• Nuclear Engineering and Technology
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• 제10권4호
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• pp.195-201
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• 1978

감마선을 이용하여 폴리에스터직포에 methacylic acid와 methyl methacylate를 graft 종합반응시켜서 그 반응성을 보았다. 폴리에스터직포에 acrylic acid, methacrylic acid, methyl methacrylate를 중합반응 시켰을 때 graft 효율은 monomer 혼합용액내에 포함되어 있는 용매의 dielectric constant에 따라 상당한 차이를 나타내었다. Graft 수율은 방사선 선량과 monomer 농도 및 swelling agent의 농도에 좌우되었다. MA graft copolymer의 glass transition temperature (101$^{\circ}C$)와 melting point (238$^{\circ}C$)를 측정하였고, 정전기 효과는 frictional electricity 8,000V에서 half life가 0 sec이었으며, moisture regain는 5.6%, wicking time은 1 sec이었다.

• Elastomers and Composites
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• 제28권3호
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• pp.191-197
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• 1993

The graft copolymerization of methyl methacrylate(MMA) onto natural rubber latex(NRL) initiated by t-butyl hydroperoxide(t-BHPO) was investigated in aquous medium. The grafting percentage, grafting efficiency and total conversion were observed in various reaction conditions such as monomer, initiator and emulsifier concentration, reaction temperature, reaction time and agitation speed. The optimum conditions for the graft copolymerization onto natural rubber latex were as follows ; At given monomer concentration of $3{\times}10^{-2}mole/l$, the maximum grafting percentage was appeared in the case of grading in initiator concentration of $4{\times}10^{-2}mo1e/l$ and emulsifier concentration of 0.2wt.% at $40^{\circ}C$ for 5hrs.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.769-774
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• 2002

In this study, methyl methacrylate (MMA)- modified polyester polymer concrete, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the fundamental properties of the polymer concrete such as workability and strength were surveyed. The experimental results showed that the workability was remarkably improved as the MMA contents increased, and the filler-binder ratio was turned out to be important factor for the workability. Slump prediction equation was derived by the regression analysis based on MMA content and filler-binder ratio. Furthermore, early-age strength was greater when the MMA content were increased in the range of 20-40 % but the strength rather showed a tendency of decrease when the MMA content was 50 %.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2003년도 학술발표논문집
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• pp.379-382
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• 2003

In this study, methyl methacrylate (MMA)- modified unsaturated polyester mortar, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the strength properties of the MMA-modified unsaturated polyester mortar were surveyed. The experimental results showed that early-age strength was greater when the MMA contents were increased in the range of $20{\sim}40%$, but the strength rather showed a tendency of decrease when the MMA contents was 50%.

• Macromolecular Research
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• 제11권3호
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• pp.163-171
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• 2003

For the pervaporation of water-ethanol mixtures, new composite membranes having poly(acrylic acid)-poly (butyl methacrylate-co-methyl methacrylate) interpenetrati ng polymer network [PAA-P(BMA-co-MMA) IPN] skin layer supported on porous and crosslinked poly(BMA-co-MMA) were prepared. The morphology of the sub-layer of the composite membrane prepared in the presence of 60 wt% solvent showed cellular structure, on the other hand that of sublayer prepared in the presence of 70 wt% solvent presented very porous interconnected pore structure with macrovoids. Permeation rates of the composite membranes were largely influenced by the morphology of the sublayer. Separation factors increased with the increase of the degree of crosslinking of the PAA network. It was found that permeation rates could be increased by introducing anionic charges on carboxyl groups of the PAA. The permeation rate changes of the PAA-P(BMA-co-MMA) IPN composite membranes according to the feed compositions showed quite similar pattern with the swelling behavior in water-ethanol mixtures.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.763-768
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• 2002

In this study, methyl methacrylate (MMA) - modified polymer mortar(MMPM) was developed and its setting shrinkage and working life properties were surveyed. In order to study the setting shrinkage, setting shrinkage test for the 24 batches were also conducted with taking the MMA monomer content to the UP resin and the mixed content of shrinkage reducing agent(SRA) as variables. Furthermore, in order to study the working life measured gel time, working time, setting time of MMPM and binder. Experimental resurts show that the workability remarkably improved as the mixed MMA content increased. The working life was proportional to MEKPO content and was shorted. also, showed high interrelationship of binder gel time and MMPM working life. Setting shrinkage markedly reduced as the content of MMA and the SRA increased.

• 폴리머
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• 제34권4호
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• pp.313-320
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• 2010

신나메이트기를 갖는 새로운 자기 경화형 감습성 고분자 및 고분자형 앵커제로 사용하기 위하여 [2-[(methacryloyloxy) ethyl]dimethyl]propyl ammonium bromide(MEPAB), methyl methacrylate(MMA), 3-(trimethoxysilyl) propyl methacrylate(TMSPM) 및 2-(cinnamoyloxy)ethyl methacrylate(CEMA)의 공중합체들 을 합성하였다. 광가교성 공중합체들로서 MEPAB/MMA/TMSPM/CEMA＝70/20/0/10의 조성을 갖는 공중합체는 감습성 전해질 고분자로서, 그리고 50/0/20/30과 0/0/50/50 조성은 고분자형 부착제로 사용하였다. 이들 광가교형 고분자 실란커플링 처리제의 전극 표면과 부착 특성을 비교하기 위하여 3-(triethoxysilyl)propyl cinnamate(TESPC)도 표면 부착을 위한 표면처리제로서 사용하였다. 표면처리제는 전극의 기재 표면 위에 공유결합을 통하여 광가교성 신나 메이트 박막을 형성시킬 수 있었으며 센서에 UV가 조사되었을 때 전해질 고분자가 [2$\pi$+2$\pi$] 환화반응을 이용한 가교반응으로 기재에 부착되었다. 이렇게 고분자 표면처리제 및 TESPC로 처리된 센서들은 24시간 물에 침적시켰을 때 60~85%의 저항 증가가 생겼으며 이것은 상대습도 변화로서 2.25~3.15%RH에 해당하였다. 또한, -0.2%RH 이하의 양호한 히스테리시스, 90초의 응답 및 회복속도, 그리고 80 $^{\circ}C$ 및 90%RH의 고온 고습에서 매우 좋은 신뢰성을 보여주었다.

• 대한의용생체공학회:의공학회지
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• 제16권4호
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• pp.533-542
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• 1995

The present study investigated the effectiveness of pretreatment on dentin bonding. The adhesive resin was 5% 4-methacryloyloxyethyl trimellitate anhydride (4-META) in methyl methacrylate (MMA) combined with poly-MMA powder. Polymerization of this resin was initiated by tri-n-butyl borage (TBB). Ground bovine dentin samples were etched with either an aqueous solution of 10% citric (10-0 solution) (Group I) or aqueous solution of 10% citric acid and 3% ferric chloride(10-3 solution) (Group ll ). After etching, the primer (an aqueous solution of 35% hydroxyethyl methacrylate (HEM- A) and 5% glutaraldehyde was applied on the differently etched surfaces (Group III , Group IV). The 10-0 treatment showed the lowest tensile bond strength, followed by the 10-3 treatment, primer application after the 10-0 treatment and primer application after the 10-3 treatment. The relationship among the surface morphology after pretreatment, fractured surface morphology and tensile bond strength was examined. It revealed that the surface morphology change by different pretreatment influenced the bond strength and the resulting fractured surface morphology. The correlation of tensile bond strength with the fracture morphology was explained.

• Macromolecular Research
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• 제15권7호
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• pp.617-622
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• 2007

A simple and economic antistatic agent, (2-methacryloyloxyethyl)acid phosphate (acryl phosphate), was synthesized via the reaction of 2-hydroxyethyl methacrylate with phosphorus pentoxide. The acryl phosphate antistatic agent, synthesized in this study, was introduced into poly(methyl methacrylate) (PMMA) resin via copolymerization with MMA. This antistatic agent provides the PMMA matrix with excellent antistatic properties, including surface resistance and electric charge. A comparison of the present antistatic agent with other commercial agents demonstrated the excellence of not only its electrical, but also its thermal and mechanical properties.

• 복합신소재구조학회 논문집
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• 제6권3호
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• pp.50-61
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• 2015

This paper presents on the structural behavior of the the methyl methacrylate monomer (MMA) double wide flanged the glass fiber-reinforced polymer(GFRP) pipe composite structures for the manhole raise. The evaluation of structural performance on this composite structure was conducted by the axial load, fatigue load, and ultimate load test. The assessment indicates that the MMA double wide flanged GFRP pipe composite structures was confirmed safety, durability and reliability in result as expected. It was found that this composite structure was able to short working times to around 30-50% and construction costs to around 10-23% with compare other construction methods. Also, environmental pollution and civil complaints will be prevented because there will be no longer any noises, vibrations, dust, or construction wastes.