• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
• /
• pp.250-254
• /
• 2002

Intergranular corrosion of austenitic stainless steels is a conventional and momentous problem during welding and high temperature use. One of the major reasons for such intergranular corrosion is so-called sensitization, i.e., chromium depletion due to chromium carbide precipitation at grain boundaries. Conventional methods for preventing sensitization of austenitic stainless steels include reduction of carbon content in the material, stabilization of carbon atoms as non-chromium carbides by the addition of titanium, niobium or zirconium, local solution-heat-treatment by laser beam, etc. These methods, however, are not without drawbacks. Recent grain boundary structure studies have demonstrated that grain boundary phenomena strongly depend on the crystallographic nature and atomic structure of the grain boundary, and that grain boundaries with coincidence site lattices are immune to intergranular corrosion. The concept of "grain boundary design and control", which involves a desirable grain boundary character distribution, has been developed as grain boundary engineering. The feasibility of grain boundary engineering has been demonstrated mainly by thermomechanical treatments. In the present study, a thermomechanical treatment was tried to improve the resistance to the sensitization by grain boundary engineering. A type 304 austenitic stainless steel was pre-strained and heat-treated, and then sensitized, varying the parameters (pre-strain, temperature, time, etc.) during the thermomechanical treatment. The grain boundary character distribution was examined by orientation imaging microscopy. The intergranular corrosion resistance was evaluated by electrochemical potentiokinetic reactivation and ferric sulfate-sulfuric acid tests. The sensitivity to intergranular corrosion was reduced by the thermomechanical treatment and indicated a minimum at a small roll-reduction. The frequency of coincidence-site-lattice boundaries indicated a maximum at a small strain. The ferric sulfate-sulfuric acid test showed much smaller corrosion rate in the thermomechanically-treated specimen than in the base material. An excellent intergranular corrosion resistance was obtained by a small strain annealing at a relatively low temperature for long time. The optimum parameters created a uniform distribution of a high frequency of coincidence site lattice boundaries in the specimen where corrosive random boundaries were isolated. The results suggest that the thermomechanical treatment can introduce low energy segments in the grain boundary network by annealing twins and can arrest the percolation of intergranular corrosion from the surface.

• 한국수소및신에너지학회논문집
• /
• 제24권4호
• /
• pp.311-319
• /
• 2013

A clear understanding on cell voltage-reversal behavior due to local hydrogen starvation in a stack is of paramount importance to operate the fuel cell vehicle (FCV) stably since it affects significantly the cell performance and durability. In the present study, a novel experimental method to simulate the local cell voltage-reversal behavior caused by local hydrogen starvation, which typically occurs only one or several cells out of several hundred cells in a stack of FCV, has been proposed. Contrary to the conventional method of overall fuel starvation, the present method of local hydrogen starvation caused the local cell voltage-reversal behavior in a stack very well. Degradation of both membrane electrode assembly (i.e., pin-hole formation) and gas diffusion layer due to an excessive exothermic heat under voltage-reversal condition was also observed clearly.

• 대한기계학회논문집A
• /
• 제30권5호
• /
• pp.533-542
• /
• 2006

In order to assess the integrity of pipes with local thinning area, the plastic strain as well as the elastic strain at the root of thinned region are required particularly when fluctuating load is applied to the pipe. For estimating elastic-plastic strain at local wall thinning area in a straight pipe under tensile load, an estimation model with idealized fully circumferential constant depth wall thinning area is proposed. Based on the compatibility and equilibrium equations a nonlinear estimation equation, from which local elastic-plastic strain can be determined as a function of pipe/defect geometry, material and the applied strain was derived. Estimation results are compared with those from detailed elastic-plastic finite element analysis, which shows good agreements. Noting that practical wall thinning in nuclear piping has not only a circular shape but also a finite circumferential length, the proposed solution for the ideal geometry is extended based on two-dimensional and three-dimensional numerical analysis of pipes with circular wall thinning.

• 한국표면공학회지
• /
• 제53권3호
• /
• pp.95-103
• /
• 2020

In this study, the material used in the hot dip galvanizing equipment was poorly corrosion-resistant, so it was performed to solve the cost and time problems caused by equipment replacement. The theoretical calculation was performed using the DV-Xα method(Discrete Variational Local-density approximation method). The alloy (STS4XX series) of the equipment currently used has a martensite phase. Therefore, the theoretical calculation was performed by applying P4 / mmm, which is a tetragonal structure. The new alloy was chosen by designing theoretical values close to existing materials. Considering elements that contribute to corrosion, most have high prices. Therefore, the design was completed by adjusting the content using only the components of the reference material in the theoretical design. The final design alloys were chosen as D6 and D9. Designed D6 and D9 were dissolved and prepared using an induction furnace. After the heat treatment process was completed, the corrosion rate of the alloys was confirmed by using the potentiodynamic polarization test. The surface of the prepared alloys were processed horizontally and then polished to # 1200 using sand paper to perform potentiodynamic polarization test. Domestic products: 4.735 mpy (mils / year), D6: 0.9166 mpy, D9: 0.3372 mpy, alloys designed than domestic products had a lower corrosion rate. Therefore, the designed alloy was expected to have better erosion resistance.

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2004년도 학술논문집
• /
• pp.285-291
• /
• 2004

LiCl-$Li_2O-O_2$ 용융염계에서 용융염 취급장치의 구조재료를 위한 평가의 일환으로 Inconel 718, X-750, Haynes 75, 263 합금의 부식거동을 분위기온도; $650^{\circ}C$, 부식시간: 24~168h, $Li_2O$농도; 3wt%, 혼합가스농도; Ar-10%$O_2$에서 조사하였다. LiCl-$Li_2O-O_2$ 용융염계에서 부식속도는 Haynes 263 ＜ Haynes 75 ＜ Inconel X-750 ＜ Inconel 718 순서로 나타났으며, Haynes 263 합금이 가장 우수한 내부식성을 나타내었다. Haynes 75의 부식생성물은 $Cr_2O_4$, $NiFe_2O_4$, $LiNiO_2$, $Li_2NiFe_2O_4$, Inconel 718의 부식생성물은 $Cr_2O_4$ 및 $NiFe_2O_4$ 이며 Haynes 263은 $Li(Ni,Co)O_2$, $NiCr_2O_4$ 및 $LiTiO_2$, Inconel X-750은 $Cr_2O_3$, $NiFe_2O_4$,$FeNi_3$, (Al,Nb,Ti)$O_2$의 부식생성물을 나타내었다. Haynes 263은 국부부식의 거동을 보이는 반면, Haynes 75, Inconel 718 및 Inconel X-750은 전면 부식 거동을 나타내었다.

• Journal of Advanced Marine Engineering and Technology
• /
• 제39권5호
• /
• pp.542-547
• /
• 2015

Since the oil price has been significantly jumped for several years, a heavy oil of low quality has been mainly used in the diesel engine of the merchant ship. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone revealed the lowest value, having the highest value of hardness. The corrosive products with red color and local corrosion like as a pitting corrosion were considerably observed at the base metal zone, while these morphologies were not wholly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the Inconel 625 electrode.

• 한국해양공학회:학술대회논문집
• /
• 한국해양공학회 2004년도 학술대회지
• /
• pp.320-325
• /
• 2004

Fracture behaviors and strength of pipes with local wall thinning are very important Jar the integrity of energy plants. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion damage. Recently, the effects of local wall thinning on strength and fracture behaviors of piping system have been well studied. In this paper, the elasto-plastic analysis is performed by FE code ANSIS. We evaluated the failure mode, fracture strength and fracture behavior from FE analysis.

• 대한기계학회논문집A
• /
• 제29권4호
• /
• pp.606-613
• /
• 2005

Effects of circumferentially local wall thinning on the fracture behavior of pipes were investigated by monotonic four-point bending. Local wall thinning was machined on the pipes in order to simulate erosion/corrosion metal loss. The configurations of the eroded area included an eroded ratio of d/t= 0.2, 0.5, 0.6, and 0.8, and an eroded length of ${\ell}\;=10mm,$ 25mm, and 120mm. Fracture type could be classified into ovalization, local buckling, and crack initiation depending on the eroded length and eroded ratio. Three-dimensional elasto-plastic analyses were also carried out using the finite element method, which is able to accurately simulate fracture behaviors excepting failure due to cracking. It was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the thinned area.

• 동력기계공학회지
• /
• 제18권1호
• /
• pp.76-83
• /
• 2014

This study was carried out an experimental and finite element analysis on the fracture behavior of straight pipes with local wall thinning under internal pressure. Local wall thinning was machined on the pipes in order to simulate erosion/corrosion metal loss. The configurations of the eroded area has an eroded ratio of d/t=0.80~0.92 and an eroded length of l=25, 50 and 102 mm. Three-dimensional elastic-plastic analyses were also carried out using the finite element method, which is able to accurately simulate failure behaviors. In regards to the relation ship between pressure and eroded ratio, the criterion that can be used safely under operating pressure and design pressure were obtained from this calculation. The results of this calculation were in relatively good agreement with that of the experiment.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 1995년도 제2회 단조심포지엄 단조기술의 진보
• /
• pp.81-90
• /
• 1995

Age hardenable aluminum alloys show high specific strength, good thermal and electrical conductivity as well as lightness, and are typical aircraft materials. High fatigue strength and good resistancy against stress corrosion cracking are also important for aircraft aluminum alloys. Al alloy 7050 has been developed to meet the above mentioned requirements and the use of this alloy as forged aircraft part becomes more important. However, forged 7050 parts showed undersirable structures such as severe local grain coarsening in surface area and unproper metal flow that is degrading mechanical properties. In this paper, microstructural aspects of die forging in the Al alloy 7050 are investigated. Also suggested are the optimal forging conditions for microstructural control of Al alloy 7050.