• Title/Summary/Keyword: MCrAlY

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High temperature oxidation of MCrAlY thermal barrier coating (MCrAlY 열차폐 코팅의 고온산화)

  • 고재황;이동복
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.219-219
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    • 2003
  • HVOF(High Velocity Oxygen Fuel)법을 사용한 MCrAlY(M=Ni, Co, Fe)계 열차폐 코팅(thermal barrier coating)은 열기관 내부의 극심한 환경 부하에 대해 구조물 표면에 열적, 화학적 장벽을 형성함으로써 구조물의 내구성을 향상시킨다 이와 동시에 열차폐 효과는 구조물의 온도상승 없이 내부 가동 온도를 높일 수 있게 함으로써 열효율을 상승시키고 연료 효율을 높여 가동비용 절감을 이룰 수 있는 동시에 고 연소를 통한 오염원의 배출을 감소시킬 수 있다. 본 연구에서는 $H_2O$$_2$=5:1 분위기 하에서 HVOF법을 사용하여 Hastelloy-X 기판위에 125$\mu\textrm{m}$의 두께로 다음 5종류의 (Ni, Co, Cr)계 MCrAlY 코팅을 용사시켰다. 준비된 (Ni, Co)-Cr-Al-(Y, Ta, Re), (Ni, Co)-Cr-Al-(Y, Re), (Ni, Co)-Cr-Al-(Y, Ta), (Ni, Co)-Cr-Al-Y, (Ni,Co)-Cr-Al-Ir 코팅시편에 대한 산화성질을 조사하기 위해 대기 중 1000, 1100, 120$0^{\circ}C$에서 50, 100, 150, 200시간 등온실험(Isothermal oxidation)을 실시하였고, XRD, SEM/EDS, EPMA를 이용하여 생성된 산화막과 코팅 시편의 조직 변화를 조사하였다. 산화온도와 산화시간이 증가할수록 산화막의 박리가 많이 발생하였으며, 분석 결과 미세하게 분포된 a-Al$_2$O$_3$ 입자, NiCr$_2$O$_4$스피넬 상, 미세한 Cr$_2$O$_3$가 관찰되었고, 코팅 조성 변화에 따라 형성되는 이들 산화물의 존재비가 달라졌으며, 산화온도가 높아질수록 산화속도가 가속화되었다.

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A Study on Acoustic Emission Characteristics of MCrAlY Coated Material by Vacuum Plasma Spray Process (진공 플라즈마 용사공정에 의한 MCrAlY코팅재의 음향방출 신호 특성 연구)

  • 박진효;이구현;예경환;김정석;강명창
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.921-924
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    • 2004
  • This paper is to investigate a crack for plasma sprayed MCrAlY coated material by acoustic emission method in 4-point bending test. The CoNiCrAlY is coated on Inconel-718 by vacuum plasma spray process. Micro-hardness measurement was conducted by means of Micro Vickers-hardness indentor. The porosity of coating layer was measured using a SEM and Image Analyzer. AE monitoring system is composed of PICO type sensor, a wide band preamplifier(40dB), a PC and AE DSP(16/32 PAC) board. The AE count, Hit and energy of coating specimens is measured according to coating thickness.

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New Scheduling Algorithm for Fairness Criteria of ATM ABR (ATM ABR의 공평성들을 위한 새로운 스케쥴링 알고리즘)

  • Chung, Kyung-Taek;Park, Jun-Seong;Park, Hyun;Chon, Byoung-Sil
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.39 no.4
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    • pp.188-200
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    • 2002
  • The WRR scheduling algorithm is widely used in ATM networks due to its simplicity and the low cost of hardware implementation. It guarantees minimum cell rate according to the weight of each queue. The fairness is a important factor for ABR service. That is, scheduling algorithm allocates network resources fairly to each VC. However, WRR algorithm shows worse performance on bursty traffic. Because it schedules input traffics according to predetermined weight, it can not satisfies fairness criteria, MCR plus equal share and Maximum of MCR or Max-Min share, defined by ATM Forum TM 4.1 specification. The Nabeshima et al algorithm is not adapt to network status rapidly because it is not compensate the weights of unused bandwidth to VCs and assign the unused bandwidth to VCs by RR method. In this paper, we propose a scheduling algorithm for satisfying the two fairness criteria, MCR plus equal share and Maximum of MCR or Max-Min share, among the six criteria defined by ATM Forum TM 4.1 specification. The WRR, Nabeshima et al, and the proposed scheduling algorithms are compared with respect to fairness and convergence time throughout experimental simulation. According to the simulation results, the proposed algorithm shows higher fairness and more rapid convergence than other algorithms.

Thermal cyclic characteristics of TBC/CoNiCrAlY thermal barrier coatings (TBC/CoNiCrAlY 용사코팅의 열싸이클 특성)

  • Kim Ui-Hyeon;Yu Geun-Bong
    • Proceedings of the KWS Conference
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    • 2006.05a
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    • pp.45-47
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    • 2006
  • The rotating components in the hot sections of land-based gas turbine are exposed to severe environments during several tens thousand operation hours at above $1100^{\circ}C$ operation temperature. To protect such components from high temperature oxidation, an intermediate bond coat is applied, typical of a MCrAlY-type metal alloy. This study is concerned with the thermal cyclic behavior of thermal barrier coatings. The MCrAlY bond coatings are deposited by HVOF (High Velocity Oxygen Fuel) method on a nickel-based superalloy (GTD-111). Thermal cyclic tests at $1100^{\circ}C$ in ambient air for various periods of time were used to evaluate the thermal cyclic resistance of the TBC coating. The microstructure and morphology of as-sprayed and of thermal cycled coatings were characterized by scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD).

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Cyclic Oxidation Behavior of Vacuum Plasma Sprayed NiCoCrAlY Overlay Coatings (진공 플라즈마 용사법을 통해 형성된 NiCoCrAlY 오버레이 코팅의 반복 산화 거동)

  • Yoo, Yeon Woo;Nam, Uk Hee;Park, Hunkwan;Park, Youngjin;Lee, Sunghun;Byon, Eungsun
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.283-288
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    • 2019
  • MCrAlY overaly coatings are used as oxidation barrier coatings to prevent degradation of the underlying substrate in high temperature and oxidizing environment of the hot section of gas turbines. Therefore, oxidation resistance in high temperature is important property of MCrAlY coatings. Also, coefficients of thermal expansion (CTE) of MCrAlY have middle value of that of Ni-based superalloys and oxides, which have the effect of preventing the delamination of the surface oxides. Cyclic oxidation test is one of the most useful methods for evaluating the high temperature durability of coatings used in gas turbines. In this study, NiCoCrAlY overlay coatings were formed on Inconel 792(IN 792) substrates by vacuum plasma spraying process. Vacuum plasma sprayed NiCoCrAlY coatings and IN 792 susbstrates were exposed to 1000℃ one-hour cyclic oxidation environment. NiCoCrAlY coatings showed lower weight gain in short-term oxidation. In long-term oxidation, IN 792 substrates showed higher weight loss due to delamination of surface oxide but NiCoCrAlY coatings showed lower weight loss. X-ray diffraction (XRD) analysis showed α-Al2O3 and NiCr2O4 was formed during the cyclic oxidation test. Through cross-section observation using scanning electron microscopy (SEM) and electron back scatter diffraction (EBSD) analysis, thermally grown oxide (TGO) layer composed of α-Al2O3 and NiCr2O4 was formed and the thickness of TGO increased during 1000℃ cyclic oxidation test. β phase in upper side of NiCoCrAlY coating was depleted due to oxidation of Al and outer beta depletion zone thickness also increased as the cyclic oxidation time increased.

A Vulnerability Analysis of Multi-Context RFID Mutual Authentication Protocol (다중 컨텍스트 RFID 상호 인증 프로토콜의 보안 취약점 분석)

  • Kim, Young-Back;Kim, Sung-Soo;Chung, Kyung-Ho;Kim, Soo-Yong;Yun, Tae-Jin;Ahn, Kwang-Seon
    • Journal of the Korea Society of Computer and Information
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    • v.18 no.10
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    • pp.71-80
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    • 2013
  • In this paper, we analyze the security vulnerability through the several attack scenarios for the MCR-MAP(Multi-Context RFID Mutual Authentication Protocol) proposed by Ahn et al. And we propose the secure mutual authentication protocol that improved a prior MCR-MAP. The suggested protocol uses the ID of the legal tag and the timestamp generated by the server, when the tag tries to authenticate. And when the tag creates the credential, we create the new secret key computing the XOR operation between the secret key shared with the server and the tag timestamp generated by the server. As a result, the proposed protocol provides the secure mutual authentication and then is safe to spoofing attack. Also it provides forward-secrecy and then is safe to offline brute-burst attack. In this paper, we compare and verify the security vulnerability of the prior and the proposed protocol through the security analysis.

SHS of Oxide Systems Based on MCR of Quartz Modified by Organometallic Compounds

  • Soh, Dea-Wha;Tlek, Ketegenov;Z.A., Mansurov
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.666-669
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    • 2002
  • The differences of the effects of mechanical substance pre-activation in the mills with divers force effect schemes on the self-propagating high temperature synthesis (SHS) of the $SiO_2$ + 37.5% Al system were investigated. The power saturation of activated material state are estimated referring on the variations of dilatometry curve paths. The effects of activation time on the temperature of sample self-ignited in the furnace, combustion temperature and completeness of the quartz reaction with aluminium were determined. The enhancing effects of organic modifiers of quartz particle surfaces on the further SHS synthesis development were shown.

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