• Bulletin of the Korean Chemical Society
• /
• 제9권4호
• /
• pp.202-206
• /
• 1988

In order to investigate the oligomerization state of the plasma membrane proteolipid apoprotein purified from the bovine kidney, fluorescence polarization experiment was carried out in the two different solvent systems, i.e., water and organic solvent(chloroform-methanol). The molecular volumes of the proteins estimated from the Perrin equation, were to be 45,258$A^3$ and 17,608$A^3$ in water and organic solvent, respectively. These values indicate that a trimerization is possibly occurring in the aqueous environment. As an auxiliary experiment for the calculation of the molecular volume using Perrin equation, fluorescence quenching constants ($K_q$) with the quencher acrylamide and fluorescence lifetimes (${\tau}_F$) of the intrinsic fluorophore tryptophan residue were estimated in the two different solvent systems. $K_q$ in water was 18.21$M^{-1}$ and it was 46.24$M^{-1}$ in organic solvent. Fluorescence lifetimes of tryptophan residue were calculated to be 2.80 nsec. in water and 3.81 nsec. in organic solvent, respectively.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.296-296
• /
• 2014

We investigate experimentally and theoretically the splitting of surface plasmon (SP) resonance peaks under TE- and TM-polarized illumination. The SP structure at infrared wavelength is fabricated with a 2-dimensional square periodic array of circular holes penetrating through Au (gold) film. In brief, the processing steps to fabricate the SP structure are as follows. (i) A standard optical lithography was performed to produce to a periodic array of photoresist (PR) circular cylinders. (ii) After the PR pattern, e-beam evaporation was used to deposit a 50-nm thick layer of Au. (iii) A lift-off processing with acetone to remove the PR layer, leading to final structure (pitch, $p=2.2{\mu}m$; aperture size, $d=1.1{\mu}m$) as shown in Fig. 1(a). The transmission is measured using a Nicolet Fourier-transform infrared spectroscopy (FTIR) at the incident angle from $0^{\circ}$ to $36^{\circ}$ with a step of $4^{\circ}$ both in TE and TM polarization. Measured first and second order SP resonances at interface between Au and GaAs exhibit the splitting into two branches under TM-polarized light as shown in Fig. 1(b). However, as the incidence angle under TE polarization is increased, the $1^{st}$ order SP resonance peak blue-shifts slightly while the splitting of $2^{nd}$ order SP resonance peak tends to be larger (not shown here). For the purpose of understanding our experimental results qualitatively, SP resonance peak wavelengths can be calculated from momentum matching condition (black circle depicted in Fig. 2(b)), $k_{sp}=k_{\parallel}{\pm}iG_x{\pm}jG_y$, where $k_{sp}$ is the SP wavevector, $k_{\parallel}$ is the in-plane component of incident light wavevector, i and j are SP coupling order, and G is the grating momentum wavevector. Moreover, for better understanding we performed 3D full field electromagnetic simulations of SP structure using a finite integration technique (CST Microwave Studio). Fig. 1(b) shows an excellent agreement between the experimental, calculated and CST-simulated splitting of SP resonance peaks with various incidence angles under TM-polarized illumination (TE results are not shown here). The simulated z-component electric field (Ez) distribution at incident angle, $4^{\circ}$ and $16^{\circ}$ under TM polarization and at the corresponding SP resonance wavelength is shown in Fig. 1(c). The analysis and comparison of theoretical results with experiment indicates a good agreement of the splitting behavior of the surface plasmon resonance modes at oblique incidence both in TE and TM polarization.

• 천문학회보
• /
• 제41권2호
• /
• pp.57.2-57.2
• /
• 2016

Polarimetry is an important tool for studying the physical processes in the interstellar medium, including star-forming regions. Polarimetry of young stellar objects and their circumstellar structures provides invaluable information about distributions of matter and configurations of magnetic fields in their environments. However, only a few near-infrared circular polarization (CP) observations were reported so far (before our survey). A systematic near-infrared CP survey has been firstly conducted in various star-forming regions, covering high-mass, intermediate-mass, and low-mass young stellar objects. All the observations were made using the SIRPOL imaging polarimeter on the Infrared Survey Facility (IRSF) 1.4 m telescope at the South African Astronomical Observatory (SAAO). In this presentation, we present the first CP survey results. The polarization patterns, extents, and maximum degrees of circular and linear polarizations are used to determine the prevalence and origin of CP in the star-forming regions. Our results are explained with a combination of circumstellar scattering and dichroic extinction mechanism generating the high degrees of CP in star-forming regions. The universality of the large and extended CPs in star-formaing regions can also be linked with the origin of homochirality of life.

• 천문학회보
• /
• 제43권1호
• /
• pp.51.2-51.2
• /
• 2018

Polarimetry is a powerful technique to investigate the physical properties of surface materials on airless bodies in the solar system. It is known that the degree of linear polarization changes as a function of the phase angle (the angle between Sun-target-Observer). Especially, the dependency of the polarization degree at large phase angle allows us to obtain information related to the particle size and porosity, which is difficult to be determined via other observation techniques (i.e., photometry and spectroscopy). However, despite the advantage, only a few asteroids were observed with polarimetric devices at large phase angles. Here, we present our new polarimetric research of Near-Earth Asteroids (NEAs) observed at the large phase angles. Among the NEAs, we focus on S- and Q-type asteroids, which include: (331471) 1984 QY1, (90075) 2002 VU94, and (66391) 1999 KW4. The observation was conducted using the Pirka 1.6-m Telescope at the Nayoro Observatory of Hokkaido University at the phase angles ${\alpha}{\sim}100degree$, which provides us the maximum polarization degrees of these objects. Considering the observational results together with two objects ((1566) Icarus and (4179) Toutatis) in reference papers [1], [2], we will discuss the implication of the regolith size on their surfaces.

• 한국광학회지
• /
• 제8권6호
• /
• pp.466-470
• /
• 1997

광학 다층박막 증착법으로 비정질 $As_2S_3$를 중간층으로 하고 앞뒷면 거울의 반사율을 다르게 한 비대칭 Fabry-Perot 에탈론을 구성하고 광의 편광에 따른 광쌍안정 현상을 관찰하였다. 사용된 중간층의 광학적 두께는 광원인 $Ar^+$($\lambda $=514.5 nm) 레이저 광에 대하여 2$\lambda$가 되도록 하였다.$Ar^+$레이저의 출력이 80~100 mW일 때 광쌍안정 현상이 관측되었고, 입사되는 광의 각 편광상태에 따라 반사와 투과하는 광의 경향이 서로 다름을 알 수 있었으며, 이는 광의 편광에 따른 비대칭 Fabry-Perot 에탈론내에서의 위상차가 입사광의 세기에 따라 다르기 때문인 것으로 해석되어질 수 있다.

• 한국신뢰성학회지:신뢰성응용연구
• /
• 제17권2호
• /
• pp.122-128
• /
• 2017

Purpose: To investigate the corrosion inhibition effect of the natural spearmint oil extracted from Mentha Spicata plants on 304 stainless steel in different concentrations of hydrochloric acid. Method: The anti-corrosive effect has been investigated in 0.5m, 1m and 2m HCl using weight loss test and electrochemical polarization method as a function of inhibitor concentration and immersion time in strong chloride environment. The surface morphology was analysed by scanning electron microscopy (SEM). Results: The corrosion rate of steel decreased and inhibition efficiency increased with the increase in inhibitor concentration. Microscopic evaluation revealed significant corrosion in the specimens immersed in uninhibited conditions. Potentiodynamic polarization test results showed an increase in corrosion potential (Ecorr) and decrease in corrosion current (icorr) value with increasing concentration of inhibitor. Conclusions: Immersion of steel in higher concentration of inhibitor resulted in greater surface coverage value and hence lesser number of surface corrosion sites/pores were formed; thus lowering the corrosion rate.

• Molecules and Cells
• /
• 제38권10호
• /
• pp.886-894
• /
• 2015

Macrophages are divided into two subpopulations: classically activated macrophages (M1) and alternatively activated macrophages (M2). BCG (Bacilli Calmette-$Gu{\acute{e}}rin$) activates disabled $na{\ddot{i}}ve$ macrophages to M1 macrophages, which act as inflammatory, microbicidal and tumoricidal cells through cell-cell contact and/or the release of soluble factors. Various transcription factors and signaling pathways are involved in the regulation of macrophage activation and polarization. We discovered that BCG-activated macrophages (BAM) expressed a new molecule, and we named it Novel Macrophage Activated Associated Protein 1 (NMAAP1). 1 The current study found that the overexpression of NMAAP1 in macrophages results in M1 polarization with increased expression levels of M1 genes, such as inducible nitric oxide synthase (iNOS), tumor necrosis factor alpha (TNF-${\alpha}$), Interleukin 6 (IL-6), Interleukin 12 (IL-12), Monocyte chemoattractant protein-1 (MCP-1) and Interleukin-1 beta (IL-$1{\beta}$), and decreased expression of some M2 genes, such as Kruppel-like factor 4 (KLF4) and suppressor of cytokine signaling 1 (SOCS1), but not other M2 genes, including arginase-1 (Arg-1), Interleukin (IL-10), transforming growth factor beta (TGF-${\beta}$) and found in inflammatory zone 1 (Fizz1). Moreover, NMAAP1 overexpression in the RAW264.7 cell line increased cytotoxicity against MCA207 tumor cells, which depends on increased inflammatory cytokines rather than cell-cell contact. NMAAP1 also substantially enhanced the phagocytic ability of macrophages, which implies that NMAAP1 promoted macrophage adhesive and clearance activities. Our results indicate that NMAAP1 is an essential molecule that modulates macrophages phenotype and plays an important role in macrophage tumoricidal functions.

• Journal of the Optical Society of Korea
• /
• 제7권4호
• /
• pp.253-257
• /
• 2003

We propose and demonstrate a novel polarization- and wavelength-independent digital electrooptic switch in $Ti:LiNbO_3$ with switching voltage of ${\pm}$32V at $1.55{\mu}m$ wavelength. This $2{\times}2$ integrated optic switch is characterized by a step-like response to the applied voltage. Switching is achieved through adiabatic mode evolution in an asymmetric waveguide junction. An average insertion loss of ∼4.5dB and polarization independent switching with average crosstalk of -12dB are achieved.

• 대한화학회지
• /
• 제56권2호
• /
• pp.264-273
• /
• 2012

Five derivatives of phenylthiourea namely: 1-(4-methoxyphenyl)-3-phenylthiourea (1), 1-(4-methylphenyl)-3- phenylthiourea (2), 1-(4-bromophenyl)-3-phenylthiourea (3), 1-(4-chlorophenyl)-3-phenylthiourea (4) and 1-phenylthiourea (5) have been evaluated as new inhibitors for the corrosion of carbon steel in 2 M HCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic polarization measurements showed that these derivatives are mixed-type inhibitors. The inhibition efficiency was found to increase with inhibitor concentration and decreases with rise in temperature. The thermodynamic parameters of adsorption and activation were determined and discussed. Nyquist plots showed depressed semicircles with their centre below real axis. The adsorption process of studied derivatives on carbon steel surface obeys Temkin adsorption isotherm. The synergistic effect of these derivatives and some anions is discussed from the viewpoint of adsorption models. The electrochemical results are in good agreement with the calculated quantum chemical HOMO and LUMO energies of the tested molecules.

• 대한화학회지
• /
• 제58권2호
• /
• pp.160-168
• /
• 2014

The electrochemical behavior and corrosion inhibition of zinc in 0.5 M $H_2SO_4$ in the absence and presence of some chromones has been investigated using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. The presence of these investigated compounds in the corrosive solutions decrease the weight loss, the corrosion current density, and double layer capacitance but increases the charge transfer resistance. Polarization studies were carried out at room temperature, and showed that all the studied compounds act as mixed type inhibitors with a slight predominance of cathodic character. The effect of temperature on corrosion inhibition has been studied and the thermodynamic activation and adsorption parameters were determined and discussed. The adsorption of the investigated compounds on zinc was found to obey Langmuir adsorption isotherm.