• 제목/요약/키워드: Luminescent centers

검색결과 11건 처리시간 0.025초

$Cr^{3+}$ Luminescent centers in $BeAl_6O_{10}$ crystal

  • Wu, Guang-Zhao;Uk Kang
    • KIEE International Transactions on Electrophysics and Applications
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    • 제11C권4호
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    • pp.138-141
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    • 2001
  • The fluorescence emission spectrum of Cr$^{3+}$ doped BeAl$_{6}$ O$_{10}$ crystals at 300 K contains a broad band, three R-like lines and another emission lines. It has been identified by a lifetime resolution spectroscopic technique that there are three kinds of single-Cr$^{3+}$ centers, Cr(I), Cr(II), Cr(III), in this crystal. Cr(I) and Cr(II) are high-crystal field centers responsible for the three main "R-lines", and Cr(III) is a low-crystal field center responsible for the main broad band emission. The structures of these luminescent centers are reported.ted.

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CuCl 농도에 따른 SrS:CuCl 박막 전계발광소자의 발광특성 (Luminescent Characteristics of SrS:CuCl Thin-Film Electroluminescent(TFEL) Devices on CuCl Concentrations)

  • 이순석;임성규
    • 대한전자공학회논문지SD
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    • 제39권8호
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    • pp.17-23
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    • 2002
  • 전자빔 증착 장비를 이용하여 SrS:CuCl TFEL 소자를 제작한 후, 발광특성을 조사하였다. 형광체 모체는 SrS 분말을 사용하였고, 발광중심체로는 CuCl 분말을 0.05 ~ 0.6 at% 범위에서 첨가하였다. 증착 온도 500℃, 전자빔 전류 20 ~ 40 mA 및 증착율 5 ~ 10 /sec의 조건에서 형광층 두께를 6000 으로 증착시켰다. CuCl 농도가 낮을 때에는 monomer, dimer, trimer 및 tetramer 발광센터에 의한 청색 발광을 확인할 수 있었으나 휘도가 낮았다. CuCl 농도가 높을 때에는 dimer와 trimer 발광센터에 의한 밝은 녹청색 빛을 방출하였다. 최적의 발광특성은 CuCl 농도를 0.2 at% 첨가한 SrS:CuCl TFEL 소자에서 관찰되었으며, 문턱전압, 휘도(L/sub 40/), 효율(η/sub 20/) 및 CIE 색좌표는 각각 55 V, 728 cd/㎡, 0.49 lm/W 및 (0.21, 0.33)을 나타내었다.

$Mg_xZn_{1-x}SiN_2$를 모체로 한 박막 전계발광소자용 형광체의 발광특성 (Luminescent Characteristics of $Mg_xZn_{1-x}SiN_2$ Based Phosphors for Thin Film Electroluminescent Device Applications)

  • 이순석;임성규
    • 전자공학회논문지D
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    • 제34D권2호
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    • pp.27-37
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    • 1997
  • Photoluminescent and cathodoluminescent charcteristics of inorganic luminescent materials were investigated ot develop possible phosphors for thin film electroluminescent (TFEL) device applications. Mg, Zn, and Photoluminescent and cathodoluminescent charcteristics of inorganic luminescent materials were investigated ot develop possible phosphors for thin film electroluminescent (TFEL) device applications. Mg, Zn, and $Si_3N_4$ powders were used to synthesize $(Mg_xZn_{1-x})SiN_2$ host materials. $Tb_4O_7$ and $Eu_2O_3$ powdrs were added as luminescent centers. Very sharp emission spectra of $Tb^{3+}$ ions were observed from $Mg._5Zn._5SiN_2:Tb$ sampels sintered at $1400^{\circ}C$ for an hour and the maximum intensity of emission spectra occured at wavelength of 550nm (green light). Synthetic conditions of $(Mg_xZn_{1-x})SiN_2:Eu$ phosphors were optimized for the hghest luminescence. The Eu concentrations were varied from 0.2% to 1.6%. Before firing, the powders were mixed using ballmills, methanol, acetone, or D.I. water. The Mg/Zn ratio also were varied from x=0.3 to x=0.7. The maximum PL intensity was obtained from a sample with 1.2% Eu concentration and the powder was mixed with methanol and dried before firing. The maximum intensity of the emission spectra occurred t the wavelength of 470nm(blue light). TFEL devices fabricated by using sputter deposition of $(Mg._3Zn._7)SiN_2:Eu$ phosphor layer showed yellowish white emission at the phosphor field of 2MV/cm.

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A Series of 3D Lanthanide Complexes Containing (La(III), Sm(III) and Gd(III)) Metal-organic Frameworks: Synthesis, Structure, Characterization and Their Luminescent Properties

  • Zhang, Huai-Min;Yang, Hao;Wu, Lan-Zhi;Song, Shuang;Yang, Li-Rong
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3777-3787
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    • 2012
  • Three kinds of 3D isomorphous and isostructural coordination polymers, namely, $\{[Ln_2(PDA)_3(H_2O)_3]{\cdot}0.25H_2O\}_{\infty}$ (Ln = La(1), Sm(2), and Gd(3)) ($PDA^{2-}$ = pyridine-2,6-dicarboxylate anion) have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectroscopy, thermal analyses and single crystal X-ray diffraction. In these MOFs, Ln(III) centers adopt eight-coordinated and nine-coordinated with the $N_1O_7$ and $N_2O_7$ donor sets to construct distorted trianglar dodecahedron geometry and tricapped trigonal prism configurations, respectively. Based on the building block of tetranuclear homometallic $Ln_4C_4O_8$ unit (16-membered ring), 1-3 are connected into highly ordered 2D sheets via O-C-O linkers and further constructed into 3D architectures through hydrogen bonds. Crystallographic parameters suggest that the lanthanide contraction effect exist in these coordination polymers. Luminescent properties of the lanthanide-based MOFs (metal-organic frameworks) have been measured at room temperature, which reveal that they presenting ionselective characters toward certain metals, such as $Mg^{2+}$, $Cd^{2+}$ and $Pb^{2+}$ ions.

Construction of Luminescence- and Fluorescence-Tagged Burkholderia pseudomallei for Pathogen Tracking in a Mouse Model

  • Shin, Yong-Woo;Park, Deok Bum;Choi, Myung-Min;Chun, Jeong-Hoon;Seong, Baik-Lin;Rhie, Gi-Eun
    • Journal of Microbiology and Biotechnology
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    • 제28권3호
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    • pp.498-502
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    • 2018
  • Molecular imaging is a powerful method for tracking various infectious disease-causing pathogens in host organisms. Currently, a dual molecular imaging method that can provide temporal and spatial information on infected hosts at the organism, organ, tissue, and cellular levels simultaneously has not been reported for Burkholderia pseudomallei, a high-risk pathogen that causes melioidosis. In this study, we have established an experimental method that provides spatiotemporal information on infected hosts using luminescent and fluorescent dual-labeled B. pseudomallei. Using this method, we visualized B. pseudomallei infection at the organism, organ, and tissue levels in a BALB/c mouse model by detecting its luminescence and fluorescence. The infection of B. pseudomallei at the cellular level was also visualized by its emitted fluorescence in infected macrophage cells. This method could be an extremely useful and applicable tool to study the pathogenesis of B. pseudomallei-related infectious diseases.

우리나라 응급의료센터 응급구조사의 직업적 방사선 노출 (Occupational Radiation Exposure of Emergency Medical Technicians in Emergency Medical Centers in Korea)

  • 이현경;박정임
    • 한국산업보건학회지
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    • 제27권3호
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    • pp.170-179
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    • 2017
  • Objectives: This study aims to investigate the occupational radiation exposures of emergency medical technicians(EMTs) in emergency medical centers in Korea. The results will provide a basis for developing prevention programs to minimize adverse health effects relating to radiation exposure among emergency medical technicians working in this area. Methods: Radiation exposure doses were measured for twenty-two EMTs working in six emergency medical centers. Thermo Luminescent Dosimeters(TLD) were placed on three representative body parts, including chest, neck, and a finger. Measurements were conducted over the entire working hours of the participants for foor weeks. Dosimeters were analyzed according to a standard method by a KFDA-designated lab. Detection rate, annual radiation exposure dose, and relative levels to dose limit were derived based on the measured doses from the dosimeters. SPSS/Win 18.0 software(IBM, US) was used for statistical analysis. Results: Detection rates were 45.5%, 36.4%, and 45.5% for the dosimeters sampled from chest, neck, and a finger, respectively. The average annual doses were $2.39{\pm}3.44mSv/year$(range 0.38-10.0 mSv/year) for the chest, $2.72{\pm}3.05mSv/year$(2.00-11.34) for the neck, and $20.98{\pm}17.57mSv/year$(1.25-53.50) for the hand dose. The average annual eye dose was estimated to $3.61{\pm}2.37mSv/year$(1.50-8.34). The exposure dose levels of EMTs were comparable to those of radiologists, who showed relatively higher radiation dose among health care workers, as reported in another study. Conclusions: EMTs working in emergency medical centers are considered to be at risk of radiation exposure. Although the radiation exposure dose of EMTs does not exceed the dose limit, it is not negligible comparing to other professionals in health care sectors.

A study on the characteristics of SrS:Cu TFEL devices prepared by hot wall deposition

  • Lee Sang-Tae
    • Journal of Advanced Marine Engineering and Technology
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    • 제30권4호
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    • pp.514-519
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    • 2006
  • SrS:Cu, Cl thin films have been grown by the hot wall technique with S furnace placed on the outside of the growth chamber in order to investigate the crystallographic and optical characteristics. The films have a good crystallinity independent of CuCl wall temperature and PL characteristics showed a peak assigned by the transition form $3d^94s^1\;(^3Eg)$ to $3d^{10}\;(^1A_{1g})$ of $Cu^+$ center. It has also been found that. from the PLE spectra, $Cu^+$ luminescent centers are doped in the host materials. The EL emission from SrS:Cu-based device showed a greenish-blue but shifted to short wavelength compared to SrS:Ce-based EL. The device was obtained the maximum luminance of $110cd/m^2$ and the maximum luminous efficiency of $0.1\;lm/W$ at $V_{40}$.

우편물 자도처리 촉진을 위한 우편용 고객 바코드 검증 시스템 (The Verification System of the Customer Barcode for the Advanced Automatic Processing of the Mail Items)

  • 박문성;송재관;우동진
    • 한국정보처리학회논문지
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    • 제6권4호
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    • pp.968-976
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    • 1999
  • 현재 유편봉투의 상태를 점검한 후, 우편 자동처리 센터(우편집 중국)에서 거의 대부분 OCR(Optical Character Recognition)로 우편주소 및 우편번호를 판독하여 3 of 5 형광(발광) 바코드로 7자리를 인쇄하고, 바코드 구분기(Barcode Sorter)에서 우편물을 자동구분 처리하고 있다. 일반적으로 자동처리 중에 우편주소 및 우편번호 잘못 기재, 주소 및 바코드 인쇄품질의 불량 등에 의하여 오류로 구분되어지는 우편 물량은 전체 우편물량의 31∼35%를 차지하고 있다. 본 논문에서는 이러한 문제점을 해결하기 위하여 도입될 고객 바코드 인쇄제도를 지원하기 위한 우편용 3 of 5 고객 바코드 및 우편주소 검증시스템을 개발하였다. 고객 바코드 검증시스템은 정해진 규격에 의해 고객 바코드가 정확하게 인쇄되었는지 검사하는 검증자 3 of 5 고객 바코드 검증시스템, 바코드 판독결과에 의하여 우편주소가 올바르게 작성되었는지 검사하는 우편주소 검증시스템을 제공하는 것이다.

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$Er^{3+}$를 첨가한 $CaZrO_3$ 축광성 형광체의 합성 및 발광 특성 분석 (Synthesis and luminescent properties of $Er^{3+}$ doped $CaZrO_3$ long persistent phosphors)

  • 박병석;최종건
    • 한국결정성장학회지
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    • 제18권1호
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    • pp.27-32
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    • 2008
  • 새로운 $CaZrO_3:Er^{3+}$ 축광성 형광체를 전통적인 고상반응법으로 제조하였으며, 분쇄한 축광성 형광체를 X 선 회절 분석, 광발광 분석, 열발광 분석과 휘도계를 통하여 장잔광 특성을 분석하였다. X 선 회절 분석 결과 순수한 $CaZrO_3$ 결정상을 확인 하였으며, 고온의 질소 분위기에서 합성한 경우 446 nm 와 550 nm의 넓은 발광 피크가 나타났다. 합성한 장잔광 특성의 형광체의 발광 지속시간은 254 nm UV lamp로 여기 시킨 후 어두운 곳에서 6시간 이상 스스로 발광 하였다. 발광 피크는 $Er^{3+}$ 이온의 $^5D_{5/2}{\rightarrow}^4F_{9/2},\;^2H_{12/2},\;^4S_{3/2}{\rightarrow}^4I_{13/2}$ 그리고 $^2G_{9/2}{\rightarrow}^4I_{13/2}$ 전이에 의한 것이며, 잔광 특성은 $CaZrO_3$ 격자 내에 적당한 trap center가 형성 된 것으로 판단된다.

우편물 처리원가 절감을 위한 고객 바코드 지원 시스템 (Customer Barcode Support System for the Cost Saving of Mail Items)

  • 황재각;박문성;송재관;우동진
    • 한국정보처리학회논문지
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    • 제6권10호
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    • pp.2563-2573
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    • 1999
  • 현재 우편집중국에서는 우편불 자동처리를 위하여 광학문자판독기예 의하여 우편물의 우편번호 인식하고, 인식된 우편번 호에 의하여 형광바코드를 인쇄한다 그리고 이 형광바코드를 판독하여 우편물을 자동구분 처리하고 었다. 이 자동구분처리 과정에서 오류우편툴 중에서 대부분은 우편주소를 기반으로 하는 우편번호와 기재와 특정 글꼴 및 흘립체로 기재된 우편변 호의 인식율 저하, 인쇄 품질의 저하에 따른 판독 불능 등이 주요한 원인이다 이러한 문제점을 해결하기 위해 고객 바코드 인쇄 제도를 도입하고 정확한 우편주소에 의한 우편번호를 사용할 수 있도록 지원하여, 우편물 자동처리 향상을 위한 노력 이 요구되고 있다. 본 논문에서는 우편물 주소를 이용한 우편번호 검출, 우편번호 변경시 우편번호 관리, 고객바코드 인쇄 동을 지원할 수 있는 고객 바코드 지원 시스템을 개발한 것이다. 이 고객 바코드 지원 시스템을 우편 이용자들에게 배포하여 사용할 수 있 도록 함으로써 우편물 자동처리 촉진을 도모하기 위해 개발한 시스템이다.

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