance the growth rate of YBCO layer and inhibit the build-up of HF gas during the annealing process in TFA-MOD for YBCO coated conductors the method of low pressure annealing was employed. Total pressure was changed from 700Torr to 1Torr and its effect on growth of YBCO films was compared with atmospheric one. The lower Pressure was effective to control of the pore size in MOD method . Surface morphology of YBCO films processed at low total pres sure was rough and composed of random YBCO (103) grains. But large pores, usually observed at atmospheric process in MOD disappeared and also the number of pores was reduced at low pressure annealing. Also discussed ate the effects of Fluorine-free Y and Cu precursor solution on the development of microstructure. Dense surface me phology and with less and small pores can be provided through controlling Fluorine content.