Non-stationarity and non-Gaussian property are two of the most important characteristics of wind. These two features are studied in this study based on wind speed records measured at different heights from a 325 m high meteorological tower during the synoptic wind storms. By using the time-frequency analysis tools, it is found that after removing the low frequency trend of the longitudinal wind, the retained fluctuating wind speeds remain to be asymmetrically non-Gaussian distributed. Results show that such non-Gaussianity is due to the weak-stationarity of the detrended fluctuating wind speed. The low frequency components of the fluctuating wind speeds mainly contribute to the non-zero skewness, while distribution of the high frequency component is found to have high kurtosis values. By further studying the decomposed wind speed, the mechanisms of the non-Gaussian distribution are examined from the phase, turbulence energy point of view.
Supported Liquid Membranes (SLMs) have been widely studied as feasible alternative to traditional processes for separation and purification of various chemicals both from aqueous and organic matrices. This technique offers various advantages like active transport, possibility to use expensive extractants, high selectivity, low energy requirements and minimization of chemical additives. SLMs are not yet used at large scale in industrial applications, because of the low stability. In the present paper, after a brief overview of the state of the art of SLM technology the facilitated transport mechanisms of SLM based separation is described, also introducing the small and the big carrousel models, which are employed for transport modeling. The main operating parameters (selectivity, flux and permeability) are introduced. The problems related to system stabilization are also discussed, giving particular attention to the influence of membrane materials (solid membrane support and organic liquid membrane (LM) phase). Various approaches proposed in literature to enhance SLM stability are also reviewed. Modification of the solid membrane support, creating an additional layer on membrane surface, which acts as a barrier to LM phase loss, increases system stability, but the membrane permeability, and then the flux, decrease. Stagnant Sandwich Liquid Membrane (SSwLM), an implementation of the SLM system, results in both high flux and stability compared to SLM. Finally, possible large scale applications of SLMs are also reviewed, evidencing that if the LM separation process is opportunely carried out (no production of byproducts), it can be considered as a green process.
Proceedings of the Korean Powder Metallurgy Institute Conference
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2006.09a
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pp.154-155
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2006
This study investigated a mechanism for controlling the shape of Cu nanocrystals fabricated using the polyol process, which considers the thermodynamic transition from a facetted surface to a rough surface and the growth mechanisms of nanocrystals with facetted or rough surfaces. The facetted surfaces were stable at relatively low temperatures due to the low entropy of perfectly facetted surfaces. Nanocrystals fabricated using a coordinative surfactant stabilized the facetted surface at a higher temperature than those fabricated using a non-coordinative surfactant. The growth rate of the surface under a given driving force was dependent on the surface structure, i.e., facetted or rough, and the growth of a facetted surface was a thermally activated process. Surface twins decreased the activation energy for growth of the facetted surface and resulted in rod- or wire-shaped nanocrystals
Proceedings of the Korean Society of Propulsion Engineers Conference
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2008.03a
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pp.364-370
/
2008
Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable and unstable pitch modes for the lower and higher activation energies, respectively. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of two modes. The maximum pressure history in the stable pitch remained nearly constant, and the single Mach leg existing on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the unstable pitch due to the generation and decay of complex Mach interaction on the shock front shape. The high frequency oscillation was self-induced because the intensity of the transverse wave was changed during propagation in one cycle. The high frequency behavior was not always the same for each cycle, and therefore the low frequency oscillation was also induced in the pressure history.
Proceedings of the Korean Vacuum Society Conference
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2012.08a
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pp.154-155
/
2012
The promise of nano-crystalites (nc) as a technological material, for applications including display backplane, and solar cells, may ultimately depend on tailoring their behavior through doping and crystallinity. Impurities can strongly modify electronic and optical properties of bulk and nc semiconductors. Highly doped dopant also effect structural properties (both grain size, crystal fraction) of nc-Si thin film. As discussed in several literatures, P atoms or radicals have the tendency to reside on the surface of nc. The P-radical segregation on the nano-grain surfaces that called self-purification may reduce the possibility of new nucleation because of the five-coordination of P. In addition, the P doping levels of ${\sim}2{\times}10^{21}\;at/cm^3$ is the solubility limitation of P in Si; the solubility of nc thin film should be smaller. Therefore, the non-activated P tends to segregate on the grain boundaries and the surface of nc. These mechanisms could prevent new nucleation on the existing grain surface. Therefore, most researches shown that highly doped nc-thin film by using conventional PECVD deposition system tended to have low crystallinity, where the formation energy of nucleation should be higher than the nc surface in the intrinsic materials. If the deposition technology that can make highly doped and simultaneously highly crystallized nc at low temperature, it can lead processes of next generation flexible devices. Recently, we are developing a novel CVD technology with a neutral particle beam (NPB) source, named as neutral beam assisted CVD (NBaCVD), which controls the energy of incident neutral particles in the range of 1~300eV in order to enhance the atomic activation and crystalline of thin films at low temperatures. During the formation of the nc-/pm-Si thin films by the NBaCVD with various process conditions, NPB energy directly controlled by the reflector bias and effectively increased crystal fraction (~80%) by uniformly distributed nc grains with 3~10 nm size. In the case of phosphorous doped Si thin films, the doping efficiency also increased as increasing the reflector bias (i.e. increasing NPB energy). At 330V of reflector bias, activation energy of the doped nc-Si thin film reduced as low as 0.001 eV. This means dopants are fully occupied as substitutional site, even though the Si thin film has nano-sized grain structure. And activated dopant concentration is recorded as high as up to 1020 #/$cm^3$ at very low process temperature (< $80^{\circ}C$) process without any post annealing. Theoretical solubility for the higher dopant concentration in Si thin film for order of 1020 #/$cm^3$ can be done only high temperature process or post annealing over $650^{\circ}C$. In general, as decreasing the grain size, the dopant binding energy increases as ratio of 1 of diameter of grain and the dopant hardly be activated. The highly doped nc-Si thin film by low-temperature NBaCVD process had smaller average grain size under 10 nm (measured by GIWAXS, GISAXS and TEM analysis), but achieved very higher activation of phosphorous dopant; NB energy sufficiently transports its energy to doping and crystallization even though without supplying additional thermal energy. TEM image shows that incubation layer does not formed between nc-Si film and SiO2 under later and highly crystallized nc-Si film is constructed with uniformly distributed nano-grains in polymorphous tissues. The nucleation should be start at the first layer on the SiO2 later, but it hardly growth to be cone-shaped micro-size grains. The nc-grain evenly embedded pm-Si thin film can be formatted by competition of the nucleation and the crystal growing, which depend on the NPB energies. In the evaluation of the light soaking degradation of photoconductivity, while conventional intrinsic and n-type doped a-Si thin films appeared typical degradation of photoconductivity, all of the nc-Si thin films processed by the NBaCVD show only a few % of degradation of it. From FTIR and RAMAN spectra, the energetic hydrogen NB atoms passivate nano-grain boundaries during the NBaCVD process because of the high diffusivity and chemical potential of hydrogen atoms.
Because of the rapid development of computer technology in recent years, wave models can utilize parallel calculations for the high-resolution prediction of open sea and coastal areas with high accuracy. Parallel calculations also allow national agencies in the relevant sectors to produce marine forecasting data through massive parallel calculations. Meanwhile, the eastern coast of the Korean Peninsula has been increasingly damaged by swell-like high waves, and many researchers and scientists are continuing their efforts to anticipate and reduce the damage. In general, the short-term transformation of swell-like high waves can be reproduced relatively well in the third generation wave models, but the transformation of relatively long period waves needs to be simulated with higher accuracy in terms of the nonlinear wave interactions to gain a better understanding of the low-frequency wave generation and development mechanisms. In this study, we developed a calculation module to improve the calculation of the nonlinear energy transfer in the 3rd generation wave model and integrated it into the wave model to effectively consider the nonlinear wave interaction. First, the nonlinear energy transfer calculation module and third generation model were combined. Then, the combined model was used to reproduce the wave transformation due to the nonlinear interaction, and the performance of the developed operation module was verified.
Le, Xuan Hung;Lee, Sung-Young;Butun, Ismail;Khalid, Murad;Sankar, Ravi;Kim, Miso Hyoung-Il;Han, Man-Hyung;Lee, Young-Koo;Lee, Hee-Jo
Journal of Communications and Networks
/
v.11
no.6
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pp.599-606
/
2009
For many mission-critical related wireless sensor network applications such as military and homeland security, user's access restriction is necessary to be enforced by access control mechanisms for different access rights. Public key-based access control schemes are more attractive than symmetric-key based approaches due to high scalability, low memory requirement, easy key-addition/revocation for a new node, and no key predistribution requirement. Although Wang et al. recently introduced a promising access control scheme based on elliptic curve cryptography (ECC), it is still burdensome for sensors and has several security limitations (it does not provide mutual authentication and is strictly vulnerable to denial-of-service (DoS) attacks). This paper presents an energy-efficient access control scheme based on ECC to overcome these problems and more importantly to provide dominant energy-efficiency. Through analysis and simulation based evaluations, we show that the proposed scheme overcomes the security problems and has far better energy-efficiency compared to current scheme proposed byWang et al.
In the core of the WWR-K reactor, a long-term irradiation of tristructural isotopic (TRISO)-coated fuel particles (CFPs) with a UO2 kernel was carried out under high-temperature gas-cooled reactor (HTGR)-like operating conditions. The temperature of this TRISO fuel during irradiation varied in the range of 950-1100 ℃. A fission per initial metal atom (FIMA) of uranium burnup of 9.9% was reached. The release of gaseous fission products was measured in-pile. The release-to-birth ratio (R/B) for the fission product isotopes was calculated. Aspects of fuel safety while achieving deep fuel burnup are important and relevant, including maintaining the integrity of the fuel coatings. The main mechanisms of fuel failure are kernel migration, silicon carbide corrosion by palladium, and gas pressure increase inside the CFP. The formation of gaseous fission products and carbon monoxide leads to an increase in the internal pressure in the CFP, which is a dominant failure mechanism of the coatings under this level of burnup. Irradiated fuel compacts were subjected to electric dissociation to isolate the CFPs from the fuel compacts. In addition, nondestructive methods, such as X-ray radiography and gamma spectrometry, were used. The predicted R/B ratio was evaluated using the fission gas release model developed in the high-temperature test reactor (HTTR) project. In the model, both the through-coatings of failed CFPs and as-fabricated uranium contamination were assumed to be sources of the fission gas. The obtained R/B ratio for gaseous fission products allows the finalization and validation of the model for the release of fission products from the CFPs and fuel compacts. The success of the integrity of TRISO fuel irradiated at approximately 9.9% FIMA was demonstrated. A low fuel failure fraction and R/B ratios indicated good performance and reliability of the studied TRISO fuel.
Chen, Shuguang;Sun, Tingting;Yuan, Jingjing;Geng, Xiaoyan;Li, Changle;Ullah, Sana;Alnuem, Mohammed Abdullah
KSII Transactions on Internet and Information Systems (TIIS)
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v.7
no.1
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pp.1-21
/
2013
The release of IEEE 802.15.4e specification significantly develops IEEE 802.15.4. The most inspiring improvement is the enhancement for medium access control (MAC) sublayer. To study the performance of IEEE 802.15.4e MAC, in this paper we first present an overview of IEEE 802.15.4e and introduce three MAC mechanisms in IEEE 802.15.4e. And the major concern here is the Time Slotted Channel Hopping (TSCH) mode that provides deterministic access and increases network capacity. Then a detailed analytical Markov chain model for TSCH carrier sense multiple access with collision avoidance (CSMA-CA) is presented. Expressions which cover most of the crucial issues in performance analysis such as the packet loss rate, energy consumption, normalized throughput, and average access delay are presented. Finally the performance evaluation for the TSCH mode is given and we make a comprehensive comparison with unslotted CSMA-CA in non-beacon enabled mode of IEEE 802.15.4. It can validate IEEE 802.15.4e network can provide low energy consumption, deterministic access and increase network capacity.
The instability and failure of engineered rock masses are influenced by crack initiation and propagation. Uniaxial compression and acoustic emission (AE) experiments were conducted on cracked sandstone. The effect of the crack's dip on the crack initiation was investigated using fracture mechanics. The crack propagation was investigated based on stress-strain curves, AE multi-parameter characteristics, and failure modes. The results show that the crack initiation occurs at the tip of the pre-fabricated crack, and the crack initiation angle increases from 0° to 70° as the dip angle increases from 0° to 90°. The fracture strength kcr is derived varies in a U-shaped pattern as β increased, and the superior crack angle βm is between 36.2 and 36.6 and is influenced by the properties of the rock and the crack surface. Low-strength, large-scale tensile cracks form during the crack initiation in the cracked sandstone, corresponding to the start of the AE energy, the first decrease in the b-value, and a low r-value. When macroscopic surface cracks form in the cracked sandstone, high-strength, large-scale shear cracks form, resulting in a rapid increase in the AE energy, a second decrease in the b-value and an abrupt increase in the r-value. This research has significant theoretical implications for rock failure mechanisms and establishment of damage indicators in underground engineering.
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