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Interfacial modulus mapping of layered dental ceramics using nanoindentation

  • Theocharopoulos, Antonios L;Bushby, Andrew J;P'ng, Ken MY;Wilson, Rory M;Tanner, K Elizabeth;Cattel, Michael J
    • The Journal of Advanced Prosthodontics
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    • v.8 no.6
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    • pp.479-488
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    • 2016
  • PURPOSE. The aim of this study was to test the modulus of elasticity (E) across the interfaces of yttria stabilized zirconia (YTZP) / veneer multilayers using nanoindentation. MATERIALS AND METHODS. YTZP core material (KaVo-Everest, Germany) specimens were either coated with a liner (IPS e.max ZirLiner, Ivoclar-Vivadent) (Type-1) or left as-sintered (Type-2) and subsequently veneered with a pressable glass-ceramic (IPS e.max ZirPress, Ivoclar-Vivadent). A $5{\mu}m$ (nominal tip diameter) spherical indenter was used with a UMIS CSIRO 2000 (ASI, Canberra, Australia) nanoindenter system to test E across the exposed and polished interfaces of both specimen types. The multiple point load - partial unload method was used for E determination. All materials used were characterized using Scanning Electron Microscopy (SEM) and X - ray powder diffraction (XRD). E mappings of the areas tested were produced from the nanoindentation data. RESULTS. A significantly (P<.05) lower E value between Type-1 and Type-2 specimens at a distance of $40{\mu}m$ in the veneer material was associated with the liner. XRD and SEM characterization of the zirconia sample showed a fine grained bulk tetragonal phase. IPS e-max ZirPress and IPS e-max ZirLiner materials were characterized as amorphous. CONCLUSION. The liner between the YTZP core and the heat pressed veneer may act as a weak link in this dental multilayer due to its significantly (P<.05) lower E. The present study has shown nanoindentation using spherical indentation and the multiple point load - partial unload method to be reliable predictors of E and useful evaluation tools for layered dental ceramic interfaces.

Filler-Elastomer Interactions. 1. Roles of Modified Carbon Black Surfaces to Enhance Mechanical Properties of Carbon Black/Rubber Vulcanizates (충전재-탄성체 상호작용. 1. 표면처리된 카본블랙이 카본블랙/고무 복합재료의 기계적 물성에 미치는 영향)

  • Kim, Jeong-Soon;Nah, Chang-Woon;Park, Soo-Jin
    • Elastomers and Composites
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    • v.35 no.2
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    • pp.98-105
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    • 2000
  • Using FT-IR and contact angle measurements it is observed that the chemical surface treatments on virgin carbon blacks lead to a change of the surface properties, including surface functionality and surface free energy It is found that the developments of surface functional groups on acidically and basically treated (ACB and BCB in this study, respectively) carbon blacks are largely correlated with the specific component of surface free energy of the carbon blacks. However, a significant advantage of compounding composites is gained by BCB or NCB (nonpolar chemical treatment) specimens, resulting in improving the hardness, elongation at break, and tensile strength. Particularly, it is seen that the tensile strength of the composites are greatly depended on the London dispersive component of surface free energy determined from the contact angle measurements. It is then concluded that the London dispersion component of carbon blacks plays an important role in an organic rubbers-based compounding composite system.

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Prognostication for recurrence patterns after curative resection for pancreatic ductal adenocarcinoma

  • Andrew Ang;Athena Michaelides;Claude Chelala;Dayem Ullah;Hemant M. Kocher
    • Annals of Hepato-Biliary-Pancreatic Surgery
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    • v.28 no.2
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    • pp.248-261
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    • 2024
  • Backgrounds/Aims: This study aimed to investigate patterns and factors affecting recurrence after curative resection for pancreatic ductal adenocarcinoma (PDAC). Methods: Consecutive patients who underwent curative resection for PDAC (2011-21) and consented to data and tissue collection (Barts Pancreas Tissue Bank) were followed up until May 2023. Clinico-pathological variables were analysed using Cox proportional hazards model. Results: Of 91 people (42 males [46%]; median age, 71 years [range, 43-86 years]) with a median follow-up of 51 months (95% confidence intervals [CIs], 40-61 months), the recurrence rate was 72.5% (n = 66; 12 loco-regional alone, 11 liver alone, 5 lung alone, 3 peritoneal alone, 29 simultaneous loco-regional and distant metastases, and 6 multi-focal distant metastases at first recurrence diagnosis). The median time to recurrence was 8.5 months (95% CI, 6.6-10.5 months). Median survival after recurrence was 5.8 months (95% CI, 4.2-7.3 months). Stratification by recurrence location revealed significant differences in time to recurrence between loco-regional only recurrence (median, 13.6 months; 95% CI, 11.7-15.5 months) and simultaneous loco-regional with distant recurrence (median, 7.5 months; 95% CI, 4.6-10.4 months; p = 0.02, pairwise log-rank test). Significant predictors for recurrence were systemic inflammation index (SII) ≥ 500 (hazard ratio [HR], 4.5; 95% CI, 1.4-14.3), lymph node ratio ≥ 0.33 (HR, 2.8; 95% CI, 1.4-5.8), and adjuvant chemotherapy (HR, 0.4; 95% CI, 0.2-0.7). Conclusions: Timing to loco-regional only recurrence was significantly longer than simultaneous loco-regional with distant recurrence. Significant predictors for recurrence were SII, lymph node ration, and adjuvant chemotherapy.

Smog and Health Effects -A Review of london Smog of December, 1952- (스모그와 건강피해 - 런던스모그참사의 재조명)

  • 조윤승
    • Journal of environmental and Sanitary engineering
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    • v.6 no.1
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    • pp.109-120
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    • 1991
  • This paper briefly reviews our knowledge concerning the potential health risk of smog. It includes a review of the meteorological phenomenon, the causes of death in different age groups from London smog which occurred during the week of December 5, 6, 7, 8, 1952. During the London disaster, which caused 4,000 excess human deaths, it was deternimed the meteorological factors of almost absence of wind, low temperature, high humidity and an inversion. Hence, at ground level of air pollutants were suddenly increased and attributed to the combined action of a particulate matter with sulfur dioxide. As a result, abnormally large numbers of persons died especially, those individuals already suffering from disease of the respiratory and cardiovascular systems.

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Dynamic characteristics of transmission line conductors and behaviour under turbulent downburst loading

  • Darwish, Mohamed M.;El Damatty, Ashraf A.;Hangan, Horia
    • Wind and Structures
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    • v.13 no.4
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    • pp.327-346
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    • 2010
  • During the past decade, many electrical transmission tower structures have failed during downburst events. This study is a part of a research program aimed to understand the behaviour of transmission lines under such localized wind events. The present study focuses on the assessment of the dynamic behaviour of the line conductors under downburst loading. A non-linear numerical model, accounting for large deformations and the effect of pretension loading, is developed and used to predict the natural frequencies and mode shapes of conductors at various loading stages. A turbulence signal is extracted from a set of full-scale data. It is added to the mean component of the downburst wind field previously evaluated from a CFD analysis. Dynamic analysis is performed using various downburst configurations. The study reveals that the response is affected by the background component, while the resonant component turns to be negligible due large aerodynamic damping of the conductors.

Comparative study of factors influencing tension lap splices in reinforced concrete beams

  • Karkarna, Yakubu M.;Bahadori-Jahromi, Ali;Jahromi, Hamid Zolghadr;Bonner, Emily;Goodchild, Charles
    • Advances in concrete construction
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    • v.10 no.4
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    • pp.279-287
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    • 2020
  • The practice of splicing reinforcing bars in reinforced concrete structures to manage insufficient bar length is a common approach, which is mainly due to transportation limitations on bar length. The splicing of reinforcing bars side by side offers a simple and economical solution to the problem of continuity. This paper examines the influence of different structural parameters such as concrete cover, lap splice length, shear links confinement and concrete strength on the lap splices based on an extensive experimental database of laps and anchorage. The current study shows that increasing the lap splices beyond 50Ø has no additional benefit for increasing its strength. The results also show that relative to the measured stress, specimens with larger concrete side covers shows higher splice stress compared to the samples with smaller concrete covers.

Development of a Five-Day Basic Microsurgery Simulation Training Course: A Cost Analysis

  • Singh, Masha;Ziolkowski, Natalia;Ramachandran, Savitha;Myers, Simon R.;Ghanem, Ali Mahmoud
    • Archives of Plastic Surgery
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    • v.41 no.3
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    • pp.213-217
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    • 2014
  • The widespread use of microsurgery in numerous surgical fields has increased the need for basic microsurgical training outside of the operating room. The traditional start of microsurgical training has been in undertaking a 5-day basic microsurgery course. In an era characterised by financial constraints in academic and healthcare institutions as well as increasing emphasis on patient safety, there has been a shift in microsurgery training to simulation environments. This paper reviews the stepwise framework of microsurgical skill acquisition providing a cost analysis of basic microsurgery courses in order to aid planning and dissemination of microsurgical training worldwide.

The Anisotropy of the London Penetration Depth and the Upper Critical Field in C-doped $MgB_2$ Single Crystals from Reversible Magnetization

  • Kang, Byeong-Won;Park, Min-Seok;Lee, Hyun-Sook;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.36-40
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    • 2010
  • We have studied the anisotropy of the London penetration depth of carbon doped $MgB_2$ single crystals, which was obtained from reversible magnetization measurements with the magnetic field both parallel and perpendicular to the c-axis. Similar to the pure $MgB_2$, the anisotropy of the upper critical field ${\gamma}_H$ decrease with temperature while the anisotropy of the London penetration depth ${\gamma}_{\lambda}$ slowly increases with temperature. However, the temperature dependence of ${\gamma}_H$ is drastically reduced and the value of ${\gamma}_{\lambda}$ becomes nearly ~1 as C is introduced. These results indicate that C substitution increases impurity scattering mainly in the $\sigma$ bands. The temperature dependence of the anisotropies agree well with the theoretical predictions with impurity scattering.

Comparative Analysis of the Role of Business Improvement Districts (BIDs) according to the Characteristics of Business Districts - Based on a case study on BIDs in London, UK -

  • Youngseo Park
    • Architectural research
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    • v.25 no.2
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    • pp.19-27
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    • 2023
  • London's BID, introduced in the early 2000s, has grown significantly to fill the gap between government services which have been decreased by the global recession and localism, and the demand for better services to strengthen competitiveness on a global level. Based on this background, this study comparatively analysed two BIDs in London with contrasting regional characteristics to find how BID works differently for the regeneration and sustainable development of regional business districts according to regional characteristics. As a result, the two BIDs ultimately had the goal of improving the local business environment and strengthening the competitiveness of local businesses and had a common point of working in close partnership with the public sector such as the local government. However, depending on the local situation and characteristics, it has been observed that there are differences in the strategies of work and the roles and relationships in the partnership with the public sector.