• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2011년도 춘계학술발표대회 논문집
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• pp.86-91
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• 2011

Thermal design was conducted for a solar thermal storage system in a medium-temperature range between $200^{\circ}C$ and $400^{\circ}C$. The system was composed of heat pipes as heat carrier and molten salts as phase-change storage material. Each heat pipe penetrated through the storage system and had two heat-exchanging sections at both ends to interact with high-and low-temperature steams, while it exchanged heat with molten salts in the middle section. During a heat-storage mode, the heat pipes transferred heat from the hot steam at one side to the molten salts and it transferred heat from the molten salt to the cold steam at the other side during the heat-dissipating mode. A tube-bank type heat exchanger theory was applied to this design task to meet the required inlet and outlet temperatures of the steams depending on the operation modes. Several design variables were considered including the lengths of evaporator and condenser of a heat pipe, traverse and longitudinal pitches of the pipe, and the number of rows of the heat pipes for two different molten salt baths. An optimum design results were presented with discussion.

• 한국가스학회지
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• 제24권6호
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• pp.61-69
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• 2020

본 논문은 압력과 온도조건에 따라 수소저장용기 TYPE 1에서 발생하는 거동특성을 FEM(Finite Element Method)으로 연구한 것이다. 용기의 구조안전성 평가를 위해 최고압력에서 발생한 VMS(Von Mises stress)을 소재의 YS(Yield Strength)를 비교하였고, 수명예측을 위한 기초데이터로써 PSED(Plastic Strain Energy Density) 결과를 분석하였다. 해석결과에 의하면 최고압력 40 Mpa 이상의 가스압에서 저장용기의 바닥면에 항복강도보다 높은 VMS가 발생하여 수소가스 저장용기의 안전성은 확보되지 않았다고 판단된다. 또한, 온도조건에 의해 발생한 VMS의 결과는 대단히 낮아서 온도에 의한 거동은 영향을 무시할 수 있다. VMS/YS이 1이하가 되는 최고압력은 약 30Mpa으로 계산되어 본 논문의 대상이 되는 수소저장용기는 30 Mpa이하의 가스충전압력으로 관리되어야 함을 알 수 있다.

• 한국재료학회지
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• 제16권3호
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• pp.193-197
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• 2006

The sodium/sulfur(Na/S) battery has many advantages such as high theoretical specific energy(760Wh/kg), and low material cost based on the abundance of electrode material in the earth. It has been reported that the electrochemical properties of sodium/sulfur cell above $300^{\circ}C$, utilized a solid ceramic electrolyte and liquid sodium and sulfur electrodes. A lot of researches have been performed in this field. Recently, Na/S battery system was applied for electricity storage system for load-leveling. One of severe problems of sodium/sulfur battery was high operating temperature above $300^{\circ}C$, which could induce the explosion and corrosion by molten sodium, sulfur and polysulfides. In order to develop sodium battery operated at low temperature, sodium ion battery has been studied using carbon anode, and sodium oxides cathodes. However, the energy densities of the sodium ion batteries were much lower than high temperature sodium/sulfur cell. In this study, the sodium/sulfur battery with 1M $NaCF_3SO_3$ is tested at room temperature. The charge-discharge mechanism was discussed based on XRD, DSC, SEM and EDS results.

• 한국식품저장유통학회지
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• 제14권3호
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• pp.227-232
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• 2007

홍고추를 원료형태에 따라 원형, 세절, 분쇄로 제조하여 $-5^{\circ}C,\;-20^{\circ}C$ 및 $-40^{\circ}C$ 저장고에 보관하였다. 고추의 표면색도는 저장온도 조건에 따라 저장일수가 증가할수록 약간 감소하는 경향을 보였으며, 비타민 C 함량은 원형 홍고추가 세절고추나 분쇄고추보다 저장기간 동안 완만하게 감소하는 경향을 보였다. 저장온도별로는 $-40^{\circ}C$ 저장군에서 비타민 C 함량이 가장 높게 유지되었으며, $-5^{\circ}C$ 저장군에서 저장 2개월째 50% 이하로 급격히 감소하였다. 유리당 함량은 저장일수가 증가할수록 모든 처리구에서 저장 2개월까지 약간 증가하다가 점차적으로 감소하였으며 $-5^{\circ}C$ 저장온도 처리군에서의 감소변화가 $-20^{\circ}C,\;-40^{\circ}C$ 저장온도 처리군보다 심하게 나타났다. 냉동고추를 실온 해동시 드립로스의 양이 냉장 해동, microwave oven 해동시보다 약 2배 가까이 드립로스양이 발생하였으며, 표면색도는 고온 해동시 갈색화가 심하게 나타났다. 해동조건에 따른 냉동고추의 성분 변화는 냉장 해동과 microwave oven 해동시 가장 적게 나타났으며, 해동 시간을 고려한다면 microwave oven 해동이 가장 실용적인 방법이라고 여겨진다.

• 태양에너지
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• 제8권1호
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• pp.13-21
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• 1988

Heat transfer phenomena in a high-temperature heat storage unit were investigated using molten salts. Carbonate salt, an equimolar mixture of $Li_2CO_3$ and $K_2CO_3$, which melts at $505^{\circ}C$ with a latent heat of 82 cal/g, was selected as the most promising latent heat storage material based on its low cost and excellent thermophysical properties at moderately high temperatures. It was also found that nitrate salts were good candidates of sensible heat storage materials. For the carbonate salt to be utilized commercially, however, several means of enhancing thermal recovery must be explored by promoting heat conduction through the solid salt formed during the heat discharge period. These would be achieved by the additions of aluminum screens and wool, and stainless fins. Finally, experimental results of moving boundary of phase change were well compared with predictied values obtained from the approximate solution.

• Journal of Advanced Marine Engineering and Technology
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• 제28권6호
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• pp.962-971
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• 2004

This paper has dealt with thermo-physical properties of microencapsulated phase change material slurry as a latent heat storage material having a low melting point. The measured results of the thermo-physical properties of the test microencapsulated phase change material slurry, those are, density, specific heat, thermal conductivity and viscosity, were discussed for the temperature region of solid and liquid phases of the dispersion material (paraffin). The measurements of these properties of microencapsulated phase change material slurry have been carried out by using a specific-gravity meter, a water calorimeter, a differential scanning calorimeter(DSC), a transient hot wire method and rotating type viscometer, respectively. It was clarified that the additional properties law could be applied to the estimation of the density and specific heat of microencapsulated phase change material slurry and also the Euckens equation could be applied to the estimation of the thermal conductivity of this slurry.

• 설비공학논문집
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• 제16권6호
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• pp.499-505
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• 2004

The objective of this study is to investigate the effect of supercooling repression on the TMA clathrate by adding ethylene glycol. For this purpose, phase change temperature, supercooling, specific heat, latent heat and rate of volume change were measured and evaluated experimentally for heat source temperatures of -6$^{\circ}C$, -7$^{\circ}C$, -8$^{\circ}C$. The results show that supercooling was decreased. Thus the experimental results are expected to be used for the increase of coefficient of performance of low temperature thermal storage system in the building.

• 한국수소및신에너지학회논문집
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• 제22권2호
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• pp.178-183
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• 2011

Metal hydride alloys are a promising type of material in hydrogen storage applications, allowing for low-pressure, high-density storage. However, while many studies are being performed on enhancing the hydrogen storage properties of such alloys, there has been little research on large-scale storage vessels which make use of the alloys. In particular, large-scale, high-density storage devices must make allowances for the inevitable generation or absorption of heat during use, which may negatively impact functioning properties of the alloys. In this study, we develop a numerical model of the discharge properties of a high-density MH hydrogen storage device. Discharge behavior for a pilot system is observed in terms of temperature and hydrogen flow rates. These results are then used to build a numerical model and verify its calculated predictions. The proposed model may be applied to scaled-up applications of the device, as well as for analyses to enhance future device designs.

• 한국식품과학회지
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• 제19권2호
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• pp.176-180
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• 1987

건조마늘 플레이크를 상대습도 11%에서 84%까지 7단계의 상대습도별로$5^{\circ}C$, $20^{\circ}C$ 및 $35^{\circ}C$온도에 저장하면서 건조마늘 플레이크의 갈변 및 흡습특성을 조사하였다. 저장시간에 따른 건조마늘 플레이크의 흡습곡선은 RH 51% 이하에서는 단시간내에 평형에 도달하여 수분함량의 변화가 거의 없었으나, $20^{\circ}C$ 및 $35^{\circ}C$의 RH 67% 이상에서 $5^{\circ}C$의 RH 84%에서 평형수분함량이 급격히 증가하여 갈변현상이 나타났다. 건조마늘 플레이크의 단분자층 수분함량은 온도에 따라서 5.80%(DB)에서 6.20%(DB)로서 온도가 내려감에 따라 다소 증가하는 경향을 나타냈고 수분함량 및 저장온도가 낮으면 낮을수록 흡습력이 크기 때문에 건조마늘 플레이크의 장기저장에 방습포장재가 필요하였다. 상대습도 및 저장온도에 따라서 건조마늘 플레이크의 갈변도를 예측할 수 있는 회귀방정식을 도출하였다.

• Nuclear Engineering and Technology
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• 제42권3호
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• pp.249-258
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• 2010

Recently, many utilities have considered interim dry storage of spent nuclear fuel as an option for increasing spent fuel storage capacity. Foreign nuclear regulatory committees have provided some regulatory and licensing requirements for relatively low- and medium-burned spent fuel with respect to the prevention of spent fuel degradation during transportation and interim dry storage. In the present study, the effect of cladding creep and hydride distribution on spent fuel degradation is reviewed and performance tests with high-burned Zircaloy-4 and advanced Zr alloy spent fuel are proposed to investigate the effect of burnup and cladding materials on the current regulatory and licensing requirements. Creep tests were also performed to investigate the effect of temperature and tensile hoop stress on hydride reorientation and subsequently to examine the temperature and stress limits against cladding material failure. It is found that the spent fuel failure is mainly caused by cladding creep rupture combined with mechanical strength degradation and hydride reorientation. Hydride reorientation from the circumferential to radial direction may reduce the critical stress intensity that accelerates radial crack propagation. The results of cladding creep tests at $400^{\circ}C$ and 130MPa hoop stress performed in this study indicate that hydride reorientation may occur between 2.6% to 7.0% strain in tube diameter with a hydrogen content range of 40-120ppm. Therefore, it is concluded that hydride re-orientation behaviour is strongly correlated with the cladding creep-induced strain, which varies as functions of temperature and stress acting on the cladding.