• 한국광학회지
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• 제25권3호
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• pp.131-136
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• 2014

본 논문에서는 짧은 길이의 편광유지 광자결정 광섬유(polarization-maintaining photonic crystal fiber : 이하 PM-PCF)와 3 dB 광섬유 결합기(fiber coupler), 그리고 편광 조절기(polarization controller)로 구성된 사냑(Sagnac) 복굴절 간섭계(birefringence interferometer)를 이용하여 온도에 둔감한 편광 간섭형 스트레인 센서(polarimetric strain sensor)를 구현하였다. 센서부(sensor head)로 사용된 PM-PCF의 길이는 2 cm이었고, 이는 기존의 PM-PCF 기반 편광 간섭형 스트레인 센서들과 비교할 때 가장 짧은 센서부 길이이다. 제안된 센서는 $0{\sim}8m{\varepsilon}$의 범위에 대해서 스트레인 측정을 수행하였으며, ${\sim}0.87pm/{\mu}{\varepsilon}$에 해당하는 스트레인 민감도를 얻을 수 있었다. 또한, 외부 온도를 $30^{\circ}C$에서 $100^{\circ}C$까지 변화시키며 제안된 센서의 온도 의존성을 조사한 결과, 약 $-12pm/^{\circ}C$의 온도 민감도를 얻을 수 있었으며, 이는 기존의 편광 유지 광섬유의 온도 민감도(약 $-990pm/^{\circ}C$) 에 비해 약 82배정도 작은 값이다. 특히, 실용적인 관점에서 센서 표지자(indicator)로 사용되는 파장이 스트레인 민감도에 큰 영향을 주지 않는다는 것을 실험 및 이론적으로 확인하였다.

• Journal of Electrochemical Science and Technology
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• 제13권4호
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• pp.497-503
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• 2022

Spinel ferrites (Ni_xFe_3-xO₄; x = 0.25, 0.5, 0.75 and 1.0) have been prepared at 550℃ by egg white auto-combustion route using egg white at 550℃ and characterized by physicochemical (TGA, IR, XRD, and SEM) and electrochemical (CV and Tafel polarization) techniques. The presence of characteristic vibration peaks in FT-IR and reflection planes in XRD spectra confirmed the formation of spinel ferrites. The prepared oxides were transformed into oxide film on glassy carbon electrodes by coating oxide powder ink using the nafion solution and investigated their electrocatalytic performance for OER in an alkaline solution. The cyclic voltammograms of the oxide electrode did not show any redox peaks in oxygen overpotential regions. The iR-free Tafel polarization curves exhibited two Tafel slopes (b₁ = 59-90 mV decade^-1 and b₂ = 92-124 mV decade^-1) in lower and higher over potential regions, respectively. Ni-substitution in oxide matrix significantly improved the electrocatalytic activity for oxygen evolution reaction. Based on the current density for OER, the 0.75 mol Ni-substituted oxide electrode was found to be the most active electrode among the prepared oxides and showed the highest value of apparent current density (~9 mA cm^-2 at 0.85 V) and lowest Tafel slope (59 mV decade^-1). The OER on oxide electrodes occurred via the formation of chemisorbed intermediate on the active sites of the oxide electrode and follow the second-order mechanism.

• 천문학회보
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• 제25권2호
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• pp.49-49
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• 2000

• 천문학회보
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• 제27권2호
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• pp.32-32
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• 2002

• 천문학회보
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• 제26권2호
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• pp.40-40
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• 2001

• E2M - 전기 전자와 첨단 소재
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• 제10권6호
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• pp.533-540
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• 1997

The microwave dielectric properties of ((P $b_{1-x}$ C $a_{x}$)Zr $O_3$ and (P $b_{0.63}$,C $a_{0.37-x}$ $M_{x}$)Zr $O_3$(M=Mg,Sr) ceramics were investigated. In (P $b_{1-x}$ C $a_{x}$)Zr $O_3$ (X=0.33~0.40) ceramics, high quality factor and small temperature coefficient of resonant frequency were obtain in (P $b_{0.63}$C $a_{0.37}$)Zr $O_3$with perovskite structure. In the case of (P $b_{0.63}$C $a_{0.37-x}$M $g_{x}$)Zr $O_3$ dielectric constant temperature coefficient of resonant frequency increased and quality factor decreased due to increase of polarization of A-O bonding. When replacing Ca ion with Sr ion with large ion radius, polarization decreased with increased of bonding length and thus dielectric constant and temperature coefficient of resonant frequency decreased.decreased.creased.

• E2M - 전기 전자와 첨단 소재
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• 제10권10호
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• pp.1011-1015
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• 1997

In this paper we investigated the electro-optical characteristics of amorphous (a)- twisted nematic (TN)-liquid crystal display(LCD) on polymide (PI) surfaces with different molecular structure. It was found that the domaine size of a-TN-LCD on PI with high polarization is small compared to a-TN-LCD on PI with medium polarization. It is considered that the response time of a-TN-LCd contributes to surface effect between the substrate surfaces and the LC molecules. Finally we obtained that the viewing angle of a-TN-LCD on PI surfaces increases with decreasing the domain size.

• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.369-376
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• 2022

In this study, the stability of an anion exchange membrane water electrolyzer (AEMWE) cell was evaluated in an on-off cycling operation with respect to an applied electric bias, i.e., a current density of 500 mA cm^-2, and an open circuit. The ohmic and polarization resistances of the system were monitored during operation (~800 h) using electrochemical impedance spectra. Specific consideration was given to the ohmic resistance of the cell, especially that of the membrane under on-off cycling conditions, by consistently feeding the cell with KOH solution. Owing to an excess feed solution, a momentary increase in the polarization resistance was observed immediately after the open-circuit. The excess feed solution was mostly recovered by subjecting the cell to the applied electric bias. Stability tests on the AEMWE cell under on-off cycling with continuous feeding even under an open circuit can guarantee long-term stability by avoiding an irreversible increase in ohmic and polarization resistances.

• Journal of Photoscience
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• 제2권2호
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• pp.73-76
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• 1995

The photohydration of 1-(m-nitrophenyl)-5, 5-dimethyl-1, 3-hexadiyne (m-NDHD) affords allenyl ketone compound (1) via triplet excited state which is converted into $\beta$-dicarbonyl compound (2) through thermal hydration. The allenyl ketone is formed by the synchronous addition of water with protonation at C$_1$ indicating that m-NDHD has the reverse polarization and greater electron withdrawing effect in the triplet excited state in comparison with p-NDHD.

• 천문학회보
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• 제41권2호
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• pp.33.1-33.1
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• 2016

We report detection of short-term flux variability in multi-epoch observations and intraday variability in polarized emission at millimeter-wavelength from S5 0716+714 using Korean VLBI Network (KVN) radio telescopes. Over the whole observation epochs, the source shows significant inter-month variations at K- and Q-band with modulation indices of 19% at K-band and 36% at Q-band. In each epoch, the source shows monotonic flux increase in Epoch 1 and 3, and monotonic flux decrease in Epoch 2 and 4. We found an inverted spectrum with mean spectral indices of -0.57 in Epoch 1 and -0.15 in Epoch. On the contrary, we found relatively steep indices of 0.24 and 0.17 in Epoch 2 and Epoch 4, respectively. In the study of intraday variability of polarization, we found significant variations in the degree of linear polarization at 86 GHz, and in polarization angle at 43 and 86 GHz during ~10 h. The spectrum of the source is quite flat with spectral indices of -0.07 to 0.07 at 22-43 GHz and -0.23 to 0.04 at 43-86 GHz. The measured degree of the linear polarization ranges from 2.3% to 3.3 % at 22 GHz, from 0.9% to 2.2 % at 43 GHz and from 0.4 % to 4.0 % at 86 GHz, yielding prominent variations at 86 GHz over 4-5 h. The linear polarization angle is in the range of 4 to $12^{\circ}$ at 22 GHz, -39 to $81^{\circ}$ at 43 GHz, and 66 to 119 at 86 GHz with a maximum rotation of $110^{\circ}$ at 43 GHz over ~4 h. We estimated the Faraday rotation measures (RM) ranging from -9200 to 6300 rad m-2 between 22 and 43 GHz, and from -71000 to 7300 rad m-2 between 43 and 86 GHz, respectively. The frequency dependency of RM was investigated, yielding a mean power-law index, a, of 2.0. This implies that the polarized emission from S5 0716+714 at 22-86 GHz moves through a Faraday screen in or near the jet of the source.