• Title/Summary/Keyword: Low heavy oil

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Use of hazardous event frequency to evaluate safety integrity level of subsea blowout preventer

  • Chung, Soyeon;Kim, Sunghee;Yang, Youngsoon
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.8 no.3
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    • pp.262-276
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    • 2016
  • Generally, the Safety Integrity Level (SIL) of a subsea Blowout Preventer (BOP) is evaluated by determining the Probability of Failure on Demand (PFD), a low demand mode evaluation indicator. However, some SIL results are above the PFD's effective area despite the subsea BOP's demand rate being within the PFD's effective range. Determining a Hazardous Event Frequency (HEF) that can cover all demand rates could be useful when establishing the effective BOP SIL. This study focused on subsea BOP functions that follow guideline 070 of the Norwegian Oil and Gas. Events that control subsea well kicks are defined. The HEF of each BOP function is analyzed and compared with the PFD by investigating the frequency for each event and the demand rate for the components. In addition, risk control options related to PFD and HEF improvements are compared, and the effectiveness of HEF as a SIL verification for subsea BOP is assessed.

Recovery of Lipids from Chlorella sp. KR-1 via Pyrolysis and Characteristics of the Pyrolysis Oil (Chlorella sp. KR-1 열분해에 의한 지질 회수 및 열분해 오일 특성 분석)

  • Lee, Ho Se;Jeon, Sang Goo;Oh, You-Kwan;Kim, Kwang Ho;Chung, Soo Hyun;Na, Jeong-Geol;Yeo, Sang-Do
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.672-677
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    • 2012
  • Lipids in microalgal biomass were recovered by using pyrolysis method. The pyrolysis experiments of two Chlorella sp. KR-1 samples, which have triglyceride contents of 10.8% and 36.5%, respectively were carried out at $600^{\circ}C$ to investigate the effects of lipid contents in the cells on the reaction characteristics. The conversion and liquid yield of the lipid-rich sample were higher than those of the lipid-lean sample since its carbon to hydrogen ratio was low. There were low molecular weight organic acids, ketones, aldehydes and alcohols in the liquid products from both KR-1 samples, but the pyrolysis oil of the lipid-rich sample was abundant in free fatty acids, particularly palmitic acid, oleic acid and stearic acid while the content of nitrogen containing organic compounds was low. The microalgal pyrolysis oil had two layers composed of the light hydrophobic fraction and the heavy hydrophilic fraction. The light fraction might be originated from triglycerides and the heavy fraction might be from carbohydrates and proteins. In the light fraction of the liquid products, there were considerable linear alkanes such as pentadecane and heptadecane as well as free fatty acids, implying that deoxygenation reaction including decarboxylation was occurred during the pyrolysis. The yield of the liquid products from the pyrolysis of the KR-1 sample having triglyceride content of 36.5% was 56.9% and the light fraction in the liquid products was 68.2%. Also more than 80% of the light fraction was free fatty acids and pure hydrocarbons, thus showing that most triglycerides could be extracted in the form of suitable raw materials for biofuels.

Development of Low Temperature Thermal Desorption System and Remediation of Soil Contaminated with Petroleum Hydrocarbon (열순환식 저온열탈착 정화장치의 개발 및 유류오염 토양 현장 적용)

  • Kim, Guk-Jin;Lee, Sun-Hwa;Park, Kwang-Jin;Kim, Chi-Kyung;Lee, Cheol-Hyo;Kim, Do-Sun;Cho, Seok-Hee;Chang, Youn-Young
    • Journal of Soil and Groundwater Environment
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    • v.13 no.4
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    • pp.62-68
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    • 2008
  • The Low Temperature Thermal Desorption (LTTD) System equipped with a soil transfer unit, a rotary kiln, RTO, cyclones and a bag filter etc. was developed. The LTTD system was designed to be economically operated using LPG as a fuel and recirculating the discharged gas from the LTTD system through RTO. For the performance test of LTTD system the soil contaminated with light and heavy oils (2,690 mg TPH/kg soil) and with particle sizes below 50 mm was fed into the rotary kiln of LTTD system at 7$m^3$/hr with retention time of 15 minutes. Operation temperatures of LTTD system for the removal of soil TPH were $567^{\circ}C$ and $692^{\circ}C$. The residual TPH after treatment was 46 mg/kg and 32mg/kg respectively at each temperature condition, which shows high TPH removal efficiencies of the developed LTTD as 98.3% and 98.9%.

Flexible Multi-body Dynamic Analysis for Reducer-integrated Motor of Autofilter (오토필터의 감속기 일체형 모터에 관한 유연 다물체 동역학 해석)

  • J.K. Kim;B.D. Kim;G.S. Lee
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.5
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    • pp.311-317
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    • 2023
  • An autofilter is a device that removes impurities contained in heavy fuel oil used in diesel engines of ships or power plants, and also automatically removes impurities accumulated in the filter through a reverse washing function. The reducer-integrated motor serves to rotate the filter at low speed to enable reverse automatic cleaning in the autofilter device. To achieve a low speed of 0.65 to 0.75 rpm in a reducer-integrated motor, a small motor that can operate at 97rpm at a rated voltage of 110 V and 112.5 rpm at 220 V is required. Additionally, a large gear ratio of 1/150 is required. To ensure the durability and reliability of these reducers, the strength of the gear must be evaluated at the design stage. In general, there is a limit to evaluating the stress and strain state according to the vibration characteristics acting on each gear in the driving state of the reducer through quasi-static analysis. Therefore, in this study, the operation characteristics of the auto filter's reducer-integrated motor were first analyzed using the rigid body dynamics analysis method. Then, this rigid body dynamics analysis model was extended to a flexible multibody dynamics analysis model to analyze the stress and strain states acting on each gear and evaluate the design feasibility of the gear.

Dispersion of Toxic Elements in the Area Covered with Uranium-Bearing Black Shales in Korea (함(含)우라늄 흑색(黑色)세일 분포지역(分布地域)에서의 유독성원소(有毒性元素)들의 분산(分散)에 관한 지구화학적(地球化學的) 연구(硏究))

  • Chon, Hyo-Taek;Jung, Myung-Chae
    • Economic and Environmental Geology
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    • v.24 no.3
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    • pp.245-260
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    • 1991
  • Surficial dispersion patterns of heavy metals and toxic elements (U, Mo, Cu, Zn, Fe, Mn, Co, Cr, V, Ni, Pb, and Cd) were investigated in the Dukpyungri, Goesan area covered with low grade uranium-bearing black shales. Maximum abundance of U in the black shale was 455ppm. Radioactivity was counted at a maximum of 7cps in black shales, and was less than 0.5cps in shales, slates, and oil shales of the control areas. Enrichment of Mo, V, Cu, Zn, Cd, and Pb in black shales is particularly characteristic compared with shales, slates, and oil shales of the control areas, whereas contents of Mn, Cr, Co, and Th in all rock samples tend to be almost similar. Residual top soils (0~15cm depth) over black shales show high contents of Mo, Cu, Zn, Ni, Cd, and V in comparison with the control areas. Contents of trace elements in subsoils (15~30cm depth) were higher about one and half times than those in topsoils. Average contents of Mo, Cu, Pb, Zn, Cd and V in garden soil and playground soil of an elementary school in Dukpyungri, Goesan area, were high about two to fifteen times compared with the control areas. Contents of trace elements in stream sediments were higher from two to eight times than those in residual soils. Sodium, AI, K, V, Cr, and Fe were more enriched in the roots of pine than in the twigs of pine. Contents of Li, AI, V, Ni, Cd, Fe, and Co were higher in the roots of azalea than in the twigs of azalea. Enrichment of P, Ca, and Mg was remarkable in the twigs of both pine and azalea. Biological absorption coefficients for essential elements (Zn, P, Mn, Ca and K)tend to be high, whereas those for the non-essential elements.(Ba, Ti, V, and Mo) and toxic elements(Cr, Co, Pb and Ni) be low. Less mobile elements (Pd, Cd, and Co) tend to show anomalies with higher contrast than more mobile elements(Mo, V, Zn, Cu and Ni) in the area covered with black shales.

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ANTI-ANGIOGENIC ACTIVITY OF GENISTEIN IN ORAL CARCINOGENESIS (구강암 발암과정에서 genistein의 혈관형성 억제에 관한 연구)

  • Song, Seung-Il;Kim, Myung-Jin
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.30 no.5
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    • pp.400-405
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    • 2004
  • Angiogenesis inhibition is major concern to cancer chemotherapy and many studies about compound inhibiting angiogenesis is in progression. The long-known preventive effect of plant-based diet on tumorigenesis and other chronic diseases is well documented. Especially soy extract, genistein, is known to be potent angiogenesis inhibitor and prevent development and progression of tumor. In the present study, the effect of angiogenesis on tumorigenesis and chemopreventive effect of genistein by angiogenesis inhibition in hamster buccal pouch oral carcinigenesis model induced by 7.12-dimethylbenza(a)nthracene (DMBA) was studied. Forty eight Syrian Golden young adult hamsters (150-200 gm) were divided into two groups. In control group, 0.5% DMBA in heavy mineral oil was applied to hamster buccal pouch three times a week and in experimental group, 0.1 mg of genistein is administered orally everyday in addition to DMBA application. The animals were euthanized from 2 weeks to 16 weeks with interval of 2 week. H&E staining and immunohistochemistry was performed to evaluate microvessel density by using factor VIII-related antigen and avidin-biotin technique. Microvessels per area was quantified and compared between control and experimental group statistically. The results were as follows. 1. Microvessel density was increased time dependently in both groups and especially the increase was significant from 12 weeks to 16 weeks. 2. When comparing both group, the experimental group showed significantly low microvessel density than control group in 12 weeks (p=0.043), 14 weeks (p=0.050), 16 weeks (p=0.037). Based on these results, it was concluded that genistein influenced oral carcinogenesis by angiogenesis inhibition.

Computational Simulation of Carburizing and Quenching Processes of a Low Alloy Steel Gear (저합금강 기어의 침탄 및 소입 공정에 대한 전산모사)

  • Lee, Kyung Ho;Han, Jeongho;Kim, Gyeong Su;Yun, Sang Dae;Lee, Young-Kook
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.6
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    • pp.300-309
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    • 2015
  • The aim of the present study was to predict the variations in microstructure and deformation occurring during gas carburizing and quenching processes of a SCM420H planetary gear in a real production environment using the finite element method (FEM). The motivation for the present study came from the fact that previous FEM simulations have a limitation of the application to the real heat treatment process because they were performed with material properties provided by commercial programs and heat transfer coefficients (HTC) measured from laboratory conditions. Therefore, for the present simulation, many experimentally measured material properties were employed; phase transformation kinetics, thermal expansion coefficients, heat capacity, heat conductivity and HTC. Particularly, the HTCs were obtained by converting the cooling curves measured with a STS304 gear without phase transformations using an oil bath with an agitator in a real heat treatment factory. The FEM simulation was successfully conducted using the aforementioned material properties and HTC, and then the predicted results were well verified with experimental data, such as the cooling rate, microstructure, hardness profile and distortion.

Prismatic-core advanced high temperature reactor and thermal energy storage coupled system - A preliminary design

  • Alameri, Saeed A.;King, Jeffrey C.;Alkaabi, Ahmed K.;Addad, Yacine
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.248-257
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    • 2020
  • This study presents an initial design for a novel system consisting in a coupled nuclear reactor and a phase change material-based thermal energy storage (TES) component, which acts as a buffer and regulator of heat transfer between the primary and secondary loops. The goal of this concept is to enhance the capacity factor of nuclear power plants (NPPs) in the case of high integration of renewable energy sources into the electric grid. Hence, this system could support in elevating the economics of NPPs in current competitive markets, especially with subsidized solar and wind energy sources, and relatively low oil and gas prices. Furthermore, utilizing a prismatic-core advanced high temperature reactor (PAHTR) cooled by a molten salt with a high melting point, have the potential in increasing the system efficiency due to its high operating temperature, and providing the baseline requirements for coupling other process heat applications. The present research studies the neutronics and thermal hydraulics (TH) of the PAHTR as well as TH calculations for the TES which consists of 300 blocks with a total heat storage capacity of 150 MWd. SERPENT Monte Carlo and MCNP5 codes carried out the neutronics analysis of the PAHTR which is sized to have a 5-year refueling cycle and rated power of 300 MWth. The PAHTR has 10 metric tons of heavy metal with 19.75 wt% enriched UO2 TRISO fuel, a hot clean excess reactivity and shutdown margin of $33.70 and -$115.68; respectively, negative temperature feedback coefficients, and an axial flux peaking factor of 1.68. Star-CCM + code predicted the correct convective heat transfer coefficient variations for both the reactor and the storage. TH analysis results show that the flow in the primary loop (in the reactor and TES) remains in the developing mixed convection regime while it reaches a fully developed flow in the secondary loop.

Characteristics of Liquid-Liquid Direct Contact Heat Exchanger for a Solar System (태양열 이용을 위한 직접접촉식 액-액 열교환기 특성)

  • 강인석;김종보;강용혁;곽희열
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.12
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    • pp.3276-3286
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    • 1994
  • In most direct contact liquid-liquid heat exchangers, oil or hydrocarbon with a density less than water is normally used as dispersed working fluid. The main difficulty that arises with this arrangement lies in the control of the interface at the top of the column. When it is connected with a solar collector which uses water as its working fluid, the main difficulties arise from the fact that the water can be frozen during winter time. In order to solve these problems and to demonstrate the technical feasibility of a direct contact liquid-liquid heat exchanger, liquids heavier than water with low freezing temperature has been utilized as dispersed phase liquids in a small laboratory scale model made of pyrex glass. In the present investigation, dimethyl phthalate(C/sub 6/H/sub 4/)COOCH/sub 3/)/sub 2/) and diethyl phthalate (C/sub 6/H/sub 4/(CO/sub 2/C/sub 2/H/sub 5/)/sub 2/) are utilized as heavy dispersed phase working fluids. The results of the present investigation the technical in the utilization of heavier dispersed working liquid in the spray-column liquid-liquid heat exchanger for a solar system. The overall average temperature difference along the column is found to be almost half of the initial temperature difference between the dispersed and the continuous phase. Despite the fact that the two phthalates tested in the experiment differ significantly in some of their physical properties, the volumetric heat transfer coefficients in terms of dispersed fluid superficial velocities were found to be similar for both phthalates tested.

Quilitative certificational plan of chenpi (진피(陳皮)의 품질인증(品質認證) 방안(方案))

  • Hyun, Jong-Uk;Roh, Seong-Soo;Kil, Ki-jeong;Seo, Bu-il;Seo, Young-Bae
    • Journal of Haehwa Medicine
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    • v.13 no.2
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    • pp.197-204
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    • 2004
  • Now many sustitution and false articles is used in korea instead of chenpi. To use chenpi correctly, we will make a quilitative certificational plan of chenpi to investigate all of lieraturea, records and documents. And we could reach conclusions as folloews. 1) Source In china source of Chen-pi is pericarp of citrus reticula Blanco(Family;rutaceae)and in korea source of Chen-pi is pericarp of citrus unshiu Markovich(Family;rutaceae). Though source of both countries are not same, it has no problems because of containing family plants and culture variants. 2) Harvesting and processing After the peel attained full growth, wash cleanly in water. And dry in shade or in low temporature at state of eliminating pericarp. 3) Quality (1) Functional standards Exocarp is soft and clear yellow with numerous oil sports. The less white mesocarp is the better. (2) Physicochemical standards We need to suggest new standards about hesperidin to various conditions by processing methods and storing time. The loss on drying is less than 13.5%. Ash content is less than 4.0%. A standard capacity of hesperidin is more than 4.0%. The content of heavy metal is less than 30 ppm. We can not detect reminding agricultural medicines.

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