• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.122-122
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• 2010

ZnO is a widely investigated material for the blue and ultraviolet solid-state emitters and detectors. It has been promoted due to a wide-band gap semiconductor which has large exciton binding energy of 60 meV, chemical stability and low radiation damage. However, there are many problems to be solved for the growth of p-type ZnO for practical device applications. Many researchers have made an efforts to achieve p-type conductivity using group-V element of N, P, As, and Sb. In this letter, we have studied the optical characteristics of the antimony-doped ZnO (ZnO:Sb) thin films by means of photoluminescence (PL), PL excitation, temperature-dependent PL, and time-resolved PL techniques. We observed donor-to-acceptor-pair transition at about 3.24 eV with its phonon replicas with a periodic spacing of about 72 meV in the PL spectra of antimony-doped ZnO (ZnO:Sb) thin films at 12 K. We also investigate thermal activation energy and carrier recombination lifetime for the samples. Our result reflects that the antimony doping can generate shallow acceptor states, leading to a good p-type conductivity in ZnO.

• 한국의학물리학회지:의학물리
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• 제9권4호
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• pp.267-276
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• 1998

팬톰내에 삽입되는 전리함은 전자 플루언스의 교란을 최소화하는 기하학적 구조를 갖는 것이 바람직한데 평행평판형 전리함은 다른 어떤 전리함보다도 이러한 조건을 잘 만족시킨다. 이러한 이유로 IAEA 표준측정법에서는 표면 평균 에너지가 10 MeV 이하인 전자선 측정시 평행평판형 전리함의 사용을 권고하고 있으나 일반적으로 편의상 원통형 전리함을 많이 사용하고 있는 실정이다. 본 연구에서는 네 가지 다른 표준 측정법 즉 1)원통형 전리함을 사용한 IAEA 표준 측정법 2)원통형 전리함을 사용한 TG-21 표준 측정법 3)평행평판형 전리함을 사용한 Markus 측정법 4)평행평판형 전리함을 원통형 전리함에 대하여 교정한 TG 39 측정법을 사용하여 서로 다른 측정법과 전리함의 차이에 의한 선량 값의 변화를 알아보고자 한다. Siemens KD-2 선형가속기에서 발생하는 고에너지 전자선(6,9,12,15,18 MeV)을 이용하여 3차원 전산화 물팬톰과 0.125 cc 전리함을 사용하여 각 에너지별로 l0$\times$10 $cm^2$ cone size의 심부선량백분율을 구하였다. 고체 물팬톰내에서 Farmer type 0.6cc 원통형 전리함을 사용하여 IAEA 표준 측정법과 TG-21 표준 측정법에 의해서 각 에너지별로 흡수선량을 측정하였다. 평행평판형 전리함(Markus Chamber)을 사용하여 Markus 측정법에 의해서 각 에너지별로 흡수선량을 측정하였다. 전자선 에너지 18 MeV를 사용하여 원통형 전리함에 대한 평행평판형 전리함의 교정계수를 얻고 TG 39 측정법에 의해서 각 에너지별로 흡수선량을 측정하였다. Cone size 는 l0$\times$10 $cm^2$ 이었고 측정점의 깊이는 d$_{max}$ 이었다. IAEA 표준 측정법과 TG 21 표준 측정법은 18 MeV 에 대하여 0.9 % 의 차이가 나타났고 그 외의 에너지 영역에서 0.7% 이내로 비교적 잘 일치하였다. Markus 측정법과 TG 39 측정법은 18 MeV 와 6 MeV 에 대하여 각각 $\pm$0.8 % 의 차이가 나타났고 그 외의 에너지 영역에서 0.5 % 이내로 잘 일치하였다. 원통형 전리함과 평행평판형 전리함을 이용한 측정법간의 차이는 18 MeV 에서 1.6 % 까지 나타나므로 주의를 요하며 TG 39 측정법에서 제시한 다른 측정방법을 사용하여 측정을 하여 교정계수를 얻을 필요가 있을 것으로 생각된다.다.

• 전자공학회논문지D
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• 제36D권4호
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• pp.48-56
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• 1999

본 논문에서는 초기 산소 농도가 고에너지 이온 주입시 결정 격자 손상에 의해 발생하는 산소 축적(pileup) 현상 및 주입된 불순물의 확산에 미치는 영향을 실험적으로 고찰하였다. 초기 산소 농도가 11.5, 15.5 ppma인 p-type (100)실리콘 웨이퍼에 \sup 11\B\sup +\ \sup 31\P\sup +\ 이온을 각각 1.2 MeV, 2.2 MeV 의 에너지로 1×10\sup 15\cm\sup 2\ 주입하고, 700℃(20시간)+1000℃(10시간)의 2단계 열처리를 거치 후 주입된 불순물 및 산소 농도의 분포를 이차이온질량분석기 (Secondary Ion Mass Spectrometry, SIMS)로 관찰하였으며 잔류 2차 결함의 분포는 투과전자현미경(Transmission Electron Microscopy, TEM)으로 관찰하였다. SIMS 측정 결과 산소의 축적이 {{{{ { R}_{ } }}}}\sub p\(projected range) 부근에서 관찰되었으며 열처리 후에도 상당한 양의 2차 결합 띠가 {{{{ { R}_{ } }}}}\sub p\부근에서 관찰되는 것으로 보아 2차 결함에 의해 산소가 포획되었음을 알 수 있다. 또한 붕소와 인의 확산은 웨이퍼의 초기 산소 농도가 클수록 벌크 방향으로의 확산이 증대되는 현상을 볼 수 있었다.

• 한국자기학회지
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• 제6권2호
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• pp.73-79
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• 1996

Y형 육방정 산화철$(Ba_{2}Me_{2}Fe_{12}O_{22}:Me=천이금속)$은 천이 금속으로 Co와 Zn가 포함된 경우 양호한 고주파 특성을 보이는 것으로 알려져 있다. 따라서, 결정 구조 내에 이들의 분포 상태를 파악하는 것이 중요하다. 본 논문에서는 엄밀한 성분 분석, X-선 회절 분석, 자기 특성 분석을 통하여 확인된 $Co_{2}Y$와 $Co_{1.6}Zn_{0.4}Y$시료에 대한 $M\"{o}ssbauer$ 분광 분석 결과로부터 다음과 같은 결론을 제시하였다. (1) Co는 주로 육방정 산화철의 S-block에 위치한 4배위 자리 $(6c_{IV})$와 S-, T-block 경계의 6배위자리(18h VI)에 들어간다. (2) Co의 일부를 Zn으로 치환하여도, Fe의 분포에는 큰 영향을 미치지 않는다.

• Bulletin of the Korean Chemical Society
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• 제15권11호
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• pp.990-996
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• 1994

New ferrocene-based chelate amines, $Fe[C_5H_4CH(Me)NMe_2]_2\;(3), \;Fe[C_5H-3(CH(Me)NMe_2)(PPh_2)-1,2]_2\;(4),\;(C_5H_5)Fe(C_5H_3(CH_2NMe_2)(CH(CN)NMe_2-1,2)\;(6),\;and\;(C_5H_5)Fe(C_5H_3(CH_2NMe_2)(CH(Me)NMe_2-1,2)$ (7) have been prepared. The reaction and the coordination chemistry of 4 and other related compounds (S,R)-(1-N,N-dimethylaminoethyl)-2-dicyclohexylphosphino)ferrocene (CPFA) and 1,1'-bis-(diphenylphosphino)ferrocene (BPPF) with $Rh_2(OAc)_4(MeOH)_2$ were investigated. The reaction of the chiral ligand (S,R)-CPFA forms a complex of the type (${\eta}^1$-(S,R)-CPFA-P)$_2Rh_2(OAc)_4$ (8) in which the ligand is coordinated to both rhodium centers in a monodentate fashion through phosphorus. In contrast, the bisphosphine analogues such as BPPF and 4 afford chelate complexes of the type (${\eta}^2-PP)Rh_2(OAc)_4$ (9 & 10) where both ligands act as a chelate bidentate to a single rhodium atom. All these complexes were characterized by microanalytical and spectroscopic techniques. In one case, the structure of 8 was determined by X-ray crystallography. Crystals are monoclinic, space group C2 (No. 5), with a=26.389 (3), b=12.942 (1), c=11.825 (1) A, ${\beta}$=111.22(1)$^{\circ}$, V=3964.7 (8) $A^3$, Z=4, and $D_{calc}$=1.58 g $cm^{-3}$. Two Rh(II) centers are bridged by four $AcO^-$ groups in the ${\eta}^1$ : ${\eta}^1$ mode across a Rh-Rh single bond, and octahedral coordination at Rh(1) and Rh(1') is completed by axially coordinating (S,R)-CPFA and a briding $AcO^-$, respectively.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.889-893
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• 2011

The energetics and transition state (TS) structures of the reactions of six substrates, $R_1R_2P$(=O or S)Cl-type where $R_1=R_2$=Me and/or MeO, with ammonia in acetonitrile are theoretically investigated at the level of CPCM-MP2/6-31+G(d) and CPCM-MP2/6-311+G(3df,2p). The degrees of distortion of TS from the ideal trigonal bipyramidal pentacoordinate, ${\Delta}{{\delta}}_{{\neq}b}$ for a backside and ${\Delta}{{\delta}}_{{\neq}f}$ for a frontside attack, are calculated. The results of calculation suggest that the feasibility of a frontside attack for P=S is greater than that for P=O system when the two ligands, $R_1$ and $R_2$, becomes larger. The experimental and calculated results of anilinolyses of $R_1R_2P$(=O or S)Cl-type show the consistent tendencies.

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1997-2002
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• 2011

The nucleophilic substitution reactions of dicyclohexyl phosphinic chloride [3; $cHex_2$P(=O)Cl] with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at 60.0 $^{\circ}C$. The anilinolysis rate is too slow to be rationalized by the stereoelectronic effects. The rate is contrary to expectations for the electronic influence of the two ligands and exhibits exceptionally great negative deviation from the Taft's eq. The deuterium kinetic isotope effects (DKIEs) involving deuterated anilines invariably change from primary normal ($k_H/k_D$ > 1; max $k_H/k_D$ = 1.10 with X = 4-MeO) with the strongly basic anilines (X = 4-MeO, 4-Me, 3-Me) to secondary inverse ($k_H/k_D$ < 1; min $k_H/k_D$ = 0.673 with X = 3-Cl) with the weakly basic anilines (X = H, 4-F, 4-Cl, 3-Cl). A concerted $S_N2$ mechanism is proposed on the basis of both secondary inverse and primary normal DKIEs. The obtained DKIEs imply that the fraction of a frontside attack increases as the aniline becomes more basic. A hydrogen-bonded, four-center-type transition state is suggested for a frontside attack, while the trigonal bipyramidal pentacoordinate transition state is suggested for a backside attack.

• 생약학회지
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• 제31권1호
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• pp.82-86
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• 2000

To evaluate anti-influenza virus activity of 113 specimens of Korean traditional medicine both water and methanol extracts were examined using haemagglutination inhibition test. The water extract from Citrus junos was found to inhibit influenza virus A/Taiwan/l/86(H1N1). The survival rates of virus were determined by in situ cellular enzyme-linked immunosorbent assay. The water extract of Citrus junos was fractionated by chromatographic separating using Amberlite XAD-4, 40% MeOH and 60% MeOH layer had antiviral activity. The half inhibition concentration $(IC_{50})$ of 40% MeOH layer on survival of influenza virus was $MIC>361.5{\mu}g/ml$ and $IC_{50}$ value of fr. 40-4 fractionated from 40% MeOH layer was $677.19{\mu}g/ml$. These results suggested that the fractions of Citus junos have potent anti-influenza A virus activity.

• 한국식품조리과학회지
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• 제8권3호
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• pp.281-289
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• 1992

The physicochemical, rheological and sensory characteristics of Backsulgies added with dietary fibers-cellulose, pectin and wheat bran-were investigated. The maximum acceptable ratio of fibers was 10% for wheat bran or cellulose, 3% for pectin. As me results of physicochemical analysis, cellulose and pectin had larger water-binding capacity man wheat bran. Swelling power was increased with temperature increment. But the type of added dietary fiber did not make significant differences. The degree of gelatinization was measured by maltose content. The retrogradation of backsulgies was significantly delayed by the addition of dietary fibers. The retardation effect of dietary fibers for retrogradation of backsulgies was also proved by textural analysis and time constant determination of Avrami equation. Pectin had especially excellent delaying effect while me storage time extended. There were no significant differences in sensory characteristics between me backsulgi with no dietary fibers and backsulgies added with cellulose 3%, pectin 1% and wheat bran 3%. Therefore, we concluded mat cellulose 3%, pectin 1% and wheat bran 3% were me optimum addition ratios, which have the delaying effect of retrogradation, and which could be accepted as same as conventional backsulgies organoreptically.

• Reproductive and Developmental Biology
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• 제37권1호
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• pp.9-16
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• 2013

Artificial insemination (AI) has been performed widely in swine industry using fresh liquid sperm instead of frozen type of sperm. However fresh sperm are not able to preserve more than three days with optimal motility and other sperm parameters for the successful fertilization, since in vitro stored sperm has an oxidative stress that resulted increase of abnormality and acrosome reation. To overcome these major problems, novel preservative formulation is needed to neutralize the oxidative stress and to provide suitable physiological environment for sperm in in vitro. In this study, naturally derived substances such as Poncirus trifoliate (Trifoliate orange), Garcinia mangostana (Mangosteen), pig placenta and testis extracts were tested as sperm preservative agents. Placenta extracts (PE), trifoliate orange extracts (TOE), testes extracts (TE) and mangosteen extracts (ME) were applied to analyze specific parameters for sperm motion characteristics individually and combinatorial. Each individual extract treatment can accelerate the sperm motility but noticeably TOE, TE and ME treatments exhibited the considerable and significant preservation of sperm motility. PE, TE and ME showed a significant (p<0.05) increase in ALH after one week. Further we evaluated the five different combinations of these extracts on sperm motility and its motion characteristics. Surprisingly even after one week ME, TOE and TE combination significantly preserved the sperm motility about 75%. It is noteworthy that unlike individual extract treatment, combination of ME, TOE and TE simultaneously protect the sperm motility and its motion characteristics. Taken together these data conclude that addition of ME, TOE and TE can be effective for preservation of pig sperm.