• Title/Summary/Keyword: Low alkali

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Effect of Cement Alkali Content on ASR Expansibility by the Test Method of ASTM C 1260 (ASTM C 1260 실험방법에 의한 시멘트 알칼리 함량이 ASR 팽창성에 미치는 영향)

  • Jeon, Sung Il;Son, Hyeon Jang;Kwon, Soo Ahn;Yun, Kyung Ku
    • International Journal of Highway Engineering
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    • v.14 no.6
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    • pp.37-43
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    • 2012
  • PURPOSES : This study is to evaluate the feasibility of setting the standard of cement alkali content by using ASTM C 1260(accelerated mortar bar test) METHODS : This study analyzes the ASR(alkali silica reaction) expansion of cement mortar bar based on the changes in the aggregate type(fine, coarse), cement type(ordinary, low alkali), and replacement contents of fly ash. ASR tests were conducted according to ASTM C 1260. RESULTS : In this test results, There is no big difference in the ASR expansion between ordinary cement and low alkali cement. From this test results, it was found that the variation of cement alkali content did not have a effect on ASR expansion because mortar bar was placed in a container with sufficient alkali aqueous solution at high temperature during the test process of ASTM C 1260. CONCLUSIONS : It is evidently clear that the alkali content of cement have a effect on ASR. But ASTM C 1260 is difficult to assess this effect.

Changes in Fiber Characteristics by Low Concentration Sodium Hydroxide Swelling and Beating (저농도 NaOH 팽윤과 고해에 따른 섬유특성 변화)

  • Kim, Ah-Ram;Choi, Kyoung-Hwa;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.65-72
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    • 2014
  • In this study, effects of alkali swelling at low concentration below 2 percent on properties of hardwood bleached kraft pulp (HwBKP) were elucidated. Swelling treatment of HwBKP was performed at various NaOH concentrations with/without beating. Then, the swelling characteristics of pulp fiber was evaluated by measuring the solvent retention values such as water retention value (WRV) and isopropyl alcohol retention value (LRV). It was found that fiber characteristics were influenced by NaOH swelling even at low alkali concentration and beating treatment as well. The values of WRV and LRV were decreased when the alkali concentration was increased. It is the result from the decreased acidic groups of pulp which were formed during beating. The acidic groups could be neutralized and then removed by alkali. The difference between WRV and LRV was decreased with increasing alkali concentration while the difference was increased when the alkali swollen pulp was beaten. In addition, the crystalline structure of HwBKP was almost not changed while the crystallinity was influenced by swelling treatment at a low alkali concentration.

Changes in the Handsheet Properties by Low Concentration Sodium Hydroxide Swelling and Beating (저농도 NaOH 팽윤과 고해에 따른 수초지 특성 변화)

  • Choi, Kyoung-Hwa;Kim, Ah-Ram;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.69-75
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    • 2014
  • Effects of alkali swelling of HwBKP (hardwood bleached kraft pulp) at a low concentration below 2 percent (based on the oven-dried weight of pulp) on handsheet properties were investigated. Swelling treatment of HwBKP was performed at various low NaOH concentrations with/without beating. Then, the changes in handsheet properties were evaluated in terms of bulk, optical and strength properties. It was found that bulk was slightly increased when the alkali concentration was increased. When the pulp was only swollen without beating, paper optical and strength properties was slightly decreased or not changed with alkali concentration. When the pulp was alkali-swollen after beating, paper strength and opacity showed almost no changes while brightness was increased. When the pulp was beaten after NaOH swelling, alkali concentration showed almost no effect on brightness and opacity of paper. Paper strength was slightly decreased with alkali concentration, suggesting that alkali pretreatment before refining could adversely affect refining efficiency.

Effect of Washing Treatment of Aged Paper Materials for Better Conservation (열화된 종이자료의 보존성 개선을 위한 세척처리 특성)

  • Lee, Kwi-Bok;Seo, Yung-Bum;Park, So-Yeon;Jeon, Yang;Shin, Jong-Soon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.53-60
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    • 2006
  • Paper materials for long term conservation suffer slowly mechanical and chemical deterioration, the extent of which may depend upon their conservation environment. Those deterioration includes discoloring, low moisture content, acidification, and brittleness. To slow deterioration, washing treatment, deacidification, and polymer reinforcement on paper materials are usually used. One easy and simple method of fixing low moisture content and acidification was an washing method, and we used both distilled and alkali water in washing method in this study. Alkali water is electrolyzed cathode water of high pH, and has no alkali metal ions in it. Experiment showed that washing treatment with both distilled and alkali water gave improvement in raising moisture content, pH, and mechanical strength of paper materials even after severe accelerated aging test. Advantageous effect of alkali water over distilled water on preventing deterioation was also shown clearly.

Premature Stiffening of Cement Paste Associated with AFm Formation

  • Chung, Chul-Woo;Lee, Jae-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.1
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    • pp.83-90
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    • 2011
  • The purpose of this research is to investigate the effect of AFm formation on the stiffening process of cement paste. High and low alkali sulfate clinkers were used for the experiments. The flow and stiffening behavior of cement paste was investigated using modified ASTM C403 penetration resistance test and oscillatory shear rheology. X-ray powder diffraction (XRD) was used for phase identification associated with stiffening of the paste. It was found from the results that low alkali clinker mixture produced very strong premature stiffening whereas high alkali clinker mixture did not cause premature stiffening. This is because of the large amount of alkali sulfate present in the clinker. Addition of calcium and sodium chloride to the high alkali clinker mixture caused faster stiffening and set.

Inheritance and Variability of Alkali Digestion Value in Rice Kernels (쌀 Alkali 붕괴성의 유전 및 변이성에 관한 연구)

  • ;Hyun-Ok Choi
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.25 no.2
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    • pp.15-22
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    • 1980
  • Alkali digestion value of rice kernels was increased with delayed planting date and decreased with temperature during ripening. Varietal difference in average digestion value between low and high groups of rice varieties was the greatest under the conditions of 1.4 percent solution of potassium hydroxide, early planting and day/night temperature of 30/22$^{\circ}C$ Segregation ratio of alkali digestion value in $F_2$ generation was varied with crosses showing 3:1 for nine crosses, 1:3 for one cross, 9:7 and 13:3 for two crosses respectively and non-segregation for one cross of 15 crosses between low and high varieties in the digestion value.

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Influence of Alkali-free Accelerating Admixtures on Aluminum Sulfate System (Aluminum Sulfate계 Alkali-free 급결제의 영향)

  • 김특준;김인섭;추용식;이종규
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.731-736
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    • 2003
  • Alkali silicate system has wide application to accelerating admixture for shotcrete, but it has several problems that decrease long-term strength and delay setting time. So alkali-free system was gradually focused on accelerating admixtures for shotcrete due to its environmental property. The aim of this study is to investigate effect of alkali-free accelerating admixtures on aluminum sulfate system containing diethanolamine or acrylic acid etc. The alkali-free accelerating admixture has better properties than silicate system accelerating admixtures on compressive strength and low pH as shotcrete. Especially, the compressive strength of alkali-free accelerating admixture containing diethanolamine was increased about 10% compared with the value of ordinary portland cement.

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Development of Near Isogenic Lines and Genetic Analysis for Alkali Digestibility of Rice Grain

  • Kim, Kwang-Ho;Kim, Doo-Hwan;Lee, Jeong-Heui
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.1
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    • pp.12-16
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    • 2001
  • In order to develop near isogenic lines (NILs) the heterozygous rice plants for alkali digestibility value(ADV) were selected and tested in every generation from $F_5$to $F_9$ of a cross, Seratus malam/Suwon 345. Finally several sets of NILs, which were six low ADV lines and four medium-high ADV lines, were selected among $F_{10}$ lines. No differences of the plant growth characteristics, amylose content and protein content of rice grain were found between low and medium-high ADV lines. Rice flour of low ADV lines showed longer gel length in gel consistency test than medium-high ADV lines, and also showed different gelatinization characteristics measured by rapid visco analyzer compared with medium-high ADV lines. The result of genetic analysis indicated that ADV-NILs developed were differed in a pair of major gene controlling ADV, and low ADV was dominant over medium-high ADV.

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Influence of Potassium on the Cement Clinker Formation : III. THe State and Formation Mechanism of Unstable Alkali (시멘트 클린커 생성과정에 미치는 Potassium의 영향 III. 불안정 알칼리의 상태 및 생성기구)

  • 서일영;최상홀
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.60-66
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    • 1985
  • The formation mechanism of unstable alkali and its existing states in the clinker were studied. The relation of unstable alkali content vs. other water-soluble components porosity and the distributionof potassium were investigated. The results are as follows :1) Two states of unstable alkali seem to exist in clinker ie compounds of $K_2O-Al_2O_3$ system and free $K_2O$ 2) The content of water-soluble $Al_2O_3$ tends to increase with increase of unstable alkali content, 3) Most of alkalies in clinker are concentrated in liquid phase at high temperature. Therefore it is possible to make various $K_2O-Al_2O_3$ system compounds according to the content of $K_2O$ in the liquid phase of clinker. In this experiment we found out a $K_2O-Al_2O_3$ compound of high $Al_2O_3$ content (34%) and high $K_2O$ content (33%) in clinker with 1.09% unstable alkali. 4) The porosity of clinker tends to increase with increase of unstable alkali content. 5) The amount of trapped alkali vapor may increase in closed pore in the clinker with high alkali and low $SO_3$ condecent. Therefore free $K_2O$ is the condensed alkali on the wall of closed pore in the clinker.

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Analysis of Varietal Variation in Alkali Digestion of Milled Rice at Several Levels of Alkali Concentration (쌀의 KOH 농도별 붕괴양상에 따른 품종변이 해석)

  • 최해춘;손영희
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.1
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    • pp.31-37
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    • 1993
  • To analyze and classify the varietal variation of alkali digestibility in detail, which is closely connected with the gelatinization temperature and physical characteristics of cooked rice, the patterns of alkali decomposition changed along the alkali concentration were investigated for thirty three Korean leading rice cultivars and new breeding lines(japonica : 25, Tongil-type:8) including five glutinous rice. Principal component analysis was used to condense the information and to classify rice materials according to decomposed reaction pattern at several levels of potassium hydroxide(KOH) concentration. Thirty three rice varieties were classified largely into four groups by the distribution on the plane of upper two principal component scores which contained above 92% of total informations. Group I was consisted of one variety, Dobongbyeo, which owned almost same strong resistance to alkali digestion at the range of 0.8% to 1.6% KOH solutions. Group II included three japonica and Tongil-type glutinous rice varieties, which revealed medium alkali digestion value(ADV) at 1.4% KOH solution and intermediate change in ADV from 0.8% to 1.6% KOH solutions. Most of Tongil-type and early-maturity japonica rice, which exhibited medium-high ADV at 1.4% of KOH concentration and large ADV difference between low and high alkali solutions, were contained in Group III. Group N included most of medium or medium-late-maturity japonica, which showed high ADV at 1.4% KOH and medium or intermediate-high ADV change between low and high alkali solutions. The 1st principal component indicated the average index of ADV through 0.8-1.6% KOH solutions and the 2nd principal component pointed out the factor related with ADV difference between low and high alkali solutions or regression coefficients of ADV change along with the KOH concentrations.

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