• Title/Summary/Keyword: Low sulfur fuel

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The Effect of Biodiesel Oxidation Deterioration on Emission (바이오디젤의 산화가 배출가스에 미치는 영향)

  • Song, Hoyoung;Lee, Minho;Kim, Kiho;Jung, Choongsub
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.220.2-220.2
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    • 2011
  • Biodiesel and biodiesel blend fuel are receiving increasing attention as alternative fuels for diesel engines without substantial modifications. Biodiesel fuels and blending have been widely studied and applied in diesel engine because of biodiesel's lower sulfur, lower aromatic hydrocarbon and higher oxygen content. Biodiesels have the potential to be oxidized in different condition. It has reported that oxidation deterioration of biodiesel is different in the condition of storage and oxidation causes chemical property change of methyl esters. Sunlight intensity, temperature, material of container and contact surface with oxygen are key dominant factors accelerating oxidation deterioration. In this study, we chose temperature among key oxidation conditions and metal container filled with biodiesel was heated at about $110^{\circ}C$ for 10 days in order to accelerate oxidation deterioration. To better understand the effect of biodiesel blends on emission, steady state tests were conducted on a heavy duty diesel engine. The engine was fueled with Ultra Low Sulphur Diesel(ULSD), a blend of 10% and 20%(BD10, BD20) on volumetric basis, equipped with a common rail direct injection system and turbocharger, lives up to the requirements of EURO 3. The experimental results show that the blend fuel of normal biodiesel with BD10 and BD20 increased NOx. The result of PM was similar to diesel fuel on BD10, but the result of PM on BD20 was increased about 63% more than its of diesel. The blend fuel of Oxidation biodiesel with BD10 and BD20 increased NOx as the results of normal biodiesel. But PM was all increased on BD10 and BD20. Especially THC was extremely increased when test fuel contains biodiesel about 140% more than its of diesel. Through this study, we knew that oxidation deterioration of biodiesel affects emission of diesel engine.

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Characteristics of Nano-particle Emitted by Auto-ignited Engine with ULSD, Bio-diesel and DME Fuel and Effects of Oxidation Catalyst on Its Reduction (디젤연소가능 청정연료(ULSD, Bio-Diesel, DME)엔진의 극미세입자 정량화 및 촉매 영향)

  • Lee, Jin-Wook;Bae, Choong-Sik;Schonborn, Alessandro;Ladommatos, Nicos
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.3
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    • pp.81-89
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    • 2009
  • In this experimental study, the effects of clean alternative fuels compatible with diesel combustion on nano-sized particle emission characteristics were investigated in a 0.5L auto-ignited single-cylinder engine with a compression ratio of 15. Because the number concentration of nano-sized particles emitted by automotive engine, that are suspected of being hazardous to human health and environment, might increase with engine fuel considerably and recently attracted attention. So a ultra-low sulfur diesel(ULSD), BD100(100% bio-diesel) and Di-Methyl Ether(DME) fuels used for this study. And, as a particle measuring instrument, a fast-response particle spectrometer (DMS 500) with heated sample line was used for continuous measurement of the particle size and number distribution in the size range of 5 to 1000nm (aerodynamic diameter). As this research results, we found that this measurements involving the large proportion of particles under size order of 300nm and number concentration of $4{\times}10^9$ allowed a single or bi-modal distribution to be found at different engine load conditions. Also the influence of oxygen content in fuel and the catalyst could be a dominant factor in controlling the nano-sized particle emissions in auto-ignited engine.

Study on Equivalent Consumption Minimization Strategy Application in PTI-PTO Mode of Diesel-Electric Hybrid Propulsion System for Ships

  • Lee, Dae-Hong;Kim, Jong-Su;Yoon, Kyoung-Kuk;Hur, Jae-Jung
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.3
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    • pp.451-458
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    • 2022
  • In Korea, five major ports have been designated as sulfur oxide emission control areas to reduce air pollutant emissions, in accordance with Article 10 of the "Special Act on Port Air Quality" and Article 32 of the "Ship Pollution Prevention Regulations". As regulations against vessel-originated air pollutants (such as PM, CO2, NOx, and SOx) have been strengthened, the Ministry of Oceans and Fisheries(MOF) enacted rules that newly built public ships should adopt eco-friendly propulsion systems. However, particularly in diesel-electric hybrid propulsion systems,the demand for precise control schemes continues to grow as the fuel saving rate significantly varies depending on the control strategy applied. The conventional Power Take In-Power Take Off(PTI - PTO) mode control adopts a rule-based strategy, but this strategy is applied only in the low-load range and PTI mode; thus, an additional method is required to determine the optimal fuel consumption point. The proposed control method is designed to optimize fuel consumption by applying the equivalent consumption minimization strategy(ECMS) to the PTI - PTO mode by considering the characteristics of the specific fuel oil consumption(SFOC) of the engine in a diesel-electric hybrid propulsion system. To apply this method, a specific fishing vessel model operating on the Korean coast was selected to simulate the load operation environment of the ship. In this study, a 10.2% reduction was achieved in the MATLAB/SimDrive and SimElectric simulation by comparing the fuel consumption and CO2 emissions of the ship to which the conventional rule-based strategy was applied and that to which the ECMS was applied.

Study on Emission Control for Precursors Causing Acid Rain (VI) : Suitability of Aquatic Plant Biomass as a Co-combustion Material with Coal

  • Hauazawa, Atsushi;Gao, Shidong;Sakamoto, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • v.2 no.2
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    • pp.102-108
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    • 2008
  • In China, energy and environmental problems are becoming serious owing to rapid economic development. Coal is the most problematic energy source because it causes indoor and outdoor air pollution, acid rain, and global warming. One type of clean coal technology that has been developed is the coal-biomass briquette (or bio-briquette, BB) technique. BBs, which are produced from pulverized coal, biomass (typically, agricultural waste), and a sulfur fixation agent (slaked lime, $Ca(OH)_2$) under high pressure without any binder, have a high sulfur-fixation effect. In addition, BB combustion ash, that is, the waste material, can be used as a neutralization agent for acidic soil because of its high alkalinity, which originates from the added slaked lime. In this study, we evaluated the suitability of alternative biomass sources, namely, aquatic plants, as a BB constituent from the perspective of their use as a source of energy. We selected three types of aquatic plants for use in BB preparation and compared the fuel, handling, and environmental characteristics of the new BBs with those of conventional BBs. Our results showed that air-dried aquatic plants had a higher calorific value, which was in proportion to their carbon content, than agricultural waste biomass; the compressive strength of the new BBs, which depends on the lignin content of the biomass, was high enough to bear long-range intracontinental transport in China; and the new BBs had the same emission control capacity as the conventional BBs.

GTL(Gas-to-Liquid) 기술 현황

  • Jun, Gi-Won
    • Journal of Energy Engineering
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    • v.16 no.2
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    • pp.58-63
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    • 2007
  • In recent years, the technologies for the production of synthetic fuel from natural gas have been attracting considerable interest because of high oil prices. While oil prices remaining high, GTL (Gas-to-Liquids) technology would provide an attractive option for utilizing gas resources. Furthermore, GTL fuels contain almost zero sulfur and low aromatics and have a very high cetane so that they are estimated to be environmentally friendly diesel fuels able of meeting the advanced fuel specifications of the 21st century. GTL process generally consists of three primary steps: synthesis gas production from natural gas reforming, hydrocarbon production from synthesis gas by Fischer-Tropsch (F-T) synthesis, product upgrading by hydrocracking/hydroisomerization. This paper presents a brief summary of GTL technology and worldwide development trend about it focusing on the reforming of natural gas and the F-T synthesis.

Development and Evaluation on a Model for Reducing SO2: Case Study on Global 2100 Model (산성비 원인물질인 이산화황 저감모형 구축과 평가에 관한 연구: Global 2100 모형을 중심으로)

  • Lee, Dong-Kun
    • Journal of Environmental Impact Assessment
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    • v.6 no.2
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    • pp.93-102
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    • 1997
  • Acid rain below pH 5.6 is responsible for 40% of annual precipitation in Korea and it is more serious especially in major cites. Because of that, it is urgent to make measures to reduce the emission of $SO_2$, one of the major air pollutants causing acid rain. The national total emission of $SO_2$ in 1994 was estimated as 1.6 million tons. The $SO_2$ emission in 2020, is expected to increase up to 3.2 million tons, about 2 times that of 1994 under Business-As-Usual scenario. We could take various $SO_2$ reduction measures such as installing desulfurization facilities, the supply of low-sulfur oil and clean fuel(LNG), energy savings, upgrading of production process. However, it is necessary to check the economic feasibility and the attainability to reduction target with a dynamic optimization mode, "Global 2100 Model". The cost-benefit analyses for the measures using the revised "Global 2100 Model" clearly revealed that the desulfurization facilities should be introduced to reduce the $SO_2$ concentration to 0.01 ppm with fuel substitution. If the introduction of desulfurization facilities is delayed, We can not attain the goal of Ministry of Environment before the year of 2012, even in the case that almost all the fuels would be substituted with LNG.

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Basic study of residual marine fuels quality (선박용 잔사유의 품질에 대한 기초연구)

  • Park, Hee-Woo;Chun, Kang-Woo;Kim, Jin-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.4
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    • pp.362-368
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    • 2016
  • In the recent International Maritime Organization's (IMOs) Maritime Safety Committee's 93rd session, the International Chamber of Shipping and International Parcel Tankers Association addressed marine fuel oil quality problems: increasing diluents in marine fuel oil, ignition in engine rooms due to the low flash point of fuel oil, and marine fuel oils that can damage marine engines. To deal with these marine fuel oil quality problems, the International Maritime Organization secretariat appointed the worlds marine fuel oil monitoring institute and constituted a correspondence group to determine the fuel oil quality required by MARPOL Annex VI regulation 14.8 (sulfur content less than 0.5%). In this study, basic research that can help with responding to marine fuel quality issues and the IMO's work is conducted. In order to perform this basic research, the off-spec ratio related to the fuel oil quality standard (ISO 8217:2012), density distribution tendency, gross specific energy, and correlation between components in the fuel oil are analyzed through actual marine fuel oil (residual marine fuel) data from the Port of Singapore.

A Study of Optical Characteristics for Biodiesel and Diesel Smoke Particles and Measuring their Dimensionless Light Extinction Constants (바이오디젤과 디젤 연기입자의 광학특성 및 무차원 광소멸계수 측정에 관한 연구)

  • Choi, Seuk-Cheun;Jang, Yeong-Seok;Park, Seul-Hyun;Kim, Youn-Kyu
    • Fire Science and Engineering
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    • v.30 no.1
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    • pp.37-42
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    • 2016
  • The dimensionless extinction constants of smoke particles produced from burning of soy methyl ester (B100) biodiesel and ultra low sulfur diesel (ULSD) fuels were measured. To this end, optical measurements of smoke volume fraction with the aid of a He-Ne laser at 633 nm were compared to the simultaneous gravimetric measurements. The average value of measured dimensionless extinction constants at 633 nm was 11.8 for biodiesel smoke particles and 11.1 for diesel smoke particles, respectively whose values are very comparable withing the range of measurement uncertainty (${\pm}10.1%$). The analysis of Raman spectroscopy revealed that overall characteristics of light extinction between particles produced from each fuel may differ from each other.

A Study on Exhaust Gas of Diesel Engine with a ULSD, CR-DPF and EGR (ULSD, CR-DPF와 EGR을 적용한 디젤기관의 배출가스에 관한 연구)

  • Moon, Byung-Chul;Oh, Yong-Suk
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.5
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    • pp.85-90
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    • 2006
  • Since air pollution has become a globally critical issue and exhaust emissions from automobiles cause a major source of air pollution, many countries including advanced countries have stipulated stringent emission regulations. This test was conducted on the effect of continuous regeneration diesel particulate filter and cooled-EGR, and 15ppm low sulfur diesel was used as a test fuel. Exhaust emissions, PM, NOx, CO, HC and Soots were measured and compared under D-13modes. Through durability test on diesel particulate filter, regeneration characteristics and control technology on PM were investigated in overall.

A Study on Recycling of Waste Tire (폐타이어 재 자원화를 위한 연구)

  • 이석일
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.38-44
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    • 2000
  • Compared to other waste, waste tire has much discharge quantity and calorie. When we use waste heat from waste tire, it can be definitely better substitute energy than coal and anthracite in high oil price age. To use as a basic data for providing low cost and highly effective heating system, following conclusion was founded. Annual waste tire production was 19,596 million in 1999, Recycling ratio was almost 55% and more than 8.78 million was stored. Waste tire has lower than 1.5% sulfur contain ratio which is resource of an pollution, So it is a waste fuel which can be combustion based on current exhaust standard value without any extra SOx exclusion materials. Waste tire has 9,256Kcal/kg calorific value and it is higher than waste rubber, waste rubber, waste energy as same as B-C oil. When primary and second air quantity was 1.6, 8.0 Nm$^3$/min, dry gas production time was 270min and total combustion time was 360 min. In the SOx, NOx, HC of air pollution material density were lower than exhaust standard value at the back of cyclone and dusty than exhaust standard value without dust collector.

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