• Title/Summary/Keyword: Lower Flammability Limit

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An Experimental Study on Flammability Limits and Combustion Characteristics of Synthetic Gas in a Constant Combustion Chamber (정적연소기를 이용한 합성가스의 가연한계 및 연소특성에 관한 실험적 연구)

  • Cho, Yong-Seok;Lee, Seang-Wock;Won, Sang-Yeon;Park, Young-Joon;Kim, Duk-Sang
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.14-21
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    • 2008
  • Synthetic gas is defined as reformed gas from hydrocarbon-based fuel and the major chemical species of the synthetic gas are $H_2$, CO and $N_2$. Among them, hydrogen from synthetic gas is very useful species in chemical process such as combustion. It is a main reason that many studies have been performed to develop an effective reforming device. Furthermore, other technologies have been studied for synthetic gas application, such as the ESGI(Exhaust Synthetic Gas Injection) technology. ESGI injects and burns synthetic gas in the exhaust pipe so that heat from hydrogen combustion helps fast warmup of the close-coupled catalyst and reduction of harmful emissions. However, it is very hard to understand combustion characteristic of hydrogen under low oxygen environment and complicated variation in chemical species in exhaust gas. This study focuses on the characteristics of hydrogen combustion under ESGI operating conditions using a CVC(Constant Volume Chamber). Measurements of pressure variation and flame speed have been performed for various oxygen and hydrogen concentrations. Results have been analyzed to understand ignition and combustion characteristics of hydrogen under lower oxygen conditions. The CVC experiments showed that under lower oxygen concentration, amount of active chemicals in the combustion chamber was a crucial factor to influence hydrogen combustion as well as hydrogen/oxygen ratio. It is also found that increase in volume fraction of oxygen is effective for the fast and stable burning of hydrogen by virtue of increase in flame speed.

An Experimental Study on the Combustion Phenomena in Porous Media (다공질 내부의 연소현상에 대한 실험적 연구)

  • Lee, Yong-Il;Sin, Hyeon-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.1
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    • pp.321-327
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    • 1996
  • Experiments were performed on the laminar premixed flame stabilized in a porous medium to know whether the flame downstream of the combustor exists or not. In previous theoretical studies, a stable flame has been predicted in the downstream region of the combustor, but it has never been observed in experiments. In this study, a stable downstream flame could be obtained for the lower burning velocity through circumferential heating by a blue flame positioned outside the periphery of the specially devised combustor. The existence of the stable downstream flame was confirmed by a direct photography of soot line, and temperature measurements. The effect of combustor diameter to flame stability was also considered. As the diameter of the combustor increases, the lean flammability limit was extended.

Explosion Characteristics of Nonhomogeneous LPG-Air Mixtures (농도 불균일 LPG-공기 혼합기체의 폭발특성)

  • 배정일;김영수;서용칠;신창섭
    • Journal of the Korean Society of Safety
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    • v.8 no.4
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    • pp.114-119
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    • 1993
  • The explosion characteristics of nonhomogeneous LPG-Air mixtures was measured in a cylindrical vessel and a pipe. The maximum explosion pressure, the maximum rate of explosion pressure rise, and the flame propagation velocity were measured and compared with that of homogeneous explosion by changing the effective factors on the explosion of nonhomogeneous mixtures such as pressure difference, effusion time and delay time. Explosion was occured even in the lower concentration than the lean flammability limit of mixture. The maximum explosion pressure was increased with increase of LPG concentration, however, the maximum explosion pressure rise was not in the nonhomogeneous explosion. An d the flame propagation velocity was decreased with nonhomogeneity, however, the maximum explosion pressure was always above 0.7kg/$\textrm{cm}^2$.

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A Study on the Lean Combustion Characteristics with Variation of Combustion Parameter in a Gasoline Direct Injection Engine (직접분사식 가솔린 엔진의 연소제어인자에 따른 희박연소 특성 연구)

  • Park, Cheol-Woong;Oh, Jin-Woo;Kim, Hong-Suk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.4
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    • pp.39-45
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    • 2012
  • Today gasoline engines for vehicular application are not only faced with stringent emission regulation but also with increasing requirements to better fuel economy, while guaranteeing power density. The spray-guided type gasoline direct injection (GDI) engine has an advantage of improved thermal efficiency and lower harmful emissions. Centrally mounted high pressure injector and adjacent spark plug allow stable lean combustion due to the flexible mixture stratification. In the present study, the performance and emissions characteristics of developed spray-guided type GDI combustion system were evaluated at various excess air ratio conditions. The specific fuel consumption and nitrogen oxides ($NO_x$) emissions were reduced due to the achievement of stable lean combustion under flammability limit. Multiple injection strategy was not helpful to improve fuel consumption while further reduction of $NO_x$ emissions was possible.

Verification on Separation Distance Criteria when Transporting Dangerous Goods in Korea Railroad (국내 철도 위험물 운송 시 격리차 운영기준 안전성 검증)

  • Lee, Byeongwoo;Park, Dasung;Kang, Taesun;Jung, Seungho
    • Journal of the Korean Society of Safety
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    • v.34 no.2
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    • pp.28-33
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    • 2019
  • After the Tianjin Port explosion on 2015, it is highlighted that securing safety for dangerous goods in Korea and try to establish safety standards for railroad dangerous substances transport. In Korea, the regulation for the transport of dangerous goods is stipulated to need 3 buffer cars. However, It is inefficient that 3 buffer cars. because 3 buffer cars, increase transportation too much costs in transit and it is too strict compared to other country rules. The purpose of this study was to improve transportation efficiency by mitigating the criteria for isolated railroads through rational safety assessment. In order to verify this, we used a risk assessment software which is PHAST 7.2 developed by DNV GL. We calculated safety distances that could prevent ignitions setting up scenarios when relief system work installed on a train loaded with propylene, nonane. As a result, we confirmed that buffer cars can be reduced from three to one. This result would be implemented in the application of Korail.

A Numerical Study on Ventilation Characteristics of Factors Affecting Leakages in Hydrogen Ventilation (누출 수소 환기에 영향을 미치는 요인별 환기 특성에 관한 수치해석적 연구)

  • Lee, Chang-Yong;Cho, Dae-Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.4
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    • pp.610-619
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    • 2022
  • Hydrogen is emerging as an alternative fuel for eco-friendly ships because it reacts with oxygen to produce electrical energy and only water as a by-product. However, unlike regular fossil fuels, hydrogen has a material with a high risk of explosion due to its low ignition point and high flammability range. In order to safely use hydrogen in ships, it is an essential task to study the flow characteristics of hydrogen leakage and diffusion need to be studied. In this study, a numerical analysis was performed on the effect of leakage, ventilation, etc. on ventilation performance when hydrogen leaks in an enclosed space such as inside a ship. ANSYS CFX ver 18.1, a commercial CFD software, was used for numerical analysis. The leakage rate was changed to 1 q, 2 q, and 3 q at 1 q = 1 g/s, the ventilation rate was changed to 1 Q, 2 Q and 3 Q at 1 Q = 0.91 m/s, and the ventilation method was changed to type I, type II, type III to analyze the ventilation performance was analyzed. As the amount of leakage increased from 1 q to 3 q, the HMF in the storage room was about 2.4 to 3.0 times higher. Furthermore, the amount of ventilation to reduce the risk of explosion should be at least 2 Q, and it was established that type III was the most suitable method for the formation of negative pressure inside the hydrogen tank storage room.

Frequency-Equivalence Ratio Correlation Analysis of Methane-Air Premixed Flame Influenced by Ultrasonic Standing Wave (I) (정상초음파의 영향을 받는 메탄-공기 예혼합화염의 주파수-당량비 상관도 분석(I))

  • Kim, Min Sung;Kim, Jeong Soo;Koo, Jaye;Kwon, Oh Chae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.4
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    • pp.37-44
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    • 2015
  • An experimental study was performed for the analysis of frequency-equivalence ratio correlation in the methane-air premixed flame influenced by ultrasonic standing wave. Evolutionary features of the propagating flame were caught by high-speed camera, and the variation of flame-behavior including local velocities was investigated in detail using a post-processing analysis of the high-speed images. It was found that propagation-velocity augmentation of the methane-air premixed flame by the intervention of ultrasonic standing wave was made in leaner mixture, but the velocity diminished when the strength of chemical reaction was saturated around the slightly fuel-rich side of stoichiometry.

Numerical Study on Atmospheric Dispersion and Fire Possibility in Toluene Leakage (톨루엔 누출 시 대기확산 및 화재가능성에 관한 수치해석 연구)

  • Ko, Jae Sun;Kim, Joo-Seok
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.1-10
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    • 2017
  • This study examined the risk of accidents when handling hazardous materials in hazardous materials storage facilities without safety facilities. In the case of illegal dangerous cargo containers, the burning rate is very fast in the case of fire, which leads to explosions, that are damaging and difficult to control. In addition, accidents that occur in flammable liquid hazardous materials are caused mostly by accidents that occur in the space due to leakage. Therefore, the variables that affect these accidents were derived and the influence of these variables was investigated. Numerical and computational fluid dynamics programs were used to obtain the following final results. First, when a flammable liquid leaks into a specific space, it is influenced by temperature and relative humidity until a certain concentration (lower limit of combustion) is reached. In the case of temperature, it was found that the reaching time was shorter than the flash point In addition, the effect of variables on pool fire accidents of leakage tanks is somewhat different, but the variables that have the largest influence are the wind speed. Therefore, it is expected that the results of this study will be used as basic data for similar numerical analysis and it will provide useful numerical information about the accidental leakage of hazardous materials under various research conditions.

Effect of Pressure and Stoichiometric Air Ratio on NOx Emissions in Gas-Turbine Dump Combustor with Double Cone Burner (이중원추형 모형연소기에서 압력과 공기비에 따른 NOx 배출특성)

  • Nam, Dong-Hyun;Nam, Hyun-Su;Han, Dong-Sik;Kim, Gyu-Bo;Cho, Seung-Wan;Kim, Han-Suk;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.3
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    • pp.251-257
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    • 2012
  • This work presents an experimental investigation of NOx emissions according to inlet air temperature (550-660 K), stoichiometric air ratio (${\lambda}$, 1.4-2.1), and elevated pressure (2-5 bar) in a High Press Combustor (HPC) equipped with a double cone burner, which was designed by Pusan Clean Coal Center (PC3). The exhaust-gas temperature and NOx emissions were measured at the end of the combustion chamber. The NOx emissions generally decreased as a function of increasing ${\lambda}$. On the other hand, NOx emissions were influenced by ${\lambda}$, inlet air temperature and pressure of the combustion chamber. In particular, when the inlet air temperature increased, the flammability limit was extended to leaner conditions. As a result, a higher adiabatic temperature and lower NOx emissions could be achieved under these operation conditions. The NOx emissions that were governed by thermal NOx were greatly increased under elevated pressures, and slightly increased at sufficiently low fuel concentrations (${\lambda}$ >1.8).

Dispersion Characteristics of Hydrogen Gas by the Effect of Leakage Hole Size in Enclosure Space (누출공 크기에 따른 밀폐공간 내 수소 가스의 확산 특성)

  • Choi, Jinwook;Li, Longnan;Park, Chul-Woo;Lee, Seong Hyuk;Kim, Daejoong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.5
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    • pp.26-35
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    • 2016
  • As a potential clean energy resource, the production and consumption of hydrogen gas are expected to gradually increase, so that hydrogen related studies are also increasing. The thermal and chemical properties of hydrogen result in its high flammability; in particular, there is a high risk if leaks occur within an enclosed space. In this study, we applied the computational fluid dynamics method to conduct a numerical study on the leakage behavior of hydrogen gas and compared these numerical study results with an experimental study. The leakage hole diameter was selected as an important parameter and the hydrogen gas dispersion behavior in an enclosed space was investigated through various analytical methods. Moreover, the flammable regions were investigated as a function of the leakage time and leakage hole size. We found that the growth rate of the flammable region increases rapidly with increasing leakage hole size. We also investigated the relation between the mass flow rate and the critical time when the hydrogen gas reaches the ceiling. The analysis of the monitoring points showed that the hydrogen gas dispersion behavior is isotropic and independent of the geometry. We found that the concentration of gas in an enclosed space is affected by both the leakage flow rate and amount of gas accumulated in the enclosure.