• Bulletin of the Korean Chemical Society
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• 제30권5호
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• pp.1047-1053
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• 2009

The future use of hydrogen as an energy source is expected to increase on account of its environmentally friendliness. In order to enhance the production of hydrogen, Pd ions (0.01, 0.05, 0.1, and 0.5 mol%) were incorporated $TiO_2$ (Pd-$TiO_2$) and used as a photocatalyst. The UV-visible absorbance decreased with increasing level of palladium incorporation without a wavelength shift. Although all the absorption plots showed excitation characteristics, there was an asymmetric tail observed towards a higher wavelength caused by scattering. However, the intensity of the photoluminescence (PL) curves of Pd-$TiO_2$ was smaller, with the smallest case being observed at 0.1 and 0.5 mol% Pd-$TiO_2$, which was attributedto recombination between the excited electrons and holes. Based on these optical characteristics, the evolution of $H_2$ from methanol/water (1:1) photo-splitting over Pd-$TiO_2$ in the liquid system was enhanced, compared with that over pure $TiO_2$. In particular, 2.4 mL of $H_2$ gas was produced after 8 h when 0.5 g of a 1.0 mol% Pd-$TiO_2$ catalyst was used. $H_2$ was stably evolved even after 28 h without catalytic deactivation, and the amount of $H_2$ produced reached 14.5 mL after 28 h. This is in contrast to the case of the Pd 0.1 mol% impregnated $TiO_2$ of $H_2$ evolution of 17.5 mL due to the more decreasedelectron-hole recombination.

• 대한화약발파공학회:학술대회논문집
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• 대한화약발파공학회 2006년도 추계학술발표회 논문집
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• pp.167-184
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• 2006

본 연구는 굴착대상구역에 축사 및 마을주택구조물이 근접위치하고 있어 이들 시설물에 대한 피해 방지를 위해 사전 발파환경영향평가를 실시하였다. 그 결과 발파공법의 적용이 불가하여 소음과 진동저감을 위해 건교부의 발파공법분류에 의한 암파쇄굴착 공법 중, 브레이커에 의한 2차 파쇄가 없는 할암공법의 일종인 슈퍼웨찌(Super wedge) 공법을 적용하였으며, 작업 공종별로 소음전용측정기(SC-310c)와 진동전용측정기 (BLASTMATE)를 이용하여 소음과 진동의 크기를 측정하였다. 측정결과 진동을 기준하면 최근접(약 10m) 위치에서 천공, 절개, 집토 및 상차작업은 가능하나 장비이동이 고려되어야 하며, 소음을 기준하면 절개작업을 제외하고 천공, 집토 및 상차작업은 20m 이내에서도 굴착작업 자체가 어려운 것으로 나타났다. 따라서 건교부 발파공법분류에 의한 암파쇄굴착공법은 작업과정별 소음도를 감안하여 적용되어야 한다.

• 한국수소및신에너지학회논문집
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• 제16권2호
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• pp.130-135
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• 2005

Cadmium selenide is one of the group IIb-VI compounds, which is the promising semiconductor material due to its wide range of technological applications in optoelectronic devices such as photoelectrochemical cells, solid state solar cells, thin film photoconductors etc. CdSe has optical band gap of 1.7-1.8eV and proper conduction band edge for water splitting. CdSe films are coated with small thickness(20-50nm) nanocrystalline $TiO_2$ film by electrodeposition or chemical bath deposition methods and PEC properties of CdSe and CdSe/$TiO_2$ sandwich structure are studied. The photoactivity of CdSe and CdSe/$TiO_2$ films deposited on titanium substrate is studied in aqueous electrolyte of 1M NaOH solution. Photocurrent and photovoltage obtained were of the order of 2-4 mA/$cm^2$ and 0.5V, respectively, under the intensity of illumination of 100 mW/$cm^2$.

• 한국표면공학회지
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• 제51권4호
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• pp.237-242
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• 2018

We report on the fabrication and photoelectrochemical (PEC) properties of a ZnO nanorod array structure as an efficient photoelectrode for hydrogen production from sunlight-driven water splitting. Vertically aligned ZnO nanorods were grown on an indium-tin-oxide-coated glass substrate via seed-mediated hydrothermal synthesis method with the use of a ZnO nanoparticle seed layer, which was formed by thermally oxidizing a sputtered Zn metal thin film. The structural and morphological properties of the synthesized ZnO nanorods were examined using X-ray diffraction and scanning electron microscopy, as well as Raman scattering. The PEC properties of the fabricated ZnO nanorod photoelectrode were evaluated by photocurrent conversion efficiency measurements under white light illumination. From the observed PEC current density versus voltage (J-V) behavior, the vertically aligned ZnO nanorod photoelectrode was found to exhibit a negligible dark current and high photocurrent density, e.g., $0.65mA/cm^2$ at 0.8 V vs Ag/AgCl in a 1 mM $Na_2SO_4$ electrolyte. In particular, a significant PEC performance was observed even at an applied bias of 0 V vs Ag/AgCl, which made the device self-powered.

• 한국자기학회지
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• 제5권5호
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• pp.496-499
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• 1995

Amorphous $Co_{80+x}TM_{12}B_{8-x}$ (TM = Ti, Zr, Hf, Nb and x = 0, 2, 4 at%) alloys were prepared by single roll melt spinning technique. Saturation magnetization of the amorphous ribbons was measured by SQUID and vibrating sample magnetometer from 5 to 800 K under applied fields up to 10 kOe. Typical thermo-magnetization curves were observed and the average values of the spectroscopic splitting g factor were estimated from the ferromagnetic resonance curve. For all the amorphous alloys studied here the saturation magnetization in the temperature range 5 K up to about $0.3T_{c}$ can be described by the Bloch relation: $M_{s}(T)\;=\;M_{s}(0)(1-BT^{3/2}-CT^{5/2})$. From the values of $M_{s}(0)$, B and spectroscopic splitting g factor the spin wave stiffness constants were calculated.

• Asian-Australasian Journal of Animal Sciences
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• 제20권11호
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• pp.1770-1776
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• 2007

Beef carcasses were examined to explore the effects of spinal cord removal and washing on central nervous system tissue (CNST) decontamination of the surface during the slaughtering process. A total of 15 carcasses were split by sawing centrally down the vertebral column and left sides of split carcasses were used for analysis. Samples were collected by swabbing the surface from 4 defined parts on the interior and 4 on the exterior of carcasses from the abattoir and analyzed using an ELISA-based test. The results showed that automatic and manual spray washing decreased CNST contamination, especially on the interior ventral parts of carcass surfaces (p<0.01), but did not decrease CNST on the interior dorsal parts. Increasing washing time to 60 s did not affect the reduction of CNST contamination. Samples following spinal cord removal prior to splitting showed lower calculated levels of "risk material" than the stated limit of detection (0.1%) of the ELISA kit on interior and exterior carcass parts (p<0.01). Therefore, spinal cord removal prior to splitting could be a very effective way to minimize CNST contamination of beef carcasses.

• 한국재료학회지
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• 제30권9호
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• pp.441-446
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• 2020

Synthesizing nanostructured thin films of oxide semiconductors is a promising approach to fabricate highly efficient photoelectrodes for hydrogen production via photoelectrochemical (PEC) water splitting. In this work, we investigate the feasibility as an efficient photoanode for PEC water oxidation of zinc oxide (ZnO) nanostructured thin films synthesized via a simple method combined with sputtering Zn metallic films on a fluorine-doped tin oxide (FTO) coated glass substrate and subsequent thermal oxidation of the sputtered Zn metallic films in dry air. Characterization of the structural, optical, and PEC properties of the ZnO nanostructured thin film synthesized at varying Zn sputtering powers reveals that we can obtain an optimum ZnO nanostructured thin film as PEC photoanode at a sputtering power of 40 W. The photocurrent density and optimal photocurrent conversion efficiency for the optimum ZnO nanostructured thin film photoanode are found to be 0.1 mA/㎠ and 0.51 %, respectively, at a potential of 0.72 V vs. RHE. Our results illustrate that the ZnO nanostructured thin film has promising potential as an efficient photoanode for PEC water splitting.

• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.302-308
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• 2009

This study investigated the production of hydrogen over Ga (1.0, 2.0, and 5.0 mol%)-$TiO_2$ photocatalysts prepared by a solvothermal method. The absorption band was slightly blue-shifted upon the incorporation of the gallium ions, but the intensity of the photoluminescence (PL) curves of Ga-incorporated $TiO_2$s was distinguishably smaller, with the smallest case being the 2.0 mol% Ga-$TiO_2$, which was related to the recombination between the excited electrons and holes. $H_2$ evolution from photo splitting of water over Ga-incorporated $TiO_2$ in the liquid system was enhanced, compared to that over pure $TiO_2$; particularly, the production of 5.6 mL of $H_2$ gas after 8 h when 1.5 g of the 2.0 mol% Ga-incorporated $TiO_2$ was used.

• Structural Engineering and Mechanics
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• 제5권6호
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• pp.803-815
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• 1997

It is well understood that concentrated forces applied in the plane of a beam or panel (such as a wall or slab) lead to splitting forces developing within a disturbed region forming beyond the bearing zone. In a linearly elastic material the length of the disturbed region is approximately equal to the depth of the member. In concrete structures, however, the length of the disturbed region is a function of the orthotropic properties of the concrete-steel composite. In the detailing of steel reinforcement within the disturbed regions two limit states must be satisfied; strength and serviceability (in this case the serviceability requirement being acceptable crack widths). If the design requires large redistribution of stresses, the member may perform poorly at service and/or overload. In this paper the results of a plane stress finite element investigation of concentrated loads on reinforced concrete panels are presented. Two cases are examined (i) panels loaded concentrically, and (ii) panels loaded eccentrically. The numerical investigation suggests that the bursting force distribution is substantially different from that calculated using elastic design methods currently used in some codes of practice. The optimum solution for a uniformly reinforced bursting region was found to be with the reinforcement distributed from approximately 0.2 times the effective depth of the member ($0.2D_e$) to between $1.2D_e$ and $1.6D_e$. Strut and tie models based on the finite element analyses are proposed herein.

• 대한수학회지
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• 제36권1호
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• pp.209-227
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• 1999

We propose new parallel block ILU (Incomplete LU) factorization preconditioners for a nonsymmetric block-tridiagonal M-matrix. Theoretial properties of these block preconditioners are studied to see the convergence rate of the preconditioned iterative methods, Lastly, numerical results of the right preconditioned GMRES and BiCGSTAB methods using the block ILU preconditioners are compared with those of these two iterative methods using a standard ILU preconditioner to see the effectiveness of the block ILU preconditioners.