• Journal of Industrial Technology
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• v.40 no.1
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• pp.7-12
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• 2020

Lithium-ion cells have become the go-to energy source across all applications; however, dendritic growth remains an issue to tackle. While there have been various research conducted and possible solutions offered, there is yet to be one that efficiently rules out the problem without, however, introducing another. This paper seeks to present a fast charging method and system to which lithium-ion batteries are charged while maintaining their lifetime. In the proposed method, various lithium cells are charged under multiple profiles. The parameters of charge profiles that inflict damage to the cell's electrodes are obtained and used as thresholds. Thus, during charging, voltage, current, and temperature are actively controlled under these thresholds. In this way, dendrite formation suppressed charging is achieved, and battery life is maintained. The fast-charging system designed, comprises of a 1.5kW charger, an inbuilt 600W battery pack, and an intelligent BMS with cell balancing technology. The system was also designed to respond to the aging of the battery to provide adequate threshold values. Among other tests conducted by KCTL, the cycle test result showed a capacity drop of only 0.68% after 500 cycles, thereby proving the life maintaining capability of the proposed method and system.

• Proceedings of the KIPE Conference
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• 2008.06a
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• pp.535-537
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• 2008

This paper proposes a modularized two-stage charge equalization converter for a series-connected lithium-ion battery string. In this paper, the series-connected battery sting is modularized into M modules, and each module has K cells in series. With this modularization, low voltage stress on the electronic devices can be achieved. A two-stage dc-dc converter with cell selection switches is employed. The first stage dc-dc converter steps down the high bus voltage to about 10 V. The second stage dc-dc converter integrated with selection switches equalizes the cell voltages. A prototype for 88 lithium-ion battery cells is optimally designed and implemented. Experimental results verify that the proposed equalization method has good cell balancing performance showing low voltage stress, small size, and low cost.

• Proceedings of the KIPE Conference
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• 2007.07a
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• pp.347-349
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• 2007

Charge equalization scheme for HEV lithium-ion battery system is proposed in this paper, where all the primary windings with in parallel bi-directional switches are coupled in series to provide the equalizing energy from the whole battery string to the specific under charged cells. Moreover, to realize minimized size of equalization circuit employing the proposed cell balancing scheme, the optimal power rating design rule according to equalization time and SOC distribution of imbalance is proposed. A prototype of HEV lithium-ion battery system of four cells shows the outstanding charge equalization performance while maintaining greatly reduced size of cell balancing circuit.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.49 no.6
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• pp.328-334
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• 2000

A lithium ion secondary battery using carbon as a negative electrode has been developed. Further improvements to increase the cell capacity are expected by modifying the structure of the carbonaceous material. There are hopes for the development of large capacity lithium ion secondary batteries with long cycle, high energy density, high power density, and high energy efficiency. In the present paper, needle cokes from petroleum were examined as an anode of lithium ion secondary battery. Petroleum cokes, MCL(Molten Caustic Leaching) treated in Korea Institute Energy Research, were carbonized at various temperatures of 0, 500, 700, $19700^{\circ}C$ at heating rate of $2^{\circ}C$/min for lh. The electrolyte was used lM liPF6 EC/DEC (1:1). The voltage range of charge & discharge was 0.0V(0.05V) ~ 2.0V. The treated petroleum coke at $700^{\circ}C$ had an initial capacity over 560mAh.g which beyond the theoretical maximum capacity, 372mAh/g for LiC6. This phenomena suggests that carbon materials with disordered structure had higher cell capacity than that the graphitic carbon materials.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.11
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• pp.1157-1163
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• 2009

This paper introduces the lithium ion battery management system for STSAT-3 satellite. The specifications of lithium ion battery unit are proposed to supply power to the satellite and the overall electrical design for lithium ion battery BMS is presented. Furthermore, the test results of battery management system are shown to verify the design.

• Journal of Industrial Technology
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• v.43 no.1
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• pp.15-23
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• 2023

Lithium-ion batteries are predominantly employed in electric vehicles and energy storage devices, offering the advantage of high energy density. However, they are susceptible to efficiency degradation when operated at high temperatures due to their sensitivity to the external environment. In this study, we conducted experiments using an indirect cooling method to prevent thermal runaway and explosions in lithium-ion batteries. The results were validated by comparing them with heat transfer simulations conducted through a commercial finite element analysis program. The experiments included single-cell exothermic tests and cooling experiments on a battery pack with 10 cells connected in series, utilizing 21700 lithium-ion batteries. To block external temperature influences, the experimental environment featured an extrusion method insulation in the environmental chamber. The cooling system, suitable for indirect cooling, was constructed with copper tubes and pins. The heat transfer analysis began by presenting a single-cell heating model using commercial software, which was then employed to analyze the heating and cooling of the battery pack.

• Journal of Industrial Technology
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• v.42 no.1
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• pp.7-12
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• 2022

High nickel layered oxide cathodes are gaining increasing attention for lithium-ion batteries due to their higher energy density and lower cost compared to LiCoO₂. However, they suffer from the formation of residual lithium on the surface in the form of LiOH and Li₂CO₃ on exposure to ambient air. The residual lithium causes notorious issues, such as slurry gelation during electrode preparation and gas evolution during cell cycling. In this review, we investigate the residual lithium issues through its impact on cathode slurry instability based on deformed polyvinylidene fluoride (PVdF) as well as its formation and reduction mechanism in terms of inherently off-stoichiometric synthesis of high nickel cathodes. Additionally, new analysis method with anhydrous methanol was introduced to exclude Li⁺/H⁺ exchange effect during sample preparation with distilled water. We hope that this review would contribute to encouraging the academic efforts to consider practical aspects and mitigation in global high-energy-density lithium-ion battery manufacturers.

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.37.1-37.1
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• 2007

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.8
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• pp.775-780
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• 2013

In general, the battery module of an electric vehicle (EV) consists of lithium-ion cells. A lithium-ion battery is a secondary rechargeable battery, and it consists of numerous stacked plates that serve as electrodes and separators. Owing to these microstructural features, its numerical analysis is very expensive. Therefore, this study aims to present a simplified thermal analysis model using equivalent thermal properties, and we compare the experimental results with numerical results for 185.3Ah and 20Ah cells. Furthermore, we show the thermal behavior of cells without the finite element method (FEM) or finite volume method (FVM) by adopting the lumped capacitance method (LCM).

• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.319-322
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• 2009

Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.