• 제목/요약/키워드: Lithium molten salt

검색결과 43건 처리시간 0.019초

A New Ionic Liquid for a Redox Electrolyte of Dye-Sensitized Solar Cells

  • Kang, Man-Gu;Ryu, Kwang-Sun;Chang, Soon-Ho;Park, Nam-Gyu
    • ETRI Journal
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    • 제26권6호
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    • pp.647-652
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    • 2004
  • A new ionic liquid, 1-vinyl-3-heptylimidazolium iodide (VHpII), was synthesized and applied as a redox electrolyte for dye-sensitized solar cells. The chemical structure of the synthesized VHpII was confirmed using $^1H$ NMR. Thermogravimetric analysis showed that the VHpII was stable for thermal stress of up to $250^{\circ}C$. The energy conversion efficiencies of the VHpII-based dye-sensitized solar cells were investigated in terms of the effect of a lithium iodide addition. A solar cell containing the redox couple of VHpII and iodine showed a conversion efficiency of 2.63% under 1 sun light intensity at AM 1.5. Adding 0.4 M LiI results in a conversion efficiency of 3.63%, which was an improvement of about 40%. The increased conversion efficiency was ascribed to an increase in external quantum efficiency.

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사용후 핵연료 차세대관리공정 원격 운전/유지보수용 천정이동 서보 매니퓰레이터 시스템 개발 (Development of a Bridge Transported Servo Manipulator System for the Remote Operation and Maintenance of Advanced Spent Fuel Conditioning Process)

  • 박병석;이종광;이효직;최창환;윤광호;윤지섭
    • 제어로봇시스템학회논문지
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    • 제13권10호
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    • pp.940-948
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    • 2007
  • The Advanced Spent Fuel Conditioning Process(ACP), which is the process of the reduction of uranium oxide by lithium metal in a high temperature molten salt bath for spent fuel, was developed at Korea Atomic Energy Research Institute (KAERI). Since the ACP equipment is located in an intense radiation field (hot cell) as well as in a high temperature, it must be remotely operated and maintained. The ACP hot cell is very narrow so the workspace of the wall-mounted mechanical Master-Slave Manipulators(MSMs) is restricted. A Bridge Transported Servo Manipulator(BTSM) system has been developed to overcome the limitation of an access that is a drawback of the mechanical MSMs. The BTSM system consists ot a bridge crane with telescoping tubeset, a slave manipulator, a master manipulator, and a control system. We applied a bilateral position-position control scheme with friction compensation as force-reflecting controller. In this paper, the transmission characteristics on the tendon-and-pulley train is numerically formulated and analyzed. Also, we evaluate the performance of the force-reflecting servo manipulator.

OVERVIEW OF FUSION BLANKET R&D IN THE US OVER THE LAST DECADE

  • ABDOU M. A.;MORLEY N. B.;YING A. Y.;SMOLENTSEV S.;CALDERONI P.
    • Nuclear Engineering and Technology
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    • 제37권5호
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    • pp.401-422
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    • 2005
  • We review here research and development progress achieved in US Plasma Chamber technology roughly over the last decade. In particular, we focus on two major programs carried out in the US: the APEX project (1998-2003) and the US ITER TBM activities (2003-present). The APEX project grew out of the US fusion program emphasis in the late 1990s on more fundamental science and innovation. APEX was commissioned to investigate novel technology concepts for achieving high power density and high temperature reactor coolants. In particular, the idea of liquid walls and the related research is described here, with some detailed examples of liquid metal and molten salt magnetohydrodynamic and free surface effects on flow control and heat transfer. The ongoing US ITER Test Blanket Module (TBM) program is also described, where the current first wall/blanket concepts being considered are the dual coolant lead lithium concept and the solid breeder helium cooled concepts, both using ferritic steel structures. The research described for these concepts includes both thermofluid MHD issues for the liquid metal coolant in the DCLL, and thermomechanical issues for ceramic breeder packed pebble beds in the solid breeder concept. Finally, future directions for ongoing research in these areas are described.