• 제목/요약/키워드: Local Equilibrium

검색결과 226건 처리시간 0.027초

천연가스의 수증기-이산화탄소 복합개질용 촉매 충진 반응기의 코킹 회피 운전을 위한 모사 (Simulation for Possible Coke-Free Operation of a Packed Catalyst Bed Reactor in the Steam-CO2 Reforming of Natural Gas)

  • 이득기;이상수;서동주;윤왕래
    • 한국수소및신에너지학회논문집
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    • 제26권5호
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    • pp.445-452
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    • 2015
  • A tubular packed bed reactor for the steam-$CO_2$ combined reforming of natural gas to produce the synthesis gas of a target $H_2/CO$ ratio 2.0 was simulated. The effects of the reactor dimension, the feed gas composition, and the gas feeding temperature upon the possibility of coke formation across the catalyst bed were investigated. For this purpose, 2-dimensional heterogeneous reactor model was used to determine the local gas concentrations and temperatures over the catalyst bed. The thermodynamic potential distribution of coke formation was determined by comparing the extent of reaction with the equilibrium constant given by the reaction, $CH_4+2CO{\Leftrightarrow}3C+2H_2O$. The simulation showed that catalysts packed in the central region nearer the entrance of the reactor were more prone to coking because of the regional characteristics of lower temperature, lower concentration of $H_2O$, and higher concentration of CO. With the higher feeding temperature, the feed gas composition of the increased $H_2O$ and correspondingly decreased $CO_2$, or the decrease in the reactor diameter, the volume fraction of the catalyst bed subsequent to coking could be diminished. Throughout the simulation, reactor dimension and reaction condition for coking-free operation were suggested.

밀양시 요업의 입지와 공간변화 (Location and Spatial Variations of Ceramic Industry in Miryang City, Kyongnam Province, Korea)

  • 임영대
    • 한국지역지리학회지
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    • 제8권1호
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    • pp.40-64
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    • 2002
  • 1900년대 초부터 근대공장제 요업의 중심지 중의 하나를 이루고 있는 경남 밀양시의 요업이 지닌 입지 특성을 구명하였다. 밀양시의 요업은 국가정책과 경기변동에 따라 양적 변화를 보이면서, 기업의 신설과 폐업에 의한 도시내부의 감소현상과 외연부의 증가현상으로, 도시내부에 집적한 요업이 외연부로 분산하는 외향적인 공간변화를 수반하였다. 유리한 원료와 교통조건을 지닌 밀양시에 일본인의 투자를 계기로 신규 산업으로 입지한 요업은 그 후 지역 내에 성장해 온 잠재 기업가와 이들 기업의 지역 내 입지로 지속되었다. 이들의 입지결정에 개인적 요인, 원료, 용지, 용수, 시장이 큰 영향을 미쳤다. 그러나 기존 집적지역에 원료 고갈, 혼잡, 토지 부족으로 인한 입지 불리성, 기업의 확장정책, 공업분산정책, 교통(도로)조건의 개선 등으로 인해 요업이 외연부로 분산하고 있다.

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A Study on the Optimal Position for the Secondary Neutron Source in Pressurized Water Reactors

  • Sun, Jungwon;Yahya, Mohd-Syukri;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제48권6호
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    • pp.1291-1302
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    • 2016
  • This paper presents a new and efficient scheme to determine the optimal neutron source position in a model near-equilibrium pressurized water reactor, which is based on the OPR1000 Hanul Unit 3 Cycle 7 configuration. The proposed scheme particularly assigns importance of source positions according to the local adjoint flux distribution. In this research, detailed pin-by-pin reactor adjoint fluxes are determined by using the Monte Carlo KENO-VI code from solutions of the reactor homogeneous critical adjoint transport equations. The adjoint fluxes at each allowable source position are subsequently ranked to yield four candidate positions with the four highest adjoint fluxes. The study next simulates ex-core detector responses using the Monte Carlo MAVRIC code by assuming a neutron source is installed in one of the four candidate positions. The calculation is repeated for all positions. These detector responses are later converted into an inverse count rate ratio curve for each candidate source position. The study confirms that the optimal source position is the one with very high adjoint fluxes and detector responses, which is interestingly the original source position in the OPR1000 core, as it yields an inverse count rate ratio curve closest to the traditional 1/M line. The current work also clearly demonstrates that the proposed adjoint flux-based approach can be used to efficiently determine the optimal geometry for a neutron source and a detector in a modern pressurized water reactor core.

Measurement of electron temperature and density using Stark broadening of the coaxial focused plasma for extreme ultraviolet (EUV) lithography

  • Lee, Sung-Hee;Hong, Young-June;Choi, Eun-Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.475-475
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    • 2010
  • We have generated Ar plasma in dense plasma focus device with coaxial electrodes for extreme ultraviolet (EUV) lithography and investigated an emitted visible light for electro-optical plasma diagnostics. We have applied an input voltage 4.5 kV to the capacitor bank of 1.53 uF and the diode chamber has been filled with Ar gas of pressure 8 mTorr. The inner surface of the cylindrical cathode has been attatched by an acetal insulator. Also, the anode made of tin metal. If we assumed that the focused plasma regions satisfy the local thermodynamic equilibrium (LTE) conditions, the electron temperature and density of the coaxial plasma focus could be obtained by Stark broadening of optical emission spectroscopy (OES). The Lorentzian profile for emission lines of Ar I of 426.629 nm and Ar II of 487.99 nm were measured with a visible monochromator. And the electron density has been estimated by FWHM (Full Width Half Maximum) of its profile. To find the exact value of FWHM, we observed the instrument line broadening of the monochromator with a Hg-Ar reference lamp. The electron temperature has been calculated using the two relative electron density ratios of the Stark profiles. In case of electron density, it has been observed by the Stark broadening method. This experiment result shows the temporal behavior of the electron temperature and density characteristics for the focused plasma. The EUV emission signal whose wavelength is about 6 ~ 16 nm has been detected by using a photo-detector (AXUV-100 Zr/C, IRD). The result compared the electron temperature and density with the temporal EUV signal. The electron density and temperature were observed to be $10^{16}\;cm^{-3}$ and 20 ~ 30 eV, respectively.

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Optical Diagnostics for Pulse-discharged Plasma by Marx Generator and Its Application for Modifications of Hemoglobin and Myoglobin Proteins

  • Park, Ji Hoon;Attri, Pankaj;Hong, Young June;Park, Bong Sang;Jeon, Su Nam;Choi, Eun Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.176.2-176.2
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    • 2013
  • Property of optical diagnostics for pulse-discharged plasma in liquid and its biological applications to proteins are investigated by making use of high voltage Marx generator. The Marx generator has been consisted of 5 stages, where each charging capacitor is 0.5 ${\mu}F$, to generate a high voltage pulse with rising time of $1{\mu}s$. We have applied an input voltage of 6 kV to the each capacitor of 0.5 ${\mu}F$. High voltage pulsed plasma has been generated inside a polycarbonate tube by a single-shot operation, where the breakdown voltage is measured to be 7 kV, current of 1.2 kA, and pulse width of ~ 1 ${\mu}s$ between the two electrodes of anode-cathode whose material is made of tungsten pin, which are immersed into the liquids. We have investigated the emitted hydrogen lines for optical diagnostics of high voltage pulsed plasma. The emission line of 656.3 nm from $H-{\alpha}$ and 486.1 nm from $H-{\beta}$ have been measured by a monochromator. If we assumed that the focused plasma regions satisfy the local thermodynamic equilibrium conditions, the electron temperature and density of the high voltage pulsed plasma in liquid could be obtained by the Stark broadening of optical emission spectroscopy. For the investigation of the influence of pulsed plasma on biological proteins, we have exposed it onto the proteins such as hemoglobin and myoglobin. The structural changes in these proteins and their analysis have also been obtained by circular dichroism (CD) and ultraviolet (UV) visible spectroscopy.

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Mathematical model for reactive transport of heavy metals in soil column: Based on PHREEQC and HP1 simulators

  • Tameh, Fatemeh Izadi;Asadollahfardi, Gholamreza;Darban, Ahmad Khodadadi
    • Advances in environmental research
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    • 제6권1호
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    • pp.67-81
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    • 2017
  • Mining activities play a significant role in environmental pollution by producing large amounts of tailings which comprise heavy metals. The impressive increase in mining activities in recent decades, due to their high influence on the industry of developing countries, duplicates the need for a substantial effort to develop and apply efficient measures of pollution control, mitigation, and abatement. In this study, our objective was to investigate the effect of simulation of the leachate, pH and inflow intensity of transport of $Pb^{2+}$, $Zn^{2+}$, and $Cd^{2+}$ through Lakan lead and zinc plant tailings, in Iran, and to evaluate the modeling efficiency by comparing the modeling results and the results obtained from previous column studies. We used the HP1 model and the PHREEQC database to simulate metals transport through a saturated soil column during a 15 day time period. The simulations assumed local equilibrium. As expected, a lower pH and inflow intensity increased metal transport. The retardation of heavy metals followed the order $Zn^{2+}$ > $Pb^{2+}$ > $Cd^{2+}$ and the removal concentrations of Cd, Pb, and Zn at the inflow intensity critical scenario, and Cd and Pb at inflow acidity critical scenario exceeded the allowable EPA and Iranian's 1053 standard thresholds. However, although the simulation results generally agreed well with the results of the column study, improvements are expected by using multi-dimensional models and a kinetic modeling approach for the reactions involved. The results of such investigations will be highly useful for designing preventative strategies to control reactive transport of hazardous metals and minimize their environmental effects.

KMRR 핵연료 알루미늄 피복재의 부식 거동 평가 (Evaluation of the Corrosion Behavior of the Aluminum Cladding in the KMRR Fuel)

  • Lee, Chan-Bock;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • 제26권4호
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    • pp.526-535
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    • 1994
  • KMRR(다목적 연구용원자로) 핵연료의 알루미늄 피복재의 부식거동을 평가하기 위해, 부식 예측치와 노내 부식 실측치의 비교를 통해 유도된 열속인자를 도입한 수정된 Griess 경험식을 유도하였다. KMRR 핵연료의 건전성이 유지되는 부식의 설계기준으로써는 산화층의 박리 방지가 보수적으로 설정되었으며, 산화층의 박리는 산화층에서의 온도차이가 114$^{\circ}C$ 이상에서 일어난다고 보수적으로 가정하였다. KMRR 핵연료의 출력이력을 첫 주기부터 평형주기까지 분석하여, 한계출력이력을 결정하였다. 한계출력이력을 가진 KMRR 핵연료의 부식량 예측계산 결과, 최대 산화층의 두께는 50$\mu\textrm{m}$ 이하였으며, 산화층 박리의 설계기준은 2배의 여유도를 가지고 만족하였다. 따라서, KMRR 핵연료는 피복재의 부식으로 인해 손상되지 않을 것으로 판단된다. 그러나, 수정된 Griess 부식경험식의 KMRR에의 적용 타당성은 KMRR 핵연료의 부식 감시를 통해 추가로 검증될 필요성이 있다.

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Physics study for high-performance and very-low-boron APR1400 core with 24-month cycle length

  • Do, Manseok;Nguyen, Xuan Ha;Jang, Seongdong;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제52권5호
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    • pp.869-877
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    • 2020
  • A 24-month Advanced Power Reactor 1400 (APR1400) core with a very-low-boron (VLB) concentration has been investigated for an inherently safe and high-performance PWR in this work. To develop a high-performance APR1400 which is able to do the passive frequency control operation, VLB feature is essential. In this paper, the centrally-shielded burnable absorber (CSBA) is utilized for an efficient VLB operation in the 24-month cycle APR1400 core. This innovative design of the VLB APR1400 core includes the optimization of burnable absorber and loading pattern as well as axial cutback for a 24-month cycle operation. In addition to CSBA, an Er-doped guide thimble is also introduced for partial management of the excess reactivity and local peaking factor. To improve the neutron economy of the core, two alternative radial reflectors are adopted in this study, which are SS-304 and ZrO2. The core reactivity and power distributions for a 2-batch equilibrium cycle are analyzed and compared for each reflector design. Numerical results show that a VLB core can be successfully designed with 24-month cycle and the cycle length is improved significantly with the alternative reflectors. The neutronic analyses are performed using the Monte Carlo Serpent code and 3-D diffusion code COREDAX-2 with the ENDF/B-VII.1.

Mechanical behaviour of composite columns composed of RAC-filled square steel tube and profile steel under eccentric compression loads

  • Ma, Hui;Xi, Jiacheng;Zhao, Yaoli;Dong, Jikun
    • Steel and Composite Structures
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    • 제38권1호
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    • pp.103-120
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    • 2021
  • This research examines the eccentric compression performance of composite columns composed of recycled aggregate concrete (RAC)-filled square steel tube and profile steel. A total of 17 specimens on the composite columns with different recycled coarse aggregate (RCA) replacement percentage, RAC strength, width to thickness ratio of square steel tube, profile steel ratio, eccentricity and slenderness ratio were subjected to eccentric compression tests. The failure process and characteristic of specimens under eccentric compression loading were observed in detail. The load-lateral deflection curves, load-train curves and strain distribution on the cross section of the composite columns were also obtained and described on the basis of test data. Results corroborate that the failure characteristics and modes of the specimens with different design parameters were basically similar under eccentric compression loads. The compression side of square steel tube yields first, followed by the compression side of profile steel. Finally, the RAC in the columns was crushed and the apparent local bulging of square steel tube was also observed, which meant that the composite column was damaged and failed. The composite columns under eccentric compression loading suffered from typical bending failure. Moreover, the eccentric bearing capacity and deformation of the specimens decreased as the RCA replacement percentage and width to thickness ratio of square steel tube increased, respectively. Slenderness ratio and eccentricity had a significantly adverse effect on the eccentric compression performance of composite columns. But overall, the composite columns generally had high-bearing capacity and good deformation. Meanwhile, the mechanism of the composite columns under eccentric compression loads was also analysed in detail, and the calculation formulas on the eccentric compression capacity of composite columns were proposed via the limit equilibrium analysis method. The calculation results of the eccentric compression capacity of columns are consistent with the test results, which verify the validity of the formulas, and the conclusions can serve as references for the engineering application of this kind of composite columns.

MEC를 활용한 커넥티드 홈의 DRL 기반 태스크 오프로딩 기법 (Task offloading scheme based on the DRL of Connected Home using MEC)

  • 임덕선;손규식
    • 한국인터넷방송통신학회논문지
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    • 제23권6호
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    • pp.61-67
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    • 2023
  • 5G의 도래와 스마트 디바이스의 급격한 증가는 멀티 액세스 엣지 컴퓨팅(MEC)의 중요성을 부각시켰다. 이런 흐름 속에서, 특히 계산 집약적이고 지연시간에 민감한 애플리케이션의 효과적인 처리가 큰 관심을 받고 있다. 본 논문에서는 이러한 도전 과제를 해결하기 위해 확률적인 MEC 환경을 고려한 새로운 태스크 오프로딩 전략을 연구한다. 먼저 동적인 태스크 요청 빈도와 불안정한 무선 채널 상태를 감안하여 차량의 전력 소모와 지연시간을 최소화하는 방안을 제시한다. 그리고 심층 강화학습(DRL) 기반의 오프로딩 기법을 중심으로 연구를 진행하였고, 로컬 연산 및 오프로딩 전송 전력 사이의 최적의 균형을 찾기 위한 방법을 제안한다. Deep Deterministic Policy Gradient (DDPG)와 Deep Q-Network (DQN) 기법을 활용하여 차량의 전력 사용량과 큐잉 지연시간을 분석하였다. 이를 통해 차량 기반의 MEC 환경에서의 최적의 성능 향상 전략을 도출 및 검증하였다.