• Title/Summary/Keyword: MAPP

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Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites

  • Kim, Hyun-Il;Han, Woong;Choi, Woong-Ki;Park, Soo-Jin;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.20
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    • pp.39-46
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    • 2016
  • In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (KIC). From the KIC test results, the KIC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

Mechanical and Thermal Properties of Polypropylene/Wax/MAPP Composites Reinforced with High Loading of Wood Flour

  • Lee, Sun-Young;Kang, In-Aeh;Doh, Geum-Hyun;Mohan, D. Jagan
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.4
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    • pp.416-426
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    • 2007
  • Polypropylene (PP) composites with wood flour/wax/coupling agent were manufactured by melt compounding and injection molding. The influence of wood flour(WF), wax, and coupling agent on the mechanical and thermal properties of the composites was investigated. The addition of wood flour to neat PP has the higher tensile modulus and strength compared with neat PP. The presence of wax also improved the tensile modulus. At the same loading of PP and WF, the addition of coupling agent highly decreased the tensile modulus, and increased the tensile strength. From thermogravimetric analysis (TGA), the addition of wax improved the thermal stability of the composites in the later stages of degradation. The presence of MAPP and wood flour in turn decreased thermal stabilities of composites. From differential scanning calorimetry analysis (DSC), neither the loading of wax. nor the presence of MAPP has shown significant effect on the thermal transition of composites.

Mechanical Properties of Natural Fiber Composites by Co-polymerized Thermoplastics (공중합된 열가소성 수지에 의한 자연섬유 복합재의 기계적 물성에 관한 연구)

  • Lee, Jung-Hoon;Hwang, Byung-Sun;Byun, Joon-Hyung;Kim, Byung-Sun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.116-120
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    • 2005
  • In this study, composites with polypropylene(PP) and Jute fiber were prepared by compression molding technique. Generally, hydrophilic jute fibers do not adhere well to PP, which is hydrophobic. Maleic anhydride grafted polypropylene(MAPP) had been widely used as a coupling agent to improve the bonding between ligno-cellulosic fibers and PP. The coupling agent improved the tensile and flexural properties when the mechanical properties were tested by using a UTM. The mechanical properties of natural fiber composites(NFCs) by modified thermoplastics were higher than those of NFCs by unmodified thermoplastics. Fracture surfaces of the composites and the fiber orientations were investigated by scanning electron microscopy. The mechanical performance of NFCs by modified thermoplastics appeared to be improved by the enhanced interface adhesion between the fiber and the matrix.

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Mechanical and Hygroscopic Behaviour of Teak Wood Sawdust Filled Recycled Polypropylene Composites

  • Yadav, Anil Kumar;Srivastava, Rajeev
    • Composites Research
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    • v.31 no.5
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    • pp.202-208
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    • 2018
  • In this paper, mechanical and hygroscopic properties of teak sawdust and recycled polypropylene (RPP) composites are evaluated and compared with virgin polypropylene (VPP) matrix based composites. Verities of composites are prepared by variation in the plastic types, wood plastic ratio and the addition of coupling agent in the formulations. Mixing of wood sawdust and polypropylene is done by a twin screw extruder, and then sheets of wood plastic composites (WPCs) are produced by using the compression molding method. The results show that recycled matrix composites exhibit better tensile, flexural strength with low impact strength than virgin matrix based composites. Recycled composites show low water absorption and thickness of swelling than virgin matrix based composites. The results confirm that wood content in the polymer matrix affects the performance of composites while presence maleated polypropylene (MAPP) improves the properties of the composites significantly. Developed RPP matrix composites are as useful as VPP matrix composites and have the potential to replace the wood and plastics products without any adverse effect of the plastics on the environment.

Studies on Borassus fruit fiber and its composites with Polypropylene

  • Sudhakara, P.;Obi Reddy, K.;Prasad, C. Venkata;Jagadeesh, Dani.;Kim, H.S.;Kim, B.S.;Bae, S.I.;Song, J.I.
    • Composites Research
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    • v.26 no.1
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    • pp.48-53
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    • 2013
  • This paper summarizes the structural characterization of borassus fruit fibers by means of various characterization techniques, optimization of alkali treatment of borassus fruit fine fibers (BFF) with a 5% concentration sodium hydroxide solution for different time intervals (1, 4, 8 and 12 h) and the changes occurring in borassus fibers. This paper also discusses the manufacturing of BFF/PP compotes using MAPP as a compatibilizer in addition to alkali treatment. Composites were evaluated for their mechanical and morphological properties. The tensile strength and modulus, flexural strength and modulus and impact strength were increased for alkali treated/MAPP composites by 4.5%, 17%, 17.2 %, 9% and 10% respectively.

Thermal and Dynamic-Mechanical Characterization of Rice-Husk Filled Polypropylene Composites

  • Rosa, Simone M.L.;Nachtigall, Sonia M.B.;Ferreira, Carlos A.
    • Macromolecular Research
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    • v.17 no.1
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    • pp.8-13
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    • 2009
  • Natural fiber-filled polymer composites have attracted great interest due to increasing environmental concerns and their low costs. In this study, the properties of rice husk flour-filled polypropylene (PP) were analysed in view of the large quantities of this agricultural product available as residue in Brazil. The rice husk flour (RHF) was characterized by SEM and particle size distribution. The properties of the composites were studied by MFI, DMA, DSC and TGA analyses. A commercial PP modified with maleic anhydride (MAPP) was used as coupling agent. It was verified that RHF decreased the MFI of the composites and that the coupling agent decreased it even more. The efficiency of MAPP was confirmed by the high storage modulus and high loss factor of the coupled composites.

Evaluation of Combustion gas during Fire Tests of Veneers Coated with Ammonium Salts (암모늄염으로 도포시킨 베니어판의 연소 시에 발생하는 연소가스 평가)

  • Jin, Eui;Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.30 no.5
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    • pp.93-99
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    • 2016
  • This study tested the combustion characteristics of veneer specimens coated with four kinds of ammonium salts. Each veneer specimen was coated three times with 20 wt.% ammonium salt solutions at room temperature. After drying, the combustion characteristics of the specimens coated with chemicals, were investigated using the cone calorimeter (ISO 5660-1, 2). The specimens coated with monoammonium phosphate (MAPP) and, diammonium phosphate (DMPP) showed a 6.7% and, 10.0%, lower mean heat release rate ($HRR_{mean}$), respectively, than that of the uncoated specimen. On the other hand, the specimens coated with MAPP showed a 15.7% higher $CO_{peak}$ production rate and the specimens coated with DAPP showed by 8.2% lower rate than that of the uncoated specimen. The veneer coated with ammonium sulfate (AMSF) and DAPP showed a 9.6% and 33.3% lower the peak smoke production rate ($SPR_{peak}$) than that of the uncoated specimen. In addition, the time to the peak smoke extinction area ($SEA_{peak}$) was delayed by 38.4% in the specimens coated with DAPP than the uncoated specimen. Therefore, DAPP inhibited the combustion properties of the veneer and showed a tendency to reduce smoke production.

Effect of the Processing History on the Morphology and Properties of the Ternary Blends of Nylon 6, a Thermotropic Liquid Crystalline Polymer, and a Functionalized Polypropylene

  • Yongsok Seo;Kim, Hyong-Jun;Kim, Byeongyeol;Hong, Soon-Man;Hwang, Seung-Sang;Kim, Kwang-Ung
    • Macromolecular Research
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    • v.9 no.4
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    • pp.238-246
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    • 2001
  • Properties of ternary blends of nylon 6 (Ny6), a thermotropic liquid crystalline polymer (TLCP, poly(ester amide), 20 wt%) and a maleic anhydride grafted polypropylene (2 wt%) (MAPP) were studied under various processing conditions. TLCP was pre-blended with MAPP first and then the binary one blended again with Ny6. The processing temperature of the second mixing was varied. Thermal properties show the partial miscibility of the ternary blend. The morphology of the TLCP phase in the first blending shows mostly in the fibril bundle shape, but varies between droplets and oriented fibrils after the second processing. Some of TLCP phase lost the fibril morphology during the second processing stage. The morphology variation invokes the change in tensile properties. Low extrusion temperature (270$\^{C}$) provides more fibril shapes, which are associated with less deformation in the second stage. The processing temperature effect was more evident when the draw ratio was high. High drawing was applicable due to the stabilizing action of tile compatibilizer.

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