• Title/Summary/Keyword: Low temperature absorption

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A Numerical Analysis of a Revised VX Absorption Cooling Cycle (Revised VX흡수식 냉동사이클의수치 해석)

  • 장원영;정은수;김병주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.6
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    • pp.505-513
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    • 2001
  • A revised VX cycle using ammonia/water as the working fluid is a cycle which is suitable to produce cooling utilizing low temperature hat sources. The cycle was analyzed numerically to investigate the effects of the design and operating conditions on the performance. It was shown that both COP and cooling capacity were significantly influenced by the performance of he rectifier. Insufficient UA of the rectifier reduced both ammonia mass fraction and mass flow rate of the vapor entering the condenser, which produced cooling effect in the evaporator. As the temperature and the mass flow rate of the heat source increased, both COP and exergetic efficiency decreased due to the irreversibilities produced in heat exchangers, but cooling capacity did not vary much. Cooling capacity increased significantly as the coolant temperature decreased, although COP and exergetic efficiency remained nearly constant.

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An Experimental Study on the Characteristics of Evaluation with Feature of Self Levelling Primer (셀프레벨링 모르타르용 Primer 성상에 따른 특성평가에 관한 실험적 연구)

  • Kang, Dong-Gyun;Kim, Gyung-Yuk;Kim, Jung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.505-508
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    • 2006
  • Self-leveling mortar is walkable bottom mortar which can maintain the horizontality of self fluid and have the the quick-setting quality, the low-human-effort practicable material of high-quality bottom in construction. In accordance with more adhesive strength with bottom side and absorption control, Primer is used for purpose to prevent pin-hole occurrence by self leveling mortar application prior to construction. This study is composed measurement of absorption, adhesive strength. Used material is NP-40 as nonionic emulsifying agent, uses SA-210L as negative ion emulsifying agent, uses APS, SBS as ridical initiator. A result of test, in accordance with image of Primer, as low temperature and application frequency, indicates low absorption rate and adhesive strength, as solid powder and dryness time is increse, absorption rate and adhesive strength lowly shows figure.

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Effects of Synthesis Conditions on Luminescence Characteristics of Glutathione Capped ZnSe Nano particles (글루타티온이 캡핑된 ZnSe 나노 입자 발광 특성에 미치는 합성 조건의 영향)

  • Back, Geum Ji;Song, Ha Yeon;Lee, Min Seo;Hong, Hyun Seon
    • Journal of Powder Materials
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    • v.28 no.1
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    • pp.44-50
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    • 2021
  • Zinc selenide (ZnSe) nanoparticles were synthesized in aqueous solution using glutathione (GSH) as a ligand. The influence of the ligand content, reaction temperature, and hydroxyl ion concentration (pH) on the fabrication of the ZnSe particles was investigated. The optical properties of the synthesized ZnSe particles were characterized using various analytical techniques. The nanoparticles absorbed UV-vis light in the range of 350-400 nm, which is shorter than the absorption wavelength of bulk ZnSe particles (460 nm). The lowest ligand concentration for achieving good light absorption and emission properties was 0.6 mmol. The reaction temperature had an impact on the emission properties; photoluminescence spectroscopic analysis showed that the photo-discharge characteristics were greatly enhanced at high temperatures. These discharge characteristics were also affected by the hydroxyl ion concentration in solution; at pH 13, sound emission characteristics were observed, even at a low temperature of 25℃. The manufactured nanoparticles showed excellent light absorption and emission properties, suggesting the possibility of fabricating ZnSe QDs in aqueous solutions at low temperatures.

Modeling of Absorption/Desorption of Fuel in Oil film on the Cylinder Liner in SI Engines (오일유막의 연료 흡수 및 방출에 관한 연구)

  • 유상석;민경덕
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.9
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    • pp.165-171
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    • 1999
  • An oil layer fuel absorption /desorption modeling was developed. Multi-component fuel model has showed more reasonable condition than single component model. Henry's constant which is related to solubility is the most important variable in the oil layer absorption/desorption mechanism. The oil segments close to the top of the cylinder liner have more significant contribution to the fuel absorption and desorption process than other oil segments. At the warmed-up condition, the effect of the engine speed on the precent fuel absorbed/desorbed is minimal. But at low il film temperature, percent of fuel abosrbed/desorbed is decreased with increasing the engine speed because of low value of molecular diffusion coefficient of fuel. The amount of fuel trapped in the piston crevice is from 2 to 2.3 times larger than that of fuel in the oil fim. However, fuel form oil film slowly desorbs into the combustion chamber compared with fuel from the piston crevices when the engines is cold.

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Enhancement of Heat and Mass Transfer for a Vertical Type Absorber (수직흡수기의 열 및 물질전달 촉진)

  • 권오경
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.3
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    • pp.362-370
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    • 1998
  • Absorption systems require a heat source for working but they have a great merit in that relatively low-temperature and low-quality types of thermal energy such as solar heat and exhaust heat can be effectively utilized as heat source. However details research related to absorbers which have a great effect on performances has been rarely done and thus there has been a strong hope for positive developments to improve their efficiencies. This paper describes absorption experiments made with different inside tube diameters and shapes. The purpose of this study is to acquire basic knowledge about heat and mass transfer in a falling film type absorber with vertical inner tubes. Heat and mass transfer were measured for water vapor absorption into a water/LiBr solution flowing down an absorber of vertical inner tubes. As a result absorption acceleration tube compares bare tube and heat transfer improved by order of insert spring tube corrugated tube grooved tube. And the acceleration that is good provided in inserting spring tube for both sides of heat and mass transfer.

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A Study on the Prediction of Self-absorption in Opposed Flames Using WSGGM-Based Spectral Model (파장별 회체가스중합모델을 이용한 대향류 화염에서의 복사 흡수 예측에 관한 연구)

  • Kim, Uk-Jung;Viskanta, Raymond;Gore, Jay Prabhakar;Zhu, Xuelei
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.600-609
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    • 2001
  • WSGGM based low-resolution spectral model for calculating radiation transfer in combustion gases is applied to estimate self-absorption of radiation energy in one-dimensional opposed flow flames. Development of such a model is necessary in order to enable detailed chemistry-radiation interaction calculations including self-absorption. Database of band model parameters which can be applied to various one-dimensional opposed flow diffusion and partially premixed flames is created. For the validation of the model and database, low resolution spectral intensities at fuel exit side are calculated and compared with the results of a narrow band model with those based on the Curtis-Godson approximation. Good agreements have been found between them. The resulting radiation model is coupled to the OPPDIF code to calculate the self-absorption of radiant energy and compared with the results of an optically thin calculation and the results of a discrete ordinates method in conjunction with the statistical narrow band model. Significant self-absorption of radiation is found for the flames considered here particularly for the fuel side of the reacting zone. However, the self-absorption does not have significant effects on the flame structure in this case. Even in the case of the low velocity diffusion flame and the partially premixed flame of low equivalence ratio, the effects of self-absorption of radiation on the flame temperature and production of minor species are not significant.

Development of a Monitoring and Control System in Gas Purification Process (가스 정제공정의 감시 제어시스템 연구)

  • 조택선;양종화
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.313-317
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    • 1996
  • This work deals with description of gas purifing system to product high pure helium gas using low temperature absorption. The system controls temperature of heaters, open/close of solenoid valves and levels of liquid nitrogen to purify a raw gas and continuously products purified gas with perfoming alternatively purification and regeneration. We develop the monitoring and control program to monitor the gas purification process on real-time and control the process time with checking the impurities in purified gas. From the result of system operation, the developed monitoring and control system continuously products high pure helium gas with reducing impurities in raw gas to permitted limits(less than 0.01 ~ 0.05 ppm)

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Characteristics of Electronic Absorption Spectrum and Photoluminescence in Cast-Poly(3-hexylthiophene) Films (캐스팅법으로 제작한 Poly(3-hexylthiophene)의 흡수스펙트럼에 따른 형광 특성)

  • 김주승;구할본;조재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.57-60
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    • 1998
  • Poly(3-hexylthiophene)(P3HT) was synthesized by use of FeCl$_3$ as a oxidizing agent at $25^{\circ}C$. The infrared spectrum of our polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. P3HT contains the HT(head-to-tail) linkage larger than 64% based on NMR analysis. Electronic absorption and photoluminescence studies show that cast films of P3HT have three exciting state. Absorption spectrum was separated with three maximum peaks by Giese-French method and shifted to the shorter wavelength with increasing temperature. Separated absorption spectrum of P3HT is well adapted to PL peak appeared at longer wavelength. Low temperature PL spectrum is well separated at 669nm, 733nm and 812nm.

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Synthesis, Crystal Structure, Spectra Characterization and DFT Studies on a Di-Cycle Pyrazoline Derivative

  • Song, Jie;Zhao, Pu Su;Zhang, Wei Guang
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1875-1880
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    • 2010
  • A dicycle pyrazoline derivative, 1-phenyl-5-(p-fluorophenyl)-3,4-($\alpha$-p-fluoro-tolylenecyclohexano) pyrazoline, was synthesized and characterized by elemental analysis, IR, UV-vis, fluorescence spectra and X-ray single crystal diffraction. Density function theory (DFT) calculations were performed by using B3LYP method with 6-$311G^{**}$ basis set. The optimized geometry can well simulate the molecular structure. Vibrational frequencies were predicted, assigned and compared with the experimental values, which suggest that B3LYP/6-$311G^{**}$ method can well predict the IR spectra. Both the experimental electronic absorption spectra and the predicted ones by B3LYP/6-$311G^{**}$ method reveal three electron-transition bands, with the theoretical ones having some red shifts compared with the experimental data. Natural bond orbital analyses indicate that the absorption bands are mainly derived from the contribution of n $\rightarrow\pi^*$ and $\pi\rightarrow\pi^*$ transitions. Fluorescence spectra determination shows that the title compound can emit blue-light at about 478 nm. On the basis of vibrational analysis, the thermodynamic properties of title compound at different temperature have been calculated, revealing the correlations between $C^0_{p,m}$, $S^0_m$, $H^0_m$ and temperature.

Design of a High Temperature Production Heat Pump System Using Geothermal Water at Moderate Temperature (중온 지열수를 이용한 고온제조 열펌프 시스템 해석 및 설계)

  • Kim, Min-Sung;Baik, Young-Jin;Park, Seong-Ryong;Chang, Ki-Chang;Lee, Young-Soo;Ra, Ho-Sang
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.638-641
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    • 2008
  • Geothermal water at moderate temperature in a range between 30 to $50^{\circ}C$ exists sparse in surroundings. Mostly they are utilized as heat or water source at spar zones in Korea. However, a large portion of used water is discarded due to its poor recovery quality and inferior application technologies. In this research, an innovative heat pump system based on the hybrid concept that combinate compression cycle and absorption cycle was investigated mathematically. The hybrid heat pump aims to recycle various kind of the heat sources at moderate temperature including geothermal water effectively. The prime objective of the simulation is to design a compression/absorption hybrid heat pump system which can make high temperature above the level of $90^{\circ}C$ and low temperature of $20^{\circ}C$ as well at the same using $50^{\circ}C$ geothermal heat water. As a result, primitive data was provided as a basis to design a prototype 3 RT class hybrid heat pump.

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