• Title/Summary/Keyword: Low temperature phase

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Preparation of Zone-melted NdBaCuO under Low Oxygen Pressure

  • wha, Soh-Dea;guo, Fan-Zhan;ying, Gao-Wei;Jeon Yongwoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.85-88
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    • 2001
  • The NdBaCuO superconductor samples were Zone-melted in low oxygen partial pressure (1% O$_2$+99% Ar). The Zone-melting temperature was decreased about 120$^{\circ}C$ from 1060$^{\circ}C$ the zone-melting temperature in air. Thus the loss of liquid phase (BaCuO$_2$ and CuO) was reduced during the zone-melting process. The content of non-superconducting phase Nd422 in zone-melted NdBaCuO samples was clearly decreased, so was the substitution of Nd for Ba. The superconductivity of zone-melted Nd$\sub$1+x/Ba$\sub$2-x/Cu$_3$O$\sub$y/ prepared under low oxygen partial pressure was distinctively improved.

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The Change of Microstructures by Low Temperature Aging in Y-TZP (저온 열처리에 의한 Y-TZP 미세조직의 변화)

  • Lee, Jong-Kook;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.735-740
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    • 1990
  • The phase transformation of Y-TZP by low temperature aging treatments and its related behaviors of crack formation were investigated. The kinetics of phase transformation was greatly dependent on the amounts of Y2O3, grian size and microstructures of sintered body. The phase transformation happened to start at specimen surface and near the pore in the first place, where the change of strain energy during the phase transformation was small and the water vapor that accelerated phase transformation easily diffused.

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Effects of Rolling and Cooling Conditions on Microstructures and Mechanical Properties of High-Deformable Pipeline Steels (고변형능 라인파이프강의 미세조직과 기계적 특성에 미치는 압연 및 냉각 조건의 영향)

  • Lee, S.I.;Hwang, B.
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.5
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    • pp.235-241
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    • 2014
  • Effects of rolling and cooling conditions on microstructures and mechanical properties of high-deformable pipeline steels were investigated in this study. Six kinds of pipeline steels were fabricated by varying rolling and cooling conditions, and their microstructures were analyzed by scanning electron microscopy, electron back-scattered diffraction, and transmission electron microscopy. Tensile and Charpy impact tests were conducted on the steels in order to examine the mechanical properties. The steels rolled in the two-phase region showed better low-temperature toughness than those in the single-phase region due to the larger amount of ferrites having high-angle boundaries, although they have lower strength and absorbed energy. The steel rolled in single-phase and finish-cooled at higher temperature showed a good combination of high strength and good low-temperature toughness as well as excellent deformability of the lowest yield ratio and the highest uniform elongation because of the presence of fine ferrite and a mixture of various low-temperature transformation phases.

Effects of Temperature and Day-Length on Heading Habit of Recently Developed Korean Rice Cultivars

  • Choi, Kyung-Jin;Lee, Jung-Il;Chung, Nam-Jin;Yang, Won-Ha;Shin, Jin-Chul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.1
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    • pp.41-47
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    • 2006
  • To understand the heading habit of recently developed 20 Korean rice cultivars, rice plants in a phytotron were exposed to different temperature: $22.5^{\circ}C(day\;27^{\circ}C/night\;18^{\circ}C),\;27.5^{\circ}C(day\;32^{\circ}C/night\;23^{\circ}C)$, and day-length conditions: 10, 12, 13, 14, 15 hours. Four rice cultivars (Sobibyeo, Juanbyeo, Ilpumbyeo and Shindongjinbyeo) showed relatively short Basic Vegetative Phase (BVP) of 17 to 18 days, while Dasanbyeo showed the longest (35 days) BVP, compared to other remaining 15 tested cultivars which exhibited 24 to 31 days of BVP. In this experiment, it was tried out to separate the eliminable vegetative phase into photosensitivity and thermo-sensitivity with two different pathways. Many tested cultivars, however, exhibited quite different responses under low temperature and / or long day-length conditions. Especially, Surabyeo and Juanbyeo were the most difficult cultivars to separate into photo- or thermo-sensitivity in that the eliminable vegetative phase of these two cultivars increased greatly only under low temperature $(22.5^{\circ}C)$ and long day-length (15 hr.) conditions. Regarding the heading response to temperatures, tested cultivars could be categorized into 2 groups. In 1st group of rice cultivars, the eliminable vegetative phase decreased almost equally as the temperature changed from $20.0^{\circ}C\rightarrow22.5^{\circ}C\rightarrow25.0^{\circ}C\rightarrow27.5^{\circ}C$. In contrast, the 2nd group of rice cultivars exhibited eliminable vegetative phase slowly decreasing when the temperature changed from $22.5^{\circ}C\rightarrow25.0^{\circ}C\rightarrow27.5^{\circ}C$, but rapidly decreasing when the mean temperature changed from $20.0^{\circ}C\;to\;22.5^{\circ}C$. All the cultivars belonged to 2nd group, the heading date would be very delayed if cool summer comes.

Enhanced Superplasticity of Two-phase Titanium Alloys by Microstructure Control (2상 타이타늄 합금의 미세조직 제어를 통한 초소성 특성 향상)

  • Park, C.H.;Lee, C.S.
    • Transactions of Materials Processing
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    • v.19 no.1
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    • pp.5-10
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    • 2010
  • The current understanding for phase/grain boundary sliding and low-temperature/high-strain rate superplasticity of two-phase titanium alloys is summarized. The quantitative analysis on boundary sliding revealed increased sliding resistance on the order of ${\alpha}/{\beta}\;\ll\;{\alpha}/{\alpha}\;{\approx}\;{\beta}/{\beta}$ boundary, hence, led to the conclusion that approximately 50% alpha(or beta) volume fraction and/or grain refinement is beneficial for obtaining large superplastic elongation at low temperature and/or high strain rate. To predict the temperature for 50% alpha volume in various alpha/beta Ti, artificial neural network was applied. Finally, much enhanced superplasticity was achieved through grain refinement utilizing dynamic globularization.

Effect of Treatment Temperature and Gas Content on the Characteristics of Surface Layer of Low Temperature Plasma Nitrided Duplex Stainless Steel. (Duplex Stainless Steel (2205)의 Low Temperature Plasma Nitriding 처리시 처리온도 및 가스함량에 따른 S-phase 거동)

  • Lee, In-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.291-292
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    • 2015
  • Duplex Stainless Steel의 Plasma Nitriding 처리 시 가스량과 처리온도가 표면 특성에 미치는 영향을 조사하였다. $N_2$함량 및 처리 온도가 각각 10%에서 25%로 $400^{\circ}C$에서 $430^{\circ}C$로 증가함에 따라서 질소가 과고용된 S-phase의 두께 및 표면 경도가 증가하였으나, 내부 식성은 $Cr_2N$$(Fe,Cr)_4N$이 석출하여 감소하였다. 질소를 10%로 고정하고 $CH_4$함량을 증가시키면 1%일 때 S-phase의 두께가 최대가 되며 그이후로 감소하였다. 처리온도 $400^{\circ}C$일 때 질소함량이 10%, $CH_4$ 함량이 5%일 경우 내식성이 모재보다 증가하였다.

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A Theoretical Study on the Low Transition Temperature of VO2 Metamaterials in the THz Regime

  • Kyoung, Jisoo
    • Current Optics and Photonics
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    • v.6 no.6
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    • pp.583-589
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    • 2022
  • Vanadium dioxide (VO2) is a well-known material that undergoes insulator-to-metal phase transition near room temperature. Since the conductivity of VO2 changes several orders of magnitude in the terahertz (THz) spectral range during the phase transition, VO2-based active metamaterials have been extensively studied. Experimentally, it is reported that the metal nanostructures on the VO2 thin film lowers the critical temperature significantly compared to the bare film. Here, we theoretically studied such early transition phenomena by developing an analytical model. Unlike experimental work that only measures transmission, we calculate the reflection and absorption and demonstrate that the role of absorption is quite different for bare and patterned samples; the absorption gradually increases for bare film during the phase transition, while an absorption peak is observed at the critical temperature for the metamaterials. In addition, we also discuss the gap width and VO2 thickness effects on the transition temperatures.

Hardness and Microstructures of Ti-Zr-(Cu) based Alloys for Dental Castings (치과주조용 Ti-Zr-(Cu)계 합금의 경도 및 미세조직)

  • Joo, Kyu-Ji
    • Journal of Technologic Dentistry
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    • v.27 no.1
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    • pp.65-71
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    • 2005
  • Experimental Ti-13%Zr and Ti-13%Zr-5%Cu alloys were made in an argon-arc melting furnace. The grade 2 CP Ti was used to control. The alloys were cast into phosphate bonded $SiO_2$ investment molds using an argon-arc casting machine, and The hardness and microstructures of the castings were investigated in order to reveal their possible use for new dental casting materials and to collect useful data for alloy design. The hardness of the Ti-13%Zr-5%Cu alloy(379Hv) became higher than that of Ti-13%Zr(317Hv) alloy, and the hardness of this alloys became higher than that of CP Ti(247Hv). Increasing in the hardness of the Ti-13%Zr-5%Cu alloy was considered to be solid solution hardening as the Ti-Zr system shows a completely solid solution for both high temperature $\beta$phase and low temperature $\alpha$ phase and also the inclusion of the eutectoid structure($\alpha Ti+Ti_{2}Cu$). No martensitic structures are observed in the specimen made of CP Ti, but Ti-13%Zr and Ti-13%Zr-5%Cu alloys show a kind of martensitic structure. Ti-13%Zr-5%Cu shows the finest microstructure. From these results, it was concluded that new alloys for dental casting materials should be designed as Ti-Zr-Cu based alloys.

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Electrical Properties of Rosen Type piezoelectric transformers using Low Temperature Sintering PMN-PNN-PZT ceramics (저온소결 PMN-PNN-PZT계 세라믹스를 이용한 Rosen형 압전변압기의 전기적 특성)

  • Lee, Sang-Ho;Yoo, Ju-Hyun;Kim, In-Sung;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.53-53
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    • 2008
  • Piezoelectric transformers have been widely used such as DC-DC convertor, invertor, Ballast, etc. Because, the y have some merits compared with electro-magnetic transformers such as step-up ratio, high efficiency, small size and lg hit weight, etc. Piezoelectric transformer require high electromechanical coupling factor kp in order to induce a large out put power in proportional to applied electric field. And also, high mechanical quality factor Qm is required to prevent mechanical loss and heat generation. In general, PZT system ceramics should be sintered at high temperatures between 1200 and $1300^{\circ}C$ in order to obtain complete densification. Accordingly, environmental pollution due to its PbO evaporation. Hence, to reduce its sintering temperature, various kinds of material processing methods such as hot pressing, high energy mill, liquid phase sintering, and using ultra fine powder have been performed. Among these methods, liquid phase sintering is basically an effective method for aiding densification at low temperature. In this study, In order to comparis on low temperature sintering and solid state sintering piezoelectric transformers, rosen type transformers were fabricated u sing two PZT ceramics compositions and their electrical properties were investigated.

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Metabolic Imbalance between Glycolysis and Mitochondrial Respiration Induced by Low Temperature in Rice Plants (벼 냉해의 초기 기작으로서 생체막과 세포질 사이의 대사 불균형)

  • Lee, Keun-Pyo;Boo, Yong-Chool;Jung, Jin
    • Applied Biological Chemistry
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    • v.43 no.4
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    • pp.236-240
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    • 2000
  • Correlations between mitochondrial respiration, glycolysis activity and overall growth activity of rice (Oryza sativa: cv. Dasan) seedlings during low temperature exposure were studied in order to provide insights into the underlying mechanism for the primary phase of chilling injury in plants. Among cellular membranes involved in energy metabolism, only the mitochondrial inner membrane showed not only physical phase transition at ca. $13^{\circ}C$, as monitored by ESR spin label, but also functional phase transition at the same temperature, as assessed by cytochrome c oxidase activity. The main regulatory enzyme of glycolysis, phosphofructokinase, in situ did not suffer phase transition of its activity at least in the $4{\sim}27^{\circ}C$ range. Low temperature caused a significant accumulation of glucose 6-phosphate (G6P) and fructose 6-phosphate (F6P), which disappeared almost completely on rewarming of the seedlings. Temperature profiles of the steady state levels of G6P and F6P revealed the inflection point appearing at around phase transition temperature of the mitochondrial membrane. The results conform to our previous proposition on the mechanism for the early stage events of chilling injury that the accumulation of glycolytic metabolites in cells due to metabolic imbalance at low temperature gives rise to an excess supply of electrons during rewarming period, which, in turn, results in overproduction of active oxygen in mitochondria.

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