• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.173-182
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• 2012

Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

• 한국수소및신에너지학회논문집
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• 제25권1호
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• pp.79-86
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• 2014

In Dimethyl Ether (DME) indirect production processes, DME have a reforming process to separate Methanol. DME has a high cetane number and Methanol has a high octane number. Each fuel has a different combustion characteristics and reactivity. So, this paper was investigated on the combustion characterisitics of DME and Methanol. Basically, Methanol has a effect of retarding ignition. However, Within 10% of total carbon mole number in DME, Methanol slightly changed the onset timing of Low Temperature Reaction (LTR) with increasing thermal-ignition preparation range. It means that controlling combustion phasing of DME can be possible without eliminated LTR. In case of IMEP, the ranges.

• Korean Chemical Engineering Research
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• 제49권6호
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• pp.857-864
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• 2011

순산소연소는 높은 연소 효율과 적은 배가스량, 낮은 질소산화물 농도를 장점으로 하고 있으며 연소온도 조절을 위한 배가스 재순환에 의해 배출되는 연소가스중의 $CO_2$ 농도를 95%까지 농축이 가능하므로 석탄 연소설비에 대한 유망한 CCS 기술로 부각되고 있다. 본 연구는 순산소연소 조건에서 배가스의 재순환을 통한 $CO_2$ 농도 증가에 기인하는 직접 황화반응이 탈황효율에 미치는 영향을 평가하고 반응온도, $CO_2$ 농도, $SO_2$ 농도상승이 $SO_2$ 제거효율에 미치는 영향과 배가스 중 수분 등이 $SO_2$ 제거효율에 미치는 영향을 실험적으로 고찰하였다. 반응온도 $1,200^{\circ}C$까지 온도 상승에 따라 $SO_2$의 제거효율은 증가하였고 Ca/S비, $CO_2$ 농도와 수분이 증가할수록 $SO_2$ 제거효율이 증가하였다. 이러한 운전변수는 영향인자 평가를 통하여 Ca/S 비>체류시간>$O_2$농도>반응온도>$SO_2$농도>$CO_2$농도>수분농도의 순으로 탈황반응에 영향을 미치는 것으로 나타났다. 또한 운전변수별 실험결과를 이용하여 로내 건식탈황에 있어서 각 운전변수별 성능 영향인자를 평가할 수 있는 반경험적 모델식을 도출하였다.

• 오토저널
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• 제25권2호
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• pp.35-38
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• 2003

• 청정기술
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• 제12권2호
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• pp.78-86
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• 2006

저발열량 석탄 및 바이오매스 합성가스의 가스 엔진 내 연소 특성에 대한 전산 해석을 수행하였다. 열화학적 해석을 통해 연소 압력, 연소 온도, 배기가스의 조성, NO 배출량 및 엔진 출력을 예측하였고, 예측결과를 소형 파이로트 가스 엔진 시험결과와 비교하였다. 합성 가스의 가스 엔진 연소실 내부의 비정상 연소 현상을 규명하기 위해 전산유체역학적 해석을 수행하였고, 석탄 및 바이오매스 합성가스의 계산결과들을 서로 비교하여 대체연료로서 합성가스 연소 시 가스엔진에 대한 설계 변경 및 조절을 위한 기준을 제시하였다.

• Bulletin of the Korean Chemical Society
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• 제31권1호
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• pp.120-124
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• 2010

Monometallic, bimetallic and trimetallic particles consisting of different weight compositions of Pt-Pd-Rh over pure alumina wash coats have been synthesized and their catalytic performance on methane conversion was studied from 150 to $600^{\circ}C$. Different catalyst formulations with variable Pt, Pd and Rh contents for bimetallic and trimetallic systems were tried and $Pt_{(1.5)}Rh_{(0.3)}/Al_2O_3$ and $Pt_{(1.0)}Pd_{(1.0)}Rh_{(0.3)}/Al_2O_3$ shows low $T_{50}$ and $T_{90}$ temperatures. Bimetallic and trimetallic particle synergism acts as three way catalysts and therefore, all the catalysts show 100% methane conversion. The effect of supports such as $ZrO_2$ and $TiO_2$ on methane combustion was investigated; from $T_{50}$ and $T_{90}$ results both $Al_2O_3$ and $ZrO_2$ are suitable supports for low temperature methane combustion.

• 수산해양기술연구
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• 제55권4호
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• pp.411-418
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• 2019

In this study, to investigate the effect of physical and chemical properties of butanol on the engine performance and combustion characteristics, the coefficient of variations of IMEP (indicated mean effective pressure) and fuel conversion efficiency were obtained by measuring the combustion pressure and the fuel consumption quantity according to the engine load and the mixing ratio of diesel oil and butanol. In addition, the combustion pressure was analyzed to obtain the pressure increasing rate and heat release rate, and then the combustion temperature was calculated using a single zone combustion model. The experimental and analysis results of butanol blending oil were compared with the those of diesel oil under the similar operation conditions to determine the performance of the engine and combustion characteristics. As a result, the combustion stabilities of D.O. and butanol blending oil were good in this experimental range, and the indicated fuel conversion efficiency of butanol blending oil was slightly higher at low load but that of D.O. was higher above medium load. The premixed combustion period of D.O. was almost constant regardless of the load. As the load was lower and the butanol blending ratio was higher, the premixed combustion period of butanol blending oil was longer and the premixed combustion period was almost constant at high load regardless of butanol blending ratio. The average heat release rate was higher with increasing loads; especially as butanol blending ratio was increased at high load, the average heat release rate of butanol blending oil was higher than that of D.O. In addition, the calculated maximum. combustion temperature of butanol blending oil was higher than that of D.O. at all loads.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 2003년도 유체기계 연구개발 발표회 논문집
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• pp.63-72
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• 2003

In order to reduce NOx emissions in the 20kW class microturbine under development, the low NOx characteristics, as being an application to the lean premixed combustion technology, have been investigated. The study has been conducted at the conditions of high temperature and high pressure. Theair from a compressor with the pressure of 2.5bar, 3.0bar, 3.5bar was supplied to the combustor with the temperature 560K through the air preheat-treatment. The sampling exhaust gas was measured at the immediate exit of the combustor. For the effect of temperature on NO and CO emissions, though NOx were increased, CO was decreased with increasing inlet air temperature. With increasing inlet air pressure, NOx were increased and CO was decreased also. NOx were decreased, but CO was increased with increasing inlet air mass flow rate. The test has been performed on the equivalent ratio of 0.10 to 0.16 in the lean region. NOx were increased with increasing equivalent ratio, but CO was decreased as an influence of flame temperature. CFD work with an appropriate combustion model predicated a complicated swirling flow pattern in the combustor, and also produced a numerical value of NOx and CO emissions which was to be compared with the experimental one. As the results of this study, NOx are expected to be reduced to less than 42ppm at 15% O2 when operated at the design condition of the 20kW class microturbine.

• 청정기술
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• 제22권4호
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• pp.299-307
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• 2016

These days, coal is one of the most important energy resources used for transportation, industry, and electricity. There are two types of coal: high-rank and low-rank. Low-rank coal has a low calorific value and contains large amounts of useless moisture. The quality of low-rank coal can be increased by simple drying technology and it needs to be stabilized by hydrocarbons (e.g. palm acid oil, PAO) to prevent spontaneous combustion and moisture re-adsorption. Spontaneous combustion becomes a major problem during coal mining, storage, and transportation. It can involve the loss of life, property, and economic value; reduce the quality of the coal; and increase greenhouse gas emissions. Besides spontaneous combustion, moisture re-adsorption also leads to a decrease in quality of the coal due to its lower heating value. In this work, PAO was used for additive to stabilize the upgraded coal. The objectives of the experiments were to determine the stabilization characteristic of coal by analyzing the behavior of upgraded coal by drying and PAO addition regarding crossing-point temperature of coal, the moisture behavior of briquette coal, and thermal decomposition behavior of coal.

• Journal of Mechanical Science and Technology
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• 제16권7호
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• pp.1009-1018
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• 2002

The Representative Interactive Flamelet (RIF) concept has been applied to numerically simulate the combustion processes and pollutant formation in the direct injection diesel engine. Due to the ability for interactively describing the transient behaviors of local flame structures with CFD solver, the RIF concept has the capabilities to predict the auto-ignition and subsequent flame propagation in the diesel engine combustion chamber as well as to effectively account for the detailed mechanisms of soot formation, NOx formation including thermal NO path, prompt and nitrous 70x formation, and reburning process. Special emphasis is given to the turbulent combustion model which properly accounts for vaporization effects on the mixture fraction fluctuations and the pdf model. The results of numerical modeling using the RIF concept are compared with experimental data and with numerical results of the commonly applied procedure which the low-temperature and high-temperature oxidation processes are represented by the Shell ignition model and the eddy dissipation model, respectively. Numerical results indicate that the RIF approach including the vaporization effect on turbulent spray combustion process successfully predicts the ignition delay time and location as well as the pollutant formation.