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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Yoon, Yong-Hee;Lee, Seung-Chul;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.81-85
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    • 2007
  • A fluidized bed reactor is made with quartz. The size of FBR is 0.055 m I.D. and 1.0 m in height. The FBR was employed for the thermocatalytic decomposition of propane to produce hydrogen without $CO_{2}$. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. Carbon black DCC-N330 is used to decompose the propane gas. The propane decomposition reaction over carbon black catalyst in a fluidized bed reactor was carried out the temperature range of 600 ${\sim}$ 800 $^{\circ}C$, propane gas velocity of 1.0 ${\sim}$ 4.0$U_{mf}$($1U_{mf}$ = 0.61cm/s) and the catalyst loading of 100 ${\sim}$ 200g. Production of $H_{2}$ such as other reaction temperature, gas velocity, catalytic loading on the reaction rates was investigated. The carbon depositied on the catalyst surface was observed by FE-SEM. The particle size of the carbon black was observed by Particle size analyzer. Resulting production in the experiment was not only hydrogen but also several by-products such as methane, ethylene, ethane, and propylene.

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Taming of large diameter triaxial setup

  • Nair, Asha M.;Madhavi Latha, G.
    • Geomechanics and Engineering
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    • v.4 no.4
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    • pp.251-262
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    • 2012
  • Triaxial tests are essential to estimate the shear strength properties of the soil or rock. Normally triaxial tests are carried out on samples of 38 mm diameter and 76 mm height. Granular materials, predominantly used in base/sub-base construction of pavements or in railways have size range of 60-75 mm. Determination of shear strength parameters of those materials can be made possible only through triaxial tests on large diameter samples. This paper describes a large diameter cyclic triaxial testing facility set up in the Geotechnical Engineering lab of Indian Institute of Science. This setup consists of 100 kN capacity dynamic loading frame, which facilitates testing of samples of up to 300 mm diameter and 600 mm height. The loading ram can be actuated up to a maximum frequency of 10 Hz, with maximum amplitude of 100 mm. The setup is capable of carrying out static as well as dynamic triaxial tests under isotropic, anisotropic conditions with a maximum confining pressure of 1 MPa. Working with this setup is a difficult task because of the size of the sample. In this paper, a detailed discussion on the various problems encountered during the initial testing using the equipment, the ideas and solutions adopted to solve them are presented. Pilot experiments on granular sub-base material of 53 mm down size are also presented.

A strengthening effect based on a grid size of a bamboo-mat and a model-test for the understanding on ground failure. (대나무매트의 격자크기에 따른 보강효과 및 지반 파괴형상 파악을 위한 모형시험)

  • Lee, Ji-Hun;Kim, Seung-Gon;Kim, Woo-Jin;Kim, Jong-Ryeol;Kang, Hee-Bog
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1673-1677
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    • 2008
  • A method of construction with a basis treatment that uses a latticed bamboo mat puts bamboo's peculiarity and bamboo mat's bending substance to use, and a latticed bamboo mat equally distributes to embankment loading in a basis ground. Therefore it prevents ground destruction by an ill-balanced load and an irregular ground subsidence, and it makes safety system. This investigation make progress a soil box model by a dredged reclamation ground of west and south sea at domestic area, and make a comparative study and analyze the strengthening effect based on a grid size of a bamboo-mat and ground failure that it will use in the field.

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Spray Drying of Ferrite Powders and the Characteristics of the Granule (페라이트 분말의 분무건조와 제조된 과립의 특성)

  • 변순천;제해준;홍국선
    • Journal of the Korean Ceramic Society
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    • v.32 no.5
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    • pp.549-558
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    • 1995
  • Mn-Zn ferrite granules were prepared by spray drying of the slurry containing different kinds and concentration of binders at various spray drying temperatures and atomizing pressures. The characteristics of the spraydried granules were analyzed according to the processing variables of spray drying and the slurries containing different solid loading and kinds and concentration of binders. Typical shape of the spray dried granules was spherical. The granules spray dried at 15$0^{\circ}C$ were more spherical and containing lower hollow percentage than any other granules prepared at higher temperature. The granules prepared at higher atomizing pressures were more spherical and become smaller in size. The granules prepared using slurry containing higher solid loading were larger in size and less defective in shape. As increasing the concentration of binder the number of donut-shaped granules was increased and the size distribution become broader. The granules prepared using the slurry containing PVA 205 were more spherical than those containing PVA 217 and PVA 117. As the amount of granules which were donut-shaped or dimpled increased the compaction response were less effective. The hollows were not fractured completely even at hight pressures and remained after sintering.

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Effects of loading frequency and specimen size on the liquefaction resistance of clean sand

  • Sung-Sik Park;Dong-Eun Lee;Dong-Kiem-Lam Tran
    • Geomechanics and Engineering
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    • v.37 no.2
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    • pp.123-133
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    • 2024
  • This study investigates the effects of loading frequency (f) and specimen size on the liquefaction resistance of clean sand. A series of cyclic direct simple shear tests were conducted on Jumunjin sand with varying consolidated relative densities (40% and 80%), f values (0.05, 0.10, and 0.20 Hz), and diameter to height (D/H) ratios (3.63, 3.18, 2.82, and 2.54). The results demonstrated the significant influence of f and D/H ratio on the number of cycles to liquefaction (Ncyc-liq) and the cyclic resistance ratio (CRR15). It was observed that increasing f linearly increased Ncyc-liq. Increasing the specimen height also led to higher Ncyc-liq values irrespective of the f or relative density. Moreover, a positive correlation between CRR15 and f indicated that higher f yielded higher CRR15. This relationship was more pronounced in dense sand than in loose sand. Specimen height also significantly affected CRR15, with increasing the specimen height resulting in higher CRR15 values. Furthermore, the effect of f on CRR15 was less significant compared to the influence of specimen height. The effect of f on the normalized cyclic resistance ratio (NCRR) was relatively negligible for loose sand but more substantial for dense sand depending on the D/H ratio. Data analysis revealed that the NCRR generally decreases as the D/H ratio increases. An interpolation formula was provided to calculate the NCRR based on the D/H ratio regardless of the f and relative density.

Highly filled AIN/epoxy composites for microelectronic encapsulation (반도체 봉지용 고충진 AIN/Epoxy 복합재료)

  • 배종우;김원호;황영훈
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.131-134
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    • 2000
  • Increased temperature adversely affects the reliability of a device. So, package material should have high thermal diffusion, i.e., high thermal conductivity. And, there are several other physical properties of polymeric materials that are important to microelectronics packaging, some of which are a low dielectric constant, a low coefficient of thermal expansion (CTE), and a high flexural strength. In this study, to get practical maximum packing fraction of AIN (granular type) filled EMC, the properties such as the spiral flow, thermal conductivity, CTE, and water resistance of AIN-filled EMC (65-vol%) were evaluated according to the size of AIN and the filler-size distribution. Also, physical properties of AIN filled EMC above 65-vol% were evaluated according to increasing AIN content at the point of maximum packing fraction (highly loading condition). The high loading conditions of EMC were set $D_L/D_S$=12 and $X_S$=0.25 like as filler of sphere shape and the AIN filled EMC in this conditions can be obtained satisfactory fluidity up to 70-vol%. As a result, the AIN filled EMC (70-vol%) at high loading condition showed improved thermal conductivity (about 6 W/m-K), dielectric constant (2.0~3.0), CTE(less than 14 ppm/$^{\circ}C$) and water resistance. So, the AIN filled EMC (70-vol%) at high loading condition meets the requirement fur advanced microelectronic packaging materials.

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Characteristics of Bearing Capacity and Settlement According to the Difference of Loading Plate Sizes (재하판의 크기에 따른 지지력 및 침하특성)

  • 정형식;김도열
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.179-188
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    • 2002
  • The scale effect should be considered to determine the bearing capacity and settlement of footings from plate-load test, because of the size difference between a footing and a loading plate. To analyze characteristics of bearing capacity and settlement according to the difference of loading plate sizes, model tests were performed with four different sizes of square plate, which are B=10, 15, 20, and 25cm respectively, on five different kinds of subsoils. Test results showed that the ultimate bearing capacity of a footing on the sand did not increase proportional to the traditional formula and the bearing capacity on the clay also increased a little with increasing the size of loading plate. The settlement of test plate on the sand did not increase as the traditional formula of Terzaghi and Peck (1967), and the settlement on the clay also did not increase proportional to the traditional formula.

Effect of Particle Loading on the Collection Performance of an Electret Cabin Air Filter for Submicron Particles (입자 퇴적이 승용차용 정전 필터의 미세 입자 포집 특성에 미치는 영향)

  • Ji, Jun-Ho;Gang, Seok-Hun;Hwang, Jeong-Ho;Bae, Gwi-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.8
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    • pp.1102-1114
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    • 2002
  • An electret filter is composed of permanently charged electret fibers and is widely used in applications requiring high collection efficiency and low-pressure drop. In this work, the collection efficiency of the filter media used in manufacturing cabin air filters was investigated by using poly-disperse particles when submicron particles were loaded. Long-term experiments were conducted by applying two different charging states, which were spray electrification and charge equilibrium by bipolar ionization. In order to investigate the effect of particle loading in filter media, NaCl particles were generated from 0.1% and 1% solutions by an atomizer. Liquid DOS particles were used to evaluate the effect of liquid particles on the collection efficiency of an electret filter. The results show significant effect of charge amount and size distribution of loading particles on the collection performance of a filter media in submicron region. Smaller particles loaded in electret fibers cause a more rapid degradation in collection efficiency and have lower minimum efficiency with time. The pressure drop of a filter media do rarely increase when the collection efficiency decreases to the minimum value. For the larger particles charged by spray electrification, which have charge amounts more than that of Boltzmann equilibrium charge distribution, the pressure drop of a filter media slowly increases in comparison with that of equilibrium charged particles. For DOS particles it is shown that the charging level of an electret filter severely decreases and the collection efficiency is below 10% in some particle size range.

Platinum nanoparticles loading on carbon nanotube by impregnation and direct heating method (열처리 방법으로 탄소나노튜브에 백금 나노입자의 담지)

  • Lee, Changho;Kim, Heeyeon;Ryu, Seungkon
    • 대한공업교육학회지
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    • v.32 no.2
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    • pp.188-198
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    • 2007
  • Platinum nanoparticles loading on carbon nanotube was carried out by impregnation of hexachloro platinate(IV) from hydrogen hexachloro platinate(IV) hydrate dissolved solution without using reduction agents, and heating the hexachloro platinate(IV) impregnated carbon nanotube up to $400^{\circ}C$. The amounts of impregnated hexachloro platinate(IV) on to carbon nanotube were measured with UV-visible spectrophotometer. The TG, XRD, and TEM analysis were performed to confirm the platinum particles loading and distribution on carbon nanotube. The average platinum particles size on carbon nanotube was under 2 nm by heating the hexachloro platinate(IV) up to $400^{\circ}C$ in spite of non-using reduction agents, while the average size increased due to the agglomeration of some particles by heating them up to $800^{\circ}C$. Therefore, uniformly distributed platinum nanoparticles loading on carbon nanotube can be obtained from simple impregnation of hexachloro platinate(IV) from solution and heating it up to $400^{\circ}C$.

A Study on the Concrete Breakout Capacity of CIP Anchor Bolts under Shear Loading (전단력을 받는 선설치 앵커볼트의 콘크리트 파열파괴강도 평가 연구)

  • Park, Yong-Myung;Jeon, Myeong-Hui;Choi, Myung-Kuk;Kim, Cheol-Hwan;Kim, In-Gi
    • Journal of Korean Society of Steel Construction
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    • v.24 no.2
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    • pp.207-215
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    • 2012
  • The 45-degree cone failure theory has been used in concrete anchor bolts design under shear loading, but the CCD (Concrete Capacity Design) method was adopted as a new design method since 2000. However, the method was allowed only for anchor diameters of less than 50mm because it is based on the experimental results of small size anchor bolts. Therefore, it is necessary to develop a rational concrete breakout capacity equation for medium-to-large size anchor bolts with large edge distance. In this study, shear tests on M56 cast-in-place single anchor bolt with edge distance of 350mm were performed using four test specimens. Based on the test results and findings of existing studies, a new equation for the breakout capacity of anchor bolts under shear loading with edge distance of up to 750mm was proposed.