• Title/Summary/Keyword: Low-dye

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Biosorption of Reactive Dyes using Chemically Modified Sewage Sludge (화학적으로 변형된 하수슬러지를 이용한 반응성염료의 생물흡착)

  • Han, Min-Hee;Choi, Gi-Wook;Yun, Yeoung-Sang
    • Clean Technology
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    • v.13 no.3
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    • pp.215-221
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    • 2007
  • Biosorption is considered to be a promising alternative to replace the present methods for the treatment of dye-containing wastewater. In this study, sewage sludge was used as a biosorbent which could be one of the cheapest and most abundant biomaterials. The objective of this work is to develop a surface-modified biosorbent with enhanced sorption capacity and binding affinity. The FT-IR and potentiometric titration studies revealed that carboxyl, phosphateand amine groups played a role in binding of dye molecules. The binding sites for reactive dye Reactive Red 4 (RR 4) were identified to be amino groups present in the biomass. In this work, based on the biosorption mechanism, the performance of biosorbentcould be enhanced by the removal of inhibitory carboxyl groups from the biomass for practical application of the biosorbents. As a result, the maximum capacity of biomass was increased up to 130% and 210% of the increment of sorption capacity at pH 2 and 4, respectively. Therefore, chemically modified sewage sludge can be used as an effective and low-cost biosorbent for the removal of dyes from industrial discharges.

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AN EXPERIMENTAL STUDY OF THE LONGTERM VARIATION OF FLUORIDE CONCENTRATION IN THE STANNOUS FLUORIDE SOLUTION AND THE EFFECTS OF VARIOUS ADDITIVES (불화석 용액내 불소농도의 장기변화와 첨가물의 영향에 관한 실험적 연구)

  • Choi, Yoon-Joo;Yu, Doo-Sun;Kim, Dae-Eop;Lee, Kwang-Hee
    • Journal of the korean academy of Pediatric Dentistry
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    • v.23 no.2
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    • pp.477-488
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    • 1996
  • The purposes of this study were to measure the solubility of the stannous fluoride experimentally, to find a method for improving the solubility of the stannous fluoride, and to observe the effect of longterm storage on the variation of the concentration of fluoride in the stannous fluoride solutions. By adding such materials as antiseptics, dye, flavor, and tastes to solution, the variation of the fluoride concentration was also observed. Ten groups of 0.4% stannous fluoride solutions to which glycerine, sodium chloride, chlorhexidine, dye, flavor, xylitol, and sorbitol were added were prepared. The measurements were carried out by direct calibration. The obtained results were as follows. 1. Effect of adding glycerine as solvent. : The solubility of stannous fluoride increased in the case of adding glycerine. By increasing the glycerine concentration, the fluoride level in stannous fluoride solution also increased. 2. Effect of adding sodium chloride and chlorhexidine. : Comparing to the case of pure water, low fluoride level was measured in case of adding sodium chloride and high fluoride level was measured in case of adding chlorhexidine. 3. Effect of adding erythrosin as dye and banna essence as flavor. : Adding erythrosin and banna essence didn't affect fluoride level. 4. Effect of adding xylitol and sorbitol. : The effects of xylitol and sorbitol were nearly the same as the effect of adding erythrosin and banna essence.

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Decolorization of dye solution using membrane bioreactor (MBR) by Trametes versicolor (막생물반응기(MBR)에 의한 염료용액의 처리연구)

  • Lee, Yuri;Kim, Hyun-Gi;Park, Chulhwan;Lee, Byunghwan;Kim, Sangyong
    • Clean Technology
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    • v.10 no.3
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    • pp.131-137
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    • 2004
  • Due to the low biodegradability of dyes, conventional biological wastewater treatment systems are inefficient in treating textile wastewater. In this study, white rot fungus, Trametes versicolor KCTC 16781, were investigated for the decolorization of Reactive black 5 solutions. This fungus was able to degrade the dye solutions by the ligninolytic enzymes (laccase and MnP) produced. The enzyme activity remained constant until the end of reaction. The combined process of biological treatment and ceramic membrane showed better efficiency for decolorization and TOC removal than each single process.

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Development of Pt-free counter electrode for dye-sensitized solar cell (Pt free 염료감응형 태양전지 전극에 대한 연구)

  • Hwang, Hyun Suk;Park, Yong Seob
    • Journal of Satellite, Information and Communications
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    • v.9 no.2
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    • pp.107-109
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    • 2014
  • Dye-sensitezed solar cell(DSSC) has aroused intense interest owing to its competitive price and stabilized properties than Si based solar cells. Recently, many studies have been reported on the DSSC, especially development of Pt-free counter electrode. In this paper, graphene is chosen counter electrode for low cost material and developed its properties. To estimate the properties of counter electrode, graphene and Pt thin films have been fabricated on FTO substrates respectively, than the films are tested AFM and J-V evaluation method. A graphene of 0.1 wt% has shown current density of 11.68 mA/cm2, maximum efficiency of 4.34% which is similar with that of Pt counter electrode. It confirmed that graphene could be good material for counter electrode if its synthesizing conditions were developed.

A Study on FTO-less Dye Sensitized Solar Cell with Ti Deposited Glass (티타늄이 증착된 유리를 사용한 FTO-less 염료감응형 태양전지에 관한 연구)

  • Park, Songyi;Seo, Hyunwoong;Son, Min-Kyu;Kim, Soo-Kyoung;Hong, Na-Yeong;Song, Jeong-Yun;Prabakar, Kandasamy;Kim, Hee-Je
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.2
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    • pp.208-212
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    • 2013
  • Dye-sensitized solar cells (DSCs) have taken much attention due to their low cost and easy fabrication method compare to silicon solar cells. But research on cost effective DSC is prerequisite for commercialization. Fluorine doped tin oxide (FTO) which have been commonly used for electrode substrate as electron collector occupied most percentage of manufacturing cost. Therefore we studied FTO-less DSC using sputtered Ti deposited glass as photoelectrode instead of FTO to reduce manufacturing cost. Ti films sputtered on the glass for different time, 5 to 20 minutes with decreasing sheet resistance as deposition time increases. A light source illuminated to counter electrode in order to overcome opaque Ti films. The efficiency of DSC (Ti20) made Ti sputtered glass for 20 min as photoelectrode was 5.87%. There are no significant difference with conventional cell despite lower manufacturing cost.

Improving the Dyeability of Cotton Fabric with Caesalpinia sappan through Pretreatment with Gelatin (면직물의 젤라틴 전처리에 의한 소목염색의 염색성 향상)

  • Lee, Ji Youn;Jang, Jeong Dae
    • Fashion & Textile Research Journal
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    • v.21 no.4
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    • pp.509-514
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    • 2019
  • Cotton fabrics were treated with gelatin to enhance dyeability and color strength when using Caesalpinia sappan dye. Gelatin was used as the protein and a pad-dry- cure method was used for the treatment process (2, 4, 6, 8, 10, 12, 14g/l concentration). Pretreated fabrics were mordanted with 10% alum. Fabrics were then dyed with freeze-dried sappan wood water extract powder form. Dyed samples were assessed in regards to dyeing behavior and color fastness. Comparing untreated and gelatin treated samples from the SEM images indicated that the Gelatin treatment (10g/l) resulted in an enhanced surface roughness that was relative to that of untreated cotton. Padding cotton with gelatin at 6g/l concentration afforded dyed fabrics with a 2 times increase in the K/S value over that of untreated fabrics. All dyed samples were red color with a significant enhancement in the sample color strength (K/S) being observed for pretreated samples. pH values favor dye absorption with pH 7 yielding the highest color strength. Dyeing at an elevated temperature resulted in a lower color strength and reddish-dull color. Longer dyeing times created greater color strengths for untreated and gelatin treated cotton. Increased dye concentrations resulted in higher K/S values for both gelatin treated and untreated cotton. As for color fastness, gelatin treated and untreated cotton fabrics dyed with sappan wood extract showed a relatively low rating in washing fastness (color change 1 rating), light fastness (1 rating), and rubbing fastness (wet:1-2, dry:3-4 rating).

Mixture Dyeing of Silk Fabrics with Gardenia and Xanthium Strumarium L. to Improve the Functionality (기능성 증진을 위한 치자색소와 창이자에 의한 견직물의 복합염색)

  • Bae, Jung-Sook;Lee, Won-Kwon;Huh, Man-Woo
    • Fashion & Textile Research Journal
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    • v.21 no.1
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    • pp.112-119
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    • 2019
  • This study had a purpose of further investigating and developing the usage of the eco-friendly functional dye that has physiological and pharmacological functions. This study was implemented complex dyeing method which used both natural dyes such as Gardenia jasminoides J.Ellis colorant, which are the yellow dyes that have high brightness and low chroma, and Xanthium strumarium L. extract. The silk fabrics were used to dye in various methods. They were also used to investigate functionalities dyed fabrics by various treating method, such as their color fastness, antibacterial activities and deodorization, the following were obtained. The fabrics that were dyed with herbs had decreasing brightness as the herbs extract concentrations were increased and had subtly changing chroma. But, because their K/S values were under 0.5, they were not properly dyed. Color fastness differed according to the natural dyes and herbs' complex dyeing order. The Color fastness was good when the fabrics were dyed with the colorant first, and then with the herb. When the fabrics were dyed with mixture dyeing solution, the natural dye and the herb extract, the herb didn't affect the dyeabilities of fabrics as much. When the fabrics were dyed with the mixture of the colorant and the herb extract, the dyeabilities didn't have much changes. However, their color fastnesses were improved a little bit due to the complex dyeing condition. When the fabrics were dyed with the mixture of the colorant and the herbs extract, their antibacterial activities and deodorization were increased.

Properties of Dye-sensitized Solar Cell by Upper Electrodes (상부전극에 의한 염료감응형태양전지의 특성)

  • Mah, Jae-Pyung
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.1
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    • pp.41-47
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    • 2012
  • In DSSC, fundamental process conditions of upper electrode were established and low cost-oriented method for TCO layer was proposed. Especially, prominent properties, that is, open-circuit voltage of 500mV or more and short-circuit current of $25mA/cm^2$ were yielded by 2-step sintering of semiconductive powder layer. High efficiency-DSSC was able to fabricate without high cost-semiconductor apparatus in common laboratory conditions.

Methylene blue-catalyzed photodecomposition of guanine (Methylene Blue에 의한 guanine의 광분해 현상)

  • 홍순우;변우현
    • Korean Journal of Microbiology
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    • v.10 no.1
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    • pp.35-40
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    • 1972
  • 1) The photodecomposition rate of guanine being catalized by methylene blue ws 53.7% in contrast with 9.3% that of dark control for 180 min. 2) In guanine control, the decomposition rate was very low. For 180 min., the rate was 8.1% in illuminated sample and 3.9% in non-illuminated sample. 3) The decomposition rate of methylene blue was obviously interfered by the existence of guanine. In guanine and methylene blue mixture solution, the net decomposition rate, excluding that of dark control ws 39.2% and in dye only solution, it was 48.5%.

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Modification of Dyeing Property of Polyester Fabrics by UV Irradiation (UV조사에 의한 Polyester직물의 염색성 개질)

  • 배중석;김인회
    • Textile Coloration and Finishing
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    • v.13 no.4
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    • pp.256-263
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    • 2001
  • Polyester fabrics were irradiated by UV produced by the low pressure mercury lamp. UV irradiation broke a C-H bond of PET fiber and caused the carbonyl groups on the fiber surfaces. Surface modification of PET fibers were accelerated by pretreatment with methanol, ethanol and acetone. The irradiated PET was dyed with basic dyes having cationic groups. The dye uptakes were proportional to irradiation times, and in inversely proportional to irradiation distances. The tensile strengths of PET fabrics decreased by UV irradiation. Washing fastness of PET dyeings were good, about 4-5 grade,andlightfastnesswerepoor, about l grade.

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