• Title/Summary/Keyword: Low alkali

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Studies on the Manufacturing of Pollution-Free Korean Traditional Paper without Bleaching (I) (표백(漂白)이 필요없는 무공해(無公害) 전통한지(傳統韓紙)의 제조(製造)에 관한 연구(硏究) (제(第) 1 보(報)))

  • Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.2
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    • pp.49-56
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    • 1993
  • This study was performed to investigate the pollution-free Korean traditional papermaking characteristics from paper mulberry by sulfomethylation pulping. Bast fibers were pulped by sulfomethylated cooking liquor, and by alkali and alkali-peroxide processes for the comparison. Sulfomethylated pulping resulted in the superior pulp with high yield and better quality compared to those of alkali and alkali-peroxide pulps. Since the pulp was so bright, there was almost no need additional bleaching. Pollutant loads of sulfomethylated pulping effluent were very low in terms of pH, turbidity and color compared to those of alkali. Pollution-free effluents was accomplished by simple filtering treatment with pine bark, charred rice hull and sawdust compost. Pine bark was the most effective in reduction rate of pollutants.

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An Experimental Study on the Alkali-Recovery Performance of Impregnating Alkalization Agent for Deteriorated Concrete by Carbonation (침투성 알칼리성부여제 도포에 의한 중성화된 콘크리트의 알칼리성 회복성능에 관한 실험적 연구)

  • 김무한;강석표;유재강;권영진
    • Journal of the Korea Concrete Institute
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    • v.13 no.1
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    • pp.9-15
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    • 2001
  • The low-durability performance of concrete structure occurs by interactive deterioration factors. In particular, carbonation increased with its time elapse is known as the general manner of deterioration characteristics. Recently, the fundamental researches of the carbonation mechanism, besides method and technique for durability improvement of deteriorated structure are advanced actively. So in this paper, alkali-recovery and maintenance performance when the impregnating alkalization agents are used, are compared and examined quantitively with the basis of past proposed study. As a result, alkali-recovery performance be ensured by impregnating alkalization agent on the carbonated concrete which has low pH by accelerated carbonation test. And alkali maintenance performance was effected by the finishing materials on the alkali recovered concrete.

Identification of Alkali Reactivity of Natural Aggregates by Application of a Rapid Method (촉진시험법을 이용한 하천골재의 알칼리 반응성 판정)

  • Yang, Dong-Yoon;Lee, Chang-Bum
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.175-183
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    • 1997
  • The concrete structure can be easily damaged due to alkali-aggregates reaction. There are several methods to identify alkali reactivity of aggregates. The most reliable method is mortar-bar test, but it takes 3 to 12 months for whole test. The authors applied "rapid method" which takes only 7 days for this test. The result of this rapid method follows; expansion ratio of mortar bar for natural aggregates taken at the Youngsan River ranges from 0.197 to 0.489%, but that from Changseong Lake has low expansion ratio of 0.147%, which is below the limit of allowance, 0.168%. Those from the Seomjin River range from 0.173 to 0.22%, and those from the Keum River range from 0.078% to 0.111%. In the case of higher expansion ratio than 0.168%, aggregates must be used with cement containing low alkali content or adding material consuming the alkali content of cement, for example, fly ash and silica fume, etc.. Most of natural aggregates in Cheolla area have no problem in physical properties, particularly the abrasion ratio is below 40%, the limit of allowance. The natural aggregate from Cheolla area consists mostly of gneiss, granite and volcanic rocks. The major alkali reactive materials are quartz mineral with undulatory extinction in gneiss and granite, and amorphous silica in volcanic rocks. Even if a certain aggregate consists of the same kind of rocks and has similar rock composition each other, content of alkali reactivity material can be various, because rock formation is locally different according to temperature and pressure. Therefore every rock type must be physically and chemically identified before using for aggregates.

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Effect of Color Developing by Alkali and Heating of Cotton Fabrics Dyed with Persimmon Extract (알칼리와 열처리에 의한 면직물의 감즙염색 발색효과)

  • Kim, Ok-Soo;Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.13 no.6
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    • pp.972-982
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    • 2011
  • The purpose of this study is to improve the method of color developing with alkali solution as a promotor of color developing for feasible use. Cotton fabric was dyed with persimmon extract ranged with 0~3% alkali component with 5 types of strong to mild alkali solution. Heat treatment for color developing was applied to fabric dyed with persimmon extract and alkali mixing solution. Tests were carried out to analyze the change of surface color, ${\Delta},Ea^*b^*$, and water repellent of the dyed cotton fabric. The alkali mixing sample showed higher ${\Delta},Ea^*b^*$ value than control one without alkali mixing on the base of dyed fabric due to high color developing by alkali in the initial step of dyeing process. As alkali concentration increased, deeper dark color appeared on the fabric. The fabric color was changed to more dark in the application of sodium hydroxide, sodium carbonate, potassium carbonate in the initial step of dyeing process but color was not changed by increased heating time. However, the fabric showed a slight dark color with sodium acetate and more color change than that of the fabric dyed with persimmon extract without alkali. Therefore, sodium acetate seemed to a suitable promotor for color developing in persimmon extract dyeing. Property of water repellent was showed after color developing by heating with low concentration of alkali treatment.

Kraft Pulping of Sapwood-A Sawmill Waste

  • Jahant M. Sarwar;Chowdhury D.A. Nasima;Islam M. Khalidul;Mun Sung Phil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.41-49
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    • 2005
  • This paper deals the effect of anthraquinone (AQ) on the contribution of sulphidity in kraft pulping of sapwood. The pulping conditions namely- active alkali concentration, pulpingtime, temperature and liquor ratio were varied in low ($15\%$) and high ($30\%$) sulphidity. $0.1\%$ AQ was added in the low and high sulphidity pulping with varying active alkali concentration and cooking time. At optimum conditions, low sulphidity kraft process produced about $44\%$ pulp yield with kappa number of about 23. But in high sulphidity kraft process kappa number was reduced to about 20 at the same yield. An addition of AQ reduced alkali requirement by $2\%$ on oven dried raw material and cooking time by 1 hour to produce pulp yield of about $44\%$ at kappa number 20. AQ is more effective in low sulphidity pulping than the high sulphidity pulping. The breaking length of kraft-AQ pulp was slightly higher than that of kraft pulp.

Spectrometer for the Study of Angle-and Energy-Resolved Reactive Ion Scattering at Surfaces

  • S-J. Han;C.-W. Lee;C.-H. Hwang;K.-H. Lee;M. C. Yang;H. Kang
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.883-888
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    • 2001
  • We describe an ion-surface scattering apparatus newly developed to investigate the reactive scattering process of low-energy alkali-metal ions at surfaces. The apparatus consists of an alkali-metal ion gun that is rotatable by 360°, a quadrupole mass spectrometer (QMS) with an ion energy analyzer, a sample manipulator with a heating-and-cooling stage, and an ultrahigh vacuum (UHV) chamber that houses these components. Preliminary experimental results obtained from the apparatus are presented on angular and energy distributions of the ions scattered from clean Pt(111) and water-adsorbed Pt surfaces.

Alkali metal free texturing for mono-crystalline silicon solar cell (알카리 금속을 배재한 단결정 실리콘 태양전지의 텍스쳐링 공정)

  • Kim, Taeyoon;Kim, Hoechang;Kim, Bumho
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.48.1-48.1
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    • 2010
  • Mono-crystalline silicon solar cell is fabricated by using alkali metals. These alkali metal, used in wet etching process, must be removed for the high efficiency solar cell. As wet etching process has been adapted due to its low cost. But lots of alkali metals like potassium remains on the silicon surface and acts as impurities. To remove these alkali metals many of cleaning process have to be applied when solar cell manufacturing process. In terms of alkali metal removal, modified etchant solution is required for concise cleaning process. In this paper ethylenediamine was used and proposed for the substituion of postassium hydroxide.

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Varietal Variation of Alkali Digestion Value and Its Relationship with Gelatinization Temperature and Water Absorption Rate of Milled Rice Grain (쌀 알칼리붕괴반응의 품종간 변이와 호화온도 및 수분흡수율과의 관계)

  • Kwang-Ho Kim
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.37 no.1
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    • pp.28-36
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    • 1992
  • Fifty rice varieties were tested for alkali digestibility of milled rice grain at four different KOH levels, and twenty-four varieties selected were tested again for alkali digestibility at different degrading times and KOH levels. Gelatinization rate at several heating times and heating temperatures, and water absorption rate at 21$^{\circ}C$ and 77$^{\circ}C$ water temperatures were observed using rice samples of twenty-four varieties to clarify the relationship between alkali digestibility response, gelatinization rate and water absorption rate. Varietal difference of ADV in Japonica and Tongil tye rices was biggest at KOH 1.2%, but it was better to test at KOH 1.2% and 1.4% levels to know the exact alkali digestibility response of rice varieties. Rice varieties tested could be classified into three groups, low, intermediate and high, based on their alkali digestibility response at four KOH levels, and most of Korean cultivated rice varieties were belonged to intermediate or high ADV group. Varietal variation was also found in alkali degrading response at different soaking times in alkali solution. Low ADV varietal group showed higher gelatinization temperature and needed longer heating time for complete gelatinization compared with intermediate or high ADV group. Same trends was found between intermediate and high ADV groups, but varietal variation in the same ADV group was also found in gelatinization temperature and heating time needed for complete gelatinization of rice grain. Water absorption rate of low ADV group was lower than intermediate or high ADV group both at 21$^{\circ}C$ and 77$^{\circ}C$ water temperatures, and intermediate ADV group showed lower absorption rate than high ADV group only in initial water absorption stage at 21$^{\circ}C$.

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Comparison of Alkali-Silica Reactivity for Mortar Bar and Concrete Prism Specimens Using Crushed Aggregates in Korea (국내 쇄석골재를 사용한 모르타르 봉 및 콘크리트 각주 시험편의 알칼리-실리카 반응성 비교)

  • Kim, Seong-Kwon;Yun, Kyong-Ku;Hur, In
    • International Journal of Highway Engineering
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    • v.14 no.5
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    • pp.93-99
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    • 2012
  • PURPOSES: The purpose of this study is to compare the alkali-silica reactivity for mortar bar and concrete prism specimens using crushed aggregates of 5 types in Korea. And the alkali-silica reactivity for those aggregates are measured by chemical test method. METHODS: The alkali-silica reactivity for those aggregates was measured by chemical test method of KS F 2545, mortar-bar test of KS F 2546, accelerated mortar-bar test method of ASTM C 1260 and concrete prism test method of ASTM C 1293, relatively. RESULTS: The alkali-silica reactivity for those aggregates was verified by chemical test of KS F 2546 and accelerated mortar-bar test of ASTM C 1260. However, it was not by mortar-bar test of KS F 2546 and concrete prism test of ASTM C 1293. CONCLUSIONS: The above results showed that relationship among the four test methods were very low. The results from 3 types of test methods using cement-aggregate combinations appeared to be different. Because the environmental conditions of test methods for measuring the alkali-silica reactivity such as equivalent alkali content(external source), humidity, temperature, and times were different though the aggregates were same. Moreover, alkali-silica reactivity showed the biggest impact when alkalis were supplied form outside and exposed to environmental conditions. The accelerated mortar-bar test method seems to be most appropriate test method for concrete structures exposed to alkali environment.

Structural and gelling properties of very low methoxyl pectin produced by an alkali-treatment

  • Lee, Byung-Hoo;Jung, Ho-Tak;Kim, Hyun-Seok;Yoo, Sang-Ho
    • Korean Journal of Food Science and Technology
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    • v.53 no.2
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    • pp.121-125
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    • 2021
  • Very low methoxyl pectin (VLMP) has different physical and rheological properties compared to high and low methoxyl pectins (HMP and LMP). In this study, we produced LMP and VLMP by alkaline de-esterification, and investigated the structural and textural properties. Apple peel pectin was kept at pH 12 using 5.0 M NaOH solution for 3 and 24 h to produce LMP and VLMP, respectively. The molecular weight was decreased due to the removal of an esterified group in the pectin backbones by the alkali treatment, and the VLMP showed a higher calcium ion sensitivity which leads to the production of the gel with increased hardness. The result clearly showed that VLMP has the potential to improve the texture and stability in food products depending on their degree of esterification, and this result can be applied as a functional ingredient in food industrial area application to enhance the current commercial pectins.