• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.12
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• pp.1681-1690
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• 1998

The aim of this paper is to investigate combustion characteristics of lean premixed mixture stabilized by catalytic surface reaction. The catalytic combustor consisted of a catalyst bed and a thermal combustor. The catalyst bed was made of two stage, Pd catalyst in the first stage and Pt catalyst in the second stage. Auto ignition of lean mixture took place in the thermal combustor. Ignition temperature was about $810{\sim}820^{\circ}C$ at the fuel-air ratio of 1.5~3.0 % and the mixture velocity of 11~18m/sec. The position of flame front in the thermal combustor moved toward back as preheat temperature increased and fuel-air ratio decreased. The f1ame supported by surface reaction was stabilized without any flame stabilizers. NOx emissions from the catalytic combustor were below 2.0 ppm ($O_2$ 15 %) when gas temperature was limited below $1350^{\circ}C$. This result demonstrates that NOx emission from the catalytic combustor is much low comparing with conventional combustors.

• Journal of the Korean Society of Combustion
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• v.12 no.3
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• pp.1-7
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• 2007

A combined hydrogen generator of plasma and catalytic reformer was developed, and was applied to stabilize unstable flame of 200,000 Kcal/hr LPG combustor. The role of the plasma reformer was to generate hydrogen in a short period and to heat-up the catalytic reformer during the start-up time. After the start-up period, the catalytic reformer generates hydrogen through steam reforming with oxygen (SRO) reactions. The maximum capacity of the hydrogen generator was enough 100 lpm to stabilize the flame of the present combustor. In order to reduce NOx and CO emissions simultaneously, 1) FGR (Flue Gas Recirculation) technique has been adopted and 2) the hydrogen was added into the fuel supplied to the combustor. Test results showed that the addition of 25% hydrogen and 30% FGR rate lead to simultaneous decrease of CO and NOx emissions. The technique developed in the present study showed good potential to replace $NH_3$ SCR technique, especially in the small-scale combustor applications.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.227-234
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• 2004

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to $CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent $CO_2$ separation and no NOx emission and to confirm high $CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and $CH_4$ and air were used as reacting gases for reduction and oxidation respectively.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.187-190
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• 2007

A combined hydrogen generator of plasma and catalytic reformers has been developed, and has been applied to stabilize unstable flame of 200,000 Kcal/hr LPG combustor. The role of the plasma reformer is to generate hydrogen in a short period and to heat-up the catalytic reformer during the start-up time. After the start-up period, the catalytic reformer generates hydrogen through steam reforming with oxygen (SRO) reactions. The maximum capacity of the hydrogen generator is 100 lpm that is sufficient to be used to stabilize the flame of the present combustor. In order to reduce NOx and CO emissions simultaneously, 1) FGR (Flue Gas Recirculation) technique has been adopted and 2) the hydrogen has been added into the fuel supplied to the combustor. Test results shows that 25 % addition of hydrogen and 30 % FGR rate lead to simultaneous decrease of CO and NOx emissions. The technique proposed in the present study shows good potential to replace $NH_3$ SCR technique, especially in the case of small-scale combustor applications.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.7-8
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• 2012

The effects of interaction between partially premixed and premixed swirl flames on CO and NOx emissions were experimentally investigated using a hybrid/dual swirl jet combustor for a micro-gas turbine. Under the condition of constant angle ($45^{\circ}$) for outer swirl vane, the angle and direction of inner swirl vane installed for a partially premixed flame were varied as main parameters with a constant fuel flow rate for each nozzle. It was found that for all conditions, CO and NOx emissions were measured below 4 ppm and 15 ppm at 15% $O_2$, respectively, in a wide range of equivalence ratio (0.6~0.9). For co-swirl flows, CO emission increased dramatically as the angle of inner swirl vane increased from $15^{\circ}$ to $45^{\circ}$ near lean-flammability limit (i.e. equivalence ratio of 0.5). On the other hand, the case of swirl $angle=45^{\circ}$ provided the lowest NOx emission at higher equivalence ratios than 0.6. For counter-swirl flows, the case of swirl $angle=45^{\circ}$ extended the lean-flammability limit but higher NOx emissions were found compared to those of co-swirl flows. These results could be inferred by interaction between (inner) partially premixed and (outer) premixed swirl flames. However, these estimations were not clear yet because there was insufficient data on turbulent flow structure and fuel-air mixing in the present experimental approach.

• 연구논문집
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• s.31
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• pp.23-43
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• 2001

An experimental investigation on the reduction of nitrogen oxide emission from swirling, turbulent diffusion flames was conducted using multi air staged combustor, The combustor utilizes swirler to dampen fuel/air mixing, allowing an extended residence time for fuel pyrolysis and fuel-N conversion chemistry in an locally fuel-rich environment prior to burnout. This process also allow to reduce thermal NOx formation to lessen the temperature of reaction zone. The aerodynamic process therefore emulates the conventional staged combustion process, but without the need for the physically separate fuel-rich and -lean stages. Parametric studies on the ratios of each staged air and droplet size were carried out the feasibility of fuel/air mixing for low NOx combustion with diesel and pyridine mixed diesel fuel oil.

• Journal of the Korea Safety Management & Science
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• v.21 no.2
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• pp.1-8
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• 2019

Most of gas turbine combined cycle power plants are located in urban areas to provide peak load and district heating. However, NOx(nitrogen oxides) of exhaust gas emission from the power plants cause additional fine dust and thus it has negative impact on the urban environment. Although DLN(dry low NOx) and multi-stage combustors have been widely applied to solve this problem, they have another critical problem of damages to combustors and turbine components due to combustion dynamic pressure. In this study, the effect of different fuel ratio on NOx emission and pressure fluctuation was investigated regarding two variable conditions; combustor stages and power output on M501J gas turbine.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.123-125
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• 2015

A study has been conducted to investigate the effect of swirl angle in low swirl combustor. In this study, the employed swirl angles were $28^{\circ}$, $32^{\circ}$ and $37^{\circ}$. Direct flame photos show that the width of the flame is expanded and the length of the flame is shortened when swirl angle is increased. Also, as the swirl angle was increased, the flame stability region could be widened due to the expansion of lower flammable limit. Between 3 and 7kW, CO emissions was below 10 ppm and NOx emissions was also below 27 ppm at $O_2$ 15% basis over the lean burning range of 0.6 < ${\Phi}$ < 0.9. From this investigation of stability expansion effect and emission performance, it was identified that the swirl angle $37^{\circ}$ is most suitable swirling condition in the low swirl model combustor.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.11a
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• pp.105-108
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• 2001

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.199-200
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• 2012

An experimental study on geometric optimization was conducted to develop a hybrid/dual swirl jet combustor for a micro-gas turbine. A hybrid concept indicating a combination of swirling jet partially premixed and premixed flames were adopted to achieve high flame stability as well as clean combustion. Location of pilot nozzle, angle and direction of swirl vane were varied as main parameters with a constant fuel flow rate for each nozzle. The results showed that the variation in location of pilot nozzle resulted in significant change in swirl intensity due to the change in flow area near burner exit, and thus, optimized nozzle location was determined on the basis of CO and NOx emissions under conditions of co-swirl flow and swirl $angle=30^{\circ}$. The increase in swirl angle (from $30^{\circ}$ to $45^{\circ}$) enhanced the emission performances, in particular, with a significant reduction of CO emission near lean-flammability limit. It was observed that the CO emission near lean-flammability limit was further reduced through the counter-swirl flow. However, there was not significant change in the NOx emission in the operating conditions (i.e. equivalence ratio of 0.6~0.7) between the co- and the counter-swirl flow.