• Title/Summary/Keyword: Loss of element

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The Properties of Aluminium Alloy Powder for Aluminothermy Process with $Mn_3O_4$ Waste Dust ($Mn_3O_4$ 분진의 Al 테르밋 반응용 Al 합금분말의 특성)

  • Kim, Youn-Che;Song, Youn-Jun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.71-77
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    • 2013
  • Aluminium powder as reductant in aluminothermy process needs a fine particle size under 200 mesh, but it is not easy economically to make that because of its high ductility and powder production cost. In order to reduce the production cost of fine aluminum powder as reductant of $Mn_3O_4$ waste dust, therefore, the properties of aluminium alloy powder were investigated. Aluminium alloy ingot containing large amount of manganese can be crushed easily because of its intermetallic compounds having brittle properties. The manganese is also main element in ferro-manganese. We can obtain economically Al-15%Mn alloy powder by mechanical comminution process. And the result of thermite reaction using Al-15% Mn alloy powder instead of pure Al powder showed the fact that can be obtained the ferro-manganese which have a high purity in case of using pure aluminium powder as reductant. The recovery of manganese from $Mn_3O_4$ waste dust with Al-15%Mn alloy powder was higher level of about 70% than about 65% in case of using aluminium powder, that is due to lower spatter loss.

SiOC Coating on Stainless Steel Using Polyphenylcarbosilane, and Its Anti-corrosion Properties (폴리페닐카보실란을 이용한 SiOC가 코팅된 스테인리스스틸 제조 및 이의 내부식성 특징)

  • Kim, Jong-Il;Lee, Yoon-Joo;Kim, Soo-Ryong;Kim, Young-Hee;Kim, Jung-Il;Woo, Chang-Hyn;Choi, Doo-Jin
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.8-14
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    • 2011
  • To improve the chemical stability of metal, the ceramic coatings on metallic materials have attracted interest from many researchers due to the chemical inertness of ceramic materials. To endure strong acids, SiOC coating on metal substrate was carried out by dip coating method using 20wt% polyphenylcarbosilane solution; SiC powder was added to the solution at 10wt% and 15wt% to improve the mechanical properties and to prevent cracks of the film. Thermal oxidation as a curing step was carried out at $200^{\circ}C$ for crosslinking of the polyphenylcarbosilane, and the coating samples were pyrolysized at $800^{\circ}C$ under argon to convert the polyphenylcarbosilane to SiOC film. The thicknesses of the SiOC coating films were $2.36{\mu}m$ and $3.16{\mu}m$. The quantities of each element were measured as $SiO_{1.07}C_{6.33}$ by EPMA, and it can be confirmed that the SiOC film from polyphenylcarbosilane was formed in a manner that was carbon rich. The hardness of the SiOC film was found to be 3.2Gpa through nanoindentor measurement. No defect including cracks appeared in the SiOC film. The weight loss of the SiOC coated stainless steel was within 2% after soaking in 10% HCl solution at $80^{\circ}C$ for one week. From these results, SiOC coating shows good potential for application to protect against severe chemical corrosion of stainless steel.

Mineralogy and Geochemistry of Green-colored Cr-bearing Sericite from Hydrothermal Alteration Zone of the Narim Gold Deposit, Korea (나림 금광상의 열수변질대에서 산출되는 녹색크롬-견운모의 광물학적 및 지구화학적 특징)

  • Lee, Hyun Koo;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.30 no.4
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    • pp.279-289
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    • 1997
  • Dark to pale green-colored, Cr-bearing sericites from hydrothermal alteration zone of the Narim gold deposit were investigated mineralogically and geochemically. The alteration zone is composed mineralogically of quartz, carbonate minerals and green sericite with minor amounts of chlorite, barite and sulfide minerals (pyrite, sphalerite, galena). The zone is enriched in As (967 to 1520 ppm), Cu (31 to 289 ppm), Ni (1027 to 1205 ppm), Pb (0.20 to 1.24 wt.%) and Zn (1.03 to 1.07 wt. %) compared with fresh rocks such as granitic gneiss, porphyritic biotite granite and basic dyke. The Cr, probably the chromophore element, is highly enriched in the alteration zone (1140 to 1500 ppm), host granitic gneiss (1200 ppm) and porphyritic biotite granite (1200 ppm). Occurrence and grain size of sericite are diverse, but most of the Cr-bearing sericites (150 to $200{\mu}m$ long and 20 to $30{\mu}m$ wide) occur along the boundaries between ore veins and host rocks (especially basic dyke and granitic gneiss). X-ray diffraction data of the sericite show its monoclinic form with unit-cell parameters of $a=5.202{\AA}$, $b=8.994{\AA}$, $c=20.103{\AA}$, ${\beta}=95.746^{\circ}$ and $V=935.83{\AA}^3$, which are similar with the normal 2M1-type muscovite. Representative chemical formula of the sericite is ($K_{1.54}Ca_{0.03}Na_{0.01}$)($Al_{3.42}Mg_{0.38}Cr_{0.14}Fe_{0.06}V_{0.02}$)($Si_{6.69}Al_{1.31}$)$O_{20}(OH)_4$. The Cr content increases with decrease of the octahedral Al content, and ranges from 0.36 to 2.58 wt.%. DTA and TG curves of the sericite show endothermic peaks at $342^{\circ}$ to $510^{\circ}$, $716^{\circ}$ to $853^{\circ}$ and $1021^{\circ}C$, which are due to the expulsion of hydroxyl group. The total weight loss by heating is measured to be about 8.8 wt. %, especially at $730^{\circ}C$. Infrared absorption experiments of the sericite show broad absorption band due to the O-H bond stretching vibration near the $3625cm^{-1}$, coupled with the 825 and $750cm^{-1}$ doublet. The vibration bands related with the H-O-Al and Si-O-Al bonds occur at $1030cm^{-1}$ and 500 to $700cm^{-1}$, respectively. Based on paragonite content of the sericite, the formation temperature of the Narim gold deposit is calculated to be $220{\pm}10^{\circ}C$.

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Study on the Justifiable Reasons for Medical Refusal (의사의 진료거부의 정당한 사유에 관한 고찰 -최근 일본의 논의를 중심으로-)

  • Lee, Eol
    • The Korean Society of Law and Medicine
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    • v.21 no.3
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    • pp.117-144
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    • 2020
  • In accordance with Article 15 of the Medical Law, medical personnel in Korea cannot refuse treatment of a patient unless there is a justifiable reason, and violation of this obligations is subject to criminal penalties. Japan also stipulates the same content in the law. However, this violation of obligations in Japan is not subject to criminal penalties, and is used as a judgment element of the liability for damages of doctors only in the case of damage to the patient. However, in both countries, it is difficult to interpret and apply the law because the regulation is a little ambiguous. In particular, the key is to find out what is the justifiable reason for the doctor to refuse treatment of the patient. Recently, Japan has completed the work of re-examining the discussion on medical refusal from a modern perspective in terms of improving the excessive working environment of doctors. On the other hand, in Korea, it is not clear in what cases it is possible to refuse treatment. because there is a lack of systematic discussion on medical refusal. Rather, unnecessary misunderstandings and controversies have resulted in the loss of trust between patients and doctors. In Korea, there is already a legal right for a doctor to reject it according to his religious beliefs or conscience in the implementation of the suspension of life-sustaining treatment decisions. And in the case of an abortion, debates are underway that doctors should be given the right to refuse it. This study introduces the current state of discussion in Japan, and examines the issues surrounding medical refusal in Korea. It is hoped that this study will facilitate further discussions on the medical refusal.

Finite Element Analysis of RF Coupler in Normal-Low Temperature (상온-저온 RF 커플러 유한요소해석)

  • Kim, Hansol;Lee, Hak Yong;Park, Chan;Lee, Jaeyeol;Lim, Dong Yeal;Yoo, Jeonghoon;Hyun, Myung Wook
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.10
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    • pp.1101-1107
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    • 2014
  • A heavy ion accelerator is a device that accelerates heavy ions in the radio frequency (RF) range. The electric field that flows into the RF cavity continuously accelerates heavy ions in accordance with the phase of the input electromagnetic wave. For the purpose, it is necessary to design a coupler shape that can stably transfer the RF wave into the cavity. The RF coupler in a heavy ion accelerator has a large temperature difference between the input port and output port, which radiates the RF waves. It is necessary to consider the heat deflection on the RF coupler that occurs as a result of the rapid temperature gradient from an ultra-low temperature about 0 K to a room temperature about 300 K. The purpose of this study was to improve the system performance through an analysis of the intensity of the output electric field and temperature distribution considering various shapes of the RF coupler, along with an analysis of the durability considering the heat deflection and heat loss.

Analytical Study of Net Section Fracture in Special Concentrically Braced Frames (중심가새골조의 순단면 파단에 관한 해석적 연구)

  • Yoo, Jung Han
    • Journal of Korean Society of Steel Construction
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    • v.21 no.1
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    • pp.63-70
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    • 2009
  • Failure modes result in fracture or tearing, which may cause deterioration of resistance and reduction of inelastic deformation capacity. The potential failure modes for Special Concentrically Braced Frames (SCBFs) include fracture or tearing of the brace, net section fracture of the brace or gusset plate, fracture of the gusset plate welds, shear fracture of the bolts, block shear, excessive bolt bearing deformation, and buckling of the gusset plate. HSS tubular braces are commonly used in SCBFs, and net section fracture of the tubular brace may also occur through the brace net section at the end of the slot cut into the tube to slip over the gusset plate. This failure mode is categorized as a tension failure mode, and may cause dramatic loss of resistance and brittle behavior. Net section reinforcement is required according to AISC design specifications (AISC 2001). In this paper, the need to reinforce the net section area was discussed. Initially, the results of the net section fracture tests done by the University of California in Berkeley were presented with the modeling of these tests using FE models. To investigate the possibility of net section fracture in an actual frame, the slot end hole model was adapted to the frame FE model, and alternate near-fault histories were applied with tension-dominated cycles, since previous analyses showed that loading history was the most critical factor in net section fracture. The need for this reinforcement (cover plate) and the tension-dominated near-fault history were investigated.

Evaluation of Fire Resistance of Unprotected Concrete-filled Rectangular Steel Tubular Columns under Axial Loading (재하가열시험에 의한 무내화피복 콘크리트충전 각형강관기둥의 내화성능평가)

  • Ahn, Jae Kwon;Lee, Cheol Ho
    • Journal of Korean Society of Steel Construction
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    • v.26 no.4
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    • pp.323-334
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    • 2014
  • In this paper, experimental program and associated numerical study were carried out to evaluate the fire resistance of unprotected concrete-filled rectangular steel tubular (CFT) columns subjected to the standard fire. The key testing parameters included the length effect, the load ratio, and the sectional dimensions of the CFT columns. Temperature distribution and axial deformation of the CFT column specimens were measured and analyzed. Rather early local buckling of steel tubes was observed in all the specimens. This caused subsequent load transfer from steel tube to concrete, and eventually triggered concrete crushing, or complete loss of the load bearing capacity of the column. This implies that the limit state of local buckling as well as overall flexural buckling should be incorporated in fire design procedure. As expected, the fire resistance time of specimen with higher load ratio consistently lessened. The prediction of fire resistance time of unprotected CFT columns based on the limiting steel temperature in current design codes or the formula proposed by previous studies is slightly conservative compared to the fire test results available. To establish the finite element analysis model that can be used to predict the thermal and structural behaviour of unprotected CFT columns in fire, the fully coupled thermal-stress analysis was also tried by using the commercial code ABAQUS. The numerical results showed a reasonable global correlation with the experimental results.

Biogeochemistry of Alkaline and Alkaline Earth Elements in the Surface Sediment of the Gamak Bay (가막만 표층퇴적물 중 알칼리 및 알칼리 토금속 원소의 생지화학적 특성)

  • Kim, Pyoung-Joong;Park, Soung-Yun;Kim, Sang-Su;Jang, Su-Jeong;Jeon, Sang-Baek;Ju, Jae-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.1
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    • pp.1-13
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    • 2012
  • We measured various geochemical parameters, including the grain size, loss on ignition(LOI), total organic carbon(TOC), total nitrogen(TN), total sulfur(TS) and metallic elements, in surface sediment collected from 19 stations in Gamak Bay in April 2010 in order to understand the sedimentary types, the origin of organic matters, and the distribution patterns of alkali(Li, Na, K, Rb) and alkaline earth(Be, Mg, Ca, Sr, Ba) elements. The surface sediments were mainly composed of mud. The concentrations of Chlorophyll-a, TOC, TN, TS and LOI in sediment were the highest at the cultivation areas of fish and shellfish in the northern and southern parts of the bay. The redox potential(or oxidation-reduction potential) showed the positive value in the middle part of the bay, indicating that the surface sediment is under oxidized condition. The organic materials in sediment at almost all of stations were characterized by the autochthonous origin. Based on the overall distributions of metallic elements, it appears that the concentrations of alkali and alkaline earth elements except Ba in sediment are mainly influenced by the dilution effect of quartz. The concentrations of Sr and Ba are also dependent on the secondary factors such as the effect of calcium carbonate and the redox potential.

An Exploratory Study of the Relationship between Smart Learning and Smart Work: The Use of Personal Laptops by Graduate Students in a Smart Campus Environment (스마트러닝과 스마트워크의 관련성에 대한 탐색적 연구: 스마트 캠퍼스 환경에서 대학원생의 개인 노트북 컴퓨터 사용을 중심으로)

  • Kim, Young-Woo
    • Journal of Digital Convergence
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    • v.10 no.5
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    • pp.27-35
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    • 2012
  • The importance of smart learning (SL) has been emphasized in schools. Additionally, the significance of smart work (SW) in improving business performance has gained much attention among industries. From theoretical, technological, and environmental perspectives, SL and SW are somewhat similar. Therefore, a case study was performed to find a way to link SL and SW, and a linking model was proposed for this purpose. Because laptops are considered a pivotal element in the technological aspect of SL, graduate students' use of personal laptops in classes (Bring Your Own Laptop, BYOL) was investigated. The results showed that the students reacted positively to the idea of using personal laptops in class and that they expected to learn IT skills more effectively this way. They listed being able to study even after class and the easy accessibility of relevant data as the strengths of BYOL. However, they cited the heaviness of the laptops and occasional loss of focus during classes as the weaknesses of BYOL. Thus, this study showed the possibility of that students who experience SL can perform better in an SW situation. Therefore, if a policy is enacted that allows students to efficiently use laptops, a greater number of educational achievements will be attained on smart campuses and, subsequently, a greater number of smart workers will be produced.

Asterisk(*) Array structure based power reduction power distribution board (애스터리스크(*) 배열구조 기반 전력저감 수배전반)

  • Kim, Mi-Suk;Park, Dong-Sam
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.138-144
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    • 2017
  • With the increase in power consumption due to the surge in the demand for power, it is necessary to improve the quality or design of the power (supply) for the purpose of reducing the energy consumption and so reduce the power loss. The switchboard is a mechanical device that receives electricity from the electricity generation facilities of KEPCO and divides it into the facilities required for each building. Switchboards generally consist of enclosures, switches, power conductors, and control components. This study deals with energized power conductors, which constitute the main element in the switchboard. Through the measurement of the effective ac resistance, it was confirmed that the vertical array structure of the conventional type plate conductor is inefficient. If the effective AC resistance increases significantly, the sectional area of the conductor becomes relatively large due to the skin effect. In this study, we studied the energy and material savings that could be obtained using the asterisk (*) array structure, which minimizes the effective ac resistance by reducing the skin effect. The core technology principle of this study is the energy saving switchgear based on conductor resistance reduction technology utilizing the asterisk array structure. The present invention involves a plate-shaped conductor arrangement structure capable of canceling out the magnetic field generated on each of the plate conductors (rst or abc) of the AC power supply in the power distribution panel by mutual action. The effect of this structure is to reduce the amount of inductive reactance due to the increase in the cross-sectional area and reduction of the effective AC resistance.