• 제목/요약/키워드: Low alkali

검색결과 445건 처리시간 0.019초

ASTM C 1260 실험방법에 의한 시멘트 알칼리 함량이 ASR 팽창성에 미치는 영향 (Effect of Cement Alkali Content on ASR Expansibility by the Test Method of ASTM C 1260)

  • 전성일;손현장;권수안;윤경구
    • 한국도로학회논문집
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    • 제14권6호
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    • pp.37-43
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    • 2012
  • PURPOSES : This study is to evaluate the feasibility of setting the standard of cement alkali content by using ASTM C 1260(accelerated mortar bar test) METHODS : This study analyzes the ASR(alkali silica reaction) expansion of cement mortar bar based on the changes in the aggregate type(fine, coarse), cement type(ordinary, low alkali), and replacement contents of fly ash. ASR tests were conducted according to ASTM C 1260. RESULTS : In this test results, There is no big difference in the ASR expansion between ordinary cement and low alkali cement. From this test results, it was found that the variation of cement alkali content did not have a effect on ASR expansion because mortar bar was placed in a container with sufficient alkali aqueous solution at high temperature during the test process of ASTM C 1260. CONCLUSIONS : It is evidently clear that the alkali content of cement have a effect on ASR. But ASTM C 1260 is difficult to assess this effect.

저농도 NaOH 팽윤과 고해에 따른 섬유특성 변화 (Changes in Fiber Characteristics by Low Concentration Sodium Hydroxide Swelling and Beating)

  • 김아람;최경화;조병욱
    • 펄프종이기술
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    • 제46권3호
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    • pp.65-72
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    • 2014
  • In this study, effects of alkali swelling at low concentration below 2 percent on properties of hardwood bleached kraft pulp (HwBKP) were elucidated. Swelling treatment of HwBKP was performed at various NaOH concentrations with/without beating. Then, the swelling characteristics of pulp fiber was evaluated by measuring the solvent retention values such as water retention value (WRV) and isopropyl alcohol retention value (LRV). It was found that fiber characteristics were influenced by NaOH swelling even at low alkali concentration and beating treatment as well. The values of WRV and LRV were decreased when the alkali concentration was increased. It is the result from the decreased acidic groups of pulp which were formed during beating. The acidic groups could be neutralized and then removed by alkali. The difference between WRV and LRV was decreased with increasing alkali concentration while the difference was increased when the alkali swollen pulp was beaten. In addition, the crystalline structure of HwBKP was almost not changed while the crystallinity was influenced by swelling treatment at a low alkali concentration.

저농도 NaOH 팽윤과 고해에 따른 수초지 특성 변화 (Changes in the Handsheet Properties by Low Concentration Sodium Hydroxide Swelling and Beating)

  • 최경화;김아람;조병욱
    • 펄프종이기술
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    • 제46권4호
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    • pp.69-75
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    • 2014
  • Effects of alkali swelling of HwBKP (hardwood bleached kraft pulp) at a low concentration below 2 percent (based on the oven-dried weight of pulp) on handsheet properties were investigated. Swelling treatment of HwBKP was performed at various low NaOH concentrations with/without beating. Then, the changes in handsheet properties were evaluated in terms of bulk, optical and strength properties. It was found that bulk was slightly increased when the alkali concentration was increased. When the pulp was only swollen without beating, paper optical and strength properties was slightly decreased or not changed with alkali concentration. When the pulp was alkali-swollen after beating, paper strength and opacity showed almost no changes while brightness was increased. When the pulp was beaten after NaOH swelling, alkali concentration showed almost no effect on brightness and opacity of paper. Paper strength was slightly decreased with alkali concentration, suggesting that alkali pretreatment before refining could adversely affect refining efficiency.

열화된 종이자료의 보존성 개선을 위한 세척처리 특성 (Effect of Washing Treatment of Aged Paper Materials for Better Conservation)

  • 이귀복;서영범;박소연;전양;신종순
    • 펄프종이기술
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    • 제38권4호
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    • pp.53-60
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    • 2006
  • Paper materials for long term conservation suffer slowly mechanical and chemical deterioration, the extent of which may depend upon their conservation environment. Those deterioration includes discoloring, low moisture content, acidification, and brittleness. To slow deterioration, washing treatment, deacidification, and polymer reinforcement on paper materials are usually used. One easy and simple method of fixing low moisture content and acidification was an washing method, and we used both distilled and alkali water in washing method in this study. Alkali water is electrolyzed cathode water of high pH, and has no alkali metal ions in it. Experiment showed that washing treatment with both distilled and alkali water gave improvement in raising moisture content, pH, and mechanical strength of paper materials even after severe accelerated aging test. Advantageous effect of alkali water over distilled water on preventing deterioation was also shown clearly.

Premature Stiffening of Cement Paste Associated with AFm Formation

  • Chung, Chul-Woo;Lee, Jae-Yong
    • 한국건축시공학회지
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    • 제11권1호
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    • pp.83-90
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    • 2011
  • The purpose of this research is to investigate the effect of AFm formation on the stiffening process of cement paste. High and low alkali sulfate clinkers were used for the experiments. The flow and stiffening behavior of cement paste was investigated using modified ASTM C403 penetration resistance test and oscillatory shear rheology. X-ray powder diffraction (XRD) was used for phase identification associated with stiffening of the paste. It was found from the results that low alkali clinker mixture produced very strong premature stiffening whereas high alkali clinker mixture did not cause premature stiffening. This is because of the large amount of alkali sulfate present in the clinker. Addition of calcium and sodium chloride to the high alkali clinker mixture caused faster stiffening and set.

쌀 Alkali 붕괴성의 유전 및 변이성에 관한 연구 (Inheritance and Variability of Alkali Digestion Value in Rice Kernels)

  • 최상진;최현옥
    • 한국작물학회지
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    • 제25권2호
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    • pp.15-22
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    • 1980
  • 미립 Alkali 붕괴도의 변이성과 유전현상을 구명하기 위하여 Japonita와 Indica 품종에서 Alkali 붕괴도가 높고 낮온 8개 품종을 가지고 KOH 농도에 따른 변이와 재배시기 및 등숙온도에 따른 변이정도를 조사하고 이 결과에 따라 품종간 반응의 차이가 가장 큰 조건하에서 $F_2$를 재배하였을 때 28개 조합의 Alkali 붕괴도에 따른 개체별 분포상태를 조사하였다. 1. 미립 Alkali 붕괴도는 품종에 따라, KOH 농도에 따라 변이가 컸는데 그중 3$0^{\circ}C$ 에서 23시간 처리한 경우 1.4%에서 품종간 차이가 가장 컸다. 2. Alkali 붕괴도는 이앙기가 늦어짐에 따라, 등숙숙온도가 낮아짐에 따라 증가하였고 그 증가정도는 양처리에서 모두 낮은 품종군에서 더 컸다. 3. 낮은 품종군과 높은 품종군간의 붕괴도 차이가 가장 큰 조건은 조기재배와 주야간 30/22$^{\circ}C$ 의 등숙온도에서였다. 4. Alkali 붕괴도가 같은 군끼리의 교잡에서는 문배친에 가까운 분포를 나타내었고, 15개 조합의 낮은 품종과 높은 품종간의 교잡에서는 낮은 쪽이 우성인 3 : 1의 분리가 9조합이었고 9 : 7과 13:3이 각각 2조합, 1:3이 1조합 그리고 분리비에 맞지 않는 것이 1조합 이었다.

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Aluminum Sulfate계 Alkali-free 급결제의 영향 (Influence of Alkali-free Accelerating Admixtures on Aluminum Sulfate System)

  • 김특준;김인섭;추용식;이종규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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    • pp.731-736
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    • 2003
  • Alkali silicate system has wide application to accelerating admixture for shotcrete, but it has several problems that decrease long-term strength and delay setting time. So alkali-free system was gradually focused on accelerating admixtures for shotcrete due to its environmental property. The aim of this study is to investigate effect of alkali-free accelerating admixtures on aluminum sulfate system containing diethanolamine or acrylic acid etc. The alkali-free accelerating admixture has better properties than silicate system accelerating admixtures on compressive strength and low pH as shotcrete. Especially, the compressive strength of alkali-free accelerating admixture containing diethanolamine was increased about 10% compared with the value of ordinary portland cement.

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Development of Near Isogenic Lines and Genetic Analysis for Alkali Digestibility of Rice Grain

  • Kim, Kwang-Ho;Kim, Doo-Hwan;Lee, Jeong-Heui
    • 한국작물학회지
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    • 제46권1호
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    • pp.12-16
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    • 2001
  • In order to develop near isogenic lines (NILs) the heterozygous rice plants for alkali digestibility value(ADV) were selected and tested in every generation from $F_5$to $F_9$ of a cross, Seratus malam/Suwon 345. Finally several sets of NILs, which were six low ADV lines and four medium-high ADV lines, were selected among $F_{10}$ lines. No differences of the plant growth characteristics, amylose content and protein content of rice grain were found between low and medium-high ADV lines. Rice flour of low ADV lines showed longer gel length in gel consistency test than medium-high ADV lines, and also showed different gelatinization characteristics measured by rapid visco analyzer compared with medium-high ADV lines. The result of genetic analysis indicated that ADV-NILs developed were differed in a pair of major gene controlling ADV, and low ADV was dominant over medium-high ADV.

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시멘트 클린커 생성과정에 미치는 Potassium의 영향 III. 불안정 알칼리의 상태 및 생성기구 (Influence of Potassium on the Cement Clinker Formation : III. THe State and Formation Mechanism of Unstable Alkali)

  • 서일영;최상홀
    • 한국세라믹학회지
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    • 제22권3호
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    • pp.60-66
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    • 1985
  • The formation mechanism of unstable alkali and its existing states in the clinker were studied. The relation of unstable alkali content vs. other water-soluble components porosity and the distributionof potassium were investigated. The results are as follows :1) Two states of unstable alkali seem to exist in clinker ie compounds of $K_2O-Al_2O_3$ system and free $K_2O$ 2) The content of water-soluble $Al_2O_3$ tends to increase with increase of unstable alkali content, 3) Most of alkalies in clinker are concentrated in liquid phase at high temperature. Therefore it is possible to make various $K_2O-Al_2O_3$ system compounds according to the content of $K_2O$ in the liquid phase of clinker. In this experiment we found out a $K_2O-Al_2O_3$ compound of high $Al_2O_3$ content (34%) and high $K_2O$ content (33%) in clinker with 1.09% unstable alkali. 4) The porosity of clinker tends to increase with increase of unstable alkali content. 5) The amount of trapped alkali vapor may increase in closed pore in the clinker with high alkali and low $SO_3$ condecent. Therefore free $K_2O$ is the condensed alkali on the wall of closed pore in the clinker.

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쌀의 KOH 농도별 붕괴양상에 따른 품종변이 해석 (Analysis of Varietal Variation in Alkali Digestion of Milled Rice at Several Levels of Alkali Concentration)

  • 최해춘;손영희
    • 한국작물학회지
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    • 제38권1호
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    • pp.31-37
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    • 1993
  • 우리나라 주요 벼 재배품종 및 신육성계통(자포니카: 25품종, 통일형:8품종)에 대한 쌀 알칼리 붕괴성의 품종적 특이성을 분시검토하여 보고자 KOH 농도를 0.8-1.8까지 0.2% 간격으로 처리하여 농도별 쌀의 알칼리 붕괴반응을 조사하고 주성분분석법을 적용하여 품종적 유형을 분류하였다. 주성분분석에서 상위 2개 주성분치의 변이가 전변이량의 92%을 차지하였고 제1 및 제2 주요분치 좌표상의 품종분포에 따라 크게 4개 유형으로 군집화 시킬 수 있었다. 제 I 군에서는 전 KOH 농도에 걸쳐 거의 비슷하게 알칼리 붕괴성(ADV)가 낮은 도봉벼만 유일하게 분포하였고, 제 II군에는 1.4% KOH 농도에서 중간정도의 ADV 이면서 고-저 알칼리 농도 ADV간차가 중도인 백운찰벼, 신선찰벼 및 수원 34002 등 찰벼가 포함되어 있었다. 제 III군에는 1.4% KOH 농도에서 중-중고의 ADV 이면서 저-고 KOH 농도간 ADV 변화가 심했던 대부분의 통일형 품종과 자포니카 조생계가 분포되어 있었고 육도농림찰 001와 한강 찰벼등은 이 유형에 포함되어 있었다. 제 IV군에는 1.4% KOH 농도에서 ADV가 중고이상으로 높으면서 고-저 알칼리 농도 ADV간차가 중-중고인 중생 및 중만생 자포니카 품종들이 주로 분포 하였으며 조생인 금조벼가 이 유형에 속하였다. 여기서 제 1 주성분은 전 알칼리 농도에서 평균적으로 표현되는 붕괴성 정도였고 제 2 주성분은 저-고 KOH 농도의 ADV간 차 또는 KOH 농도에 따른 ADV 변화의 회귀계수와 밀접하게 관련된 요소였다. 1.2%-1.4% KOH 농도에서의 ADV는 저-고 KOH 농도간 ADV차와 2차 곡선 회귀계수를 나타내었다.

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