• 제목/요약/키워드: Lithium bromide solution

검색결과 44건 처리시간 0.028초

스프링삽입형 유하액막식 흡수기의 열 및 물질전달 특성 (Characteristics of Heat and Mass Transfer for a Falling Film Type Absorber with Insert Spring Tubes)

  • 윤정인;오후규;백목효부
    • 대한기계학회논문집
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    • 제19권6호
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    • pp.1501-1509
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    • 1995
  • It is known that the heat and mass transfer characteristics in the absorber are most sensitive of the temperature boost of all the heat exchangers and the development of a more efficient absorber should be highly important. This paper describes absorption experiments made with different inside tube diameters, tube length and tube shapes. The purpose of this study is to acquire basic knowledge about heat and mass transfer in a falling film type absorber with vertical inner tubes. Heat and mass transfer were measured for water vapor absorption into a Lithium Bromide-water solution flowing down an absorber of vertical inner tubes. As a result, insert spring tube compares bare tube and heat transfer improved by order of insert spring tube P2(pitch 20 mm) and P1(pitch 10 mm).

LiBr작동유체 중에서 가스흡수식 냉온수기의 국부부식 특성에 관한 연구 (A Study on the Characteristics of Local Corrosion for Gas Absorption Refrigeration and Hot Water Systems in LiBr-$H_2O$ Working Fluids)

  • Uh- Joh Lim;Ki-Cheol Jeong;Byoung-Du Yun
    • Journal of Advanced Marine Engineering and Technology
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    • 제27권6호
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    • pp.714-720
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    • 2003
  • Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

Experimental Study on Heat Transfer Performance of Absorber with Variable Plate Types

  • M.A. Sarker;Moon, C.G.;Lee, H.S.;Kim, E.P.;Yoon, J.I.
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2004년도 춘계 학술발표회 논문집
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    • pp.201-212
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    • 2004
  • An experimental study of the absorption process of water vapor into a lithium bromide solution was performed. For the purpose of developing high performance absorption chiller/hater utilizing lithium bromide solution as working fluid, it is important to improve the performance of absorber with the larger heat transfer area of the four heat exchangers. The experimental apparatus was composed of a plate type absorber which could increase the heat exchange area per unit volume to investigate more detail characteristics instead of the conventional type, that is, horizontal tube bundle type. The size of plate absorbers were made for 0.4m$\times$0.6m and the design objective of a refrigeration capacity was 1RT. In this experiment, three kinds of plate absorbers namely flat plate, dimple plate and groove plate were used. The obtained results were less than the design objective values, that is, the refrigeration capacity was about 0.3 ~0.4RT and the overall heat transfer coefficient was 500~600 kcal/$m^2$h$^{\circ}C$ at the standard conditions.

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중성염에 의한 견사의 수축작용 (Studies on Silk Contraction Treated with Neutral Salts)

  • 이광길;이용우;남중희
    • 한국잠사곤충학회지
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    • 제39권1호
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    • pp.44-55
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    • 1997
  • This study was carried out to find out the relationship between qualities and contraction phenomenon of silk fibers by treatment of concentrated neutral salts. The contraction effects of silk fibers showed the critical point on the treatment conditions of concentration, temperature and time, among three kinds of neutral salts such as calcium nitrate, calcium chloride and lithium bromide. But, The silk fibers, pretreated with bromide and/or formaldehyde, did not show the contraction upon treating with calcium nitrate. This indicates that tyrosine and serine can be correlated with the contraction reaction because of coupling these amino acids with bromide and formaldehyde. In conclusion, a mechanism for the contraction of silk fiber with highly concentrated calcium nitrate solution is supposed as follows. At the initial stage of ration, the water was penetrated into the amorphous regions and fibers swollen, therefore, the contraction took place mainly in amorphous regions, which have plenty of functional groups with hydroxyl residues. Then, as the calcium nitrate is penetrated into the microfibril, the gydrogen bonds of tyrosine and serine residues and broken and crystalline regions are more and more influenced by increasing concentration of calcium nitrate solution. Microgibrils of crystalline regions become entangled, contracted to linear direction and rearranged to form new stable hydrogen bonds.

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$LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향 (The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids)

  • 임우조;정기철
    • 한국가스학회지
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    • 제5권4호
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    • pp.33-39
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    • 2001
  • 흡수식냉동기의 작동매체로 사용되고 있는 LiBr수용액 중에서 각 구성재료인 일반구조용 압연강재, 동 및 동합금재인 Ai-Ni bronze의 부식거동에 관한 연구를 하기 위하여, 여러 가지 농도의 LiBr 수용액 중에서 각 재료에 대한 분극실험을 실시하여 부식거동을 고찰한 결과 다음과 같은 결론을 얻었다. 1) 수용액의 LiBr 농도가 증가할수록 각 재료의 분극저항은 낮아지고, 개로전위는 비전 위화되면서 부식전류밀도는 높게 배류된다. 2) 일반구조용 압연강재의 개로전위는 동 및 Al-Ni bronze의 개로전위보다 비전위화되면서 부식전류밀도는 더 높게 배류된다. 3) 동 및 Al-Ni bronze에 대한 $62\%$ LiBr 수용액 중에서의 양극분극은 활성태로 지속되지만, 천연해수 중에서의 양극분극은 활성태가 지속되다가 부동태화전류가 나타난다.

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고성능 흡수냉동 사이클의 특성 시뮬레이션 (Simulation of the Characteristics of High-Performance Absorption Cycles)

  • 윤정인;오후규;이용화
    • 대한기계학회논문집
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    • 제19권1호
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    • pp.231-239
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    • 1995
  • This paper describes a computer simulation of the triple effect, water-lithium bromide absorption cooling cycles. The performance of the absorption systems is investigated through cycle simulation to obtain the system characteristics with the cooling water inlet temperature, the working solution concentrations, the ratio of the amount of the weak solution to the high, middle and low temperature generators, and the temperature difference of each solution heat exchanger. The efficiency of different cycles has been studied and the simulation results show that higher coefficient of performance could be obtained for the parallel cycle of constant solution distribution rate. As a result of this analysis, the optimum designs and operating conditions were determined based on the operating conditions and coefficient of performance.

Fluorescent Silk Fibroin Nanoparticles Prepared Using a Reverse Microemulsion

  • Myung, Seung-Jun;Kim, Hun-Sik;Kim, Yeseul;Chen, Peng;Jin, Hyoung-Joon
    • Macromolecular Research
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    • 제16권7호
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    • pp.604-608
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    • 2008
  • Color dye-doped silk fibroin nanoparticles were successfully fabricated using a microemulsion method. An aqueous silk fibroin solution was prepared by dissolving cocoons (Bombyx mori) in a concentrated lithium bromide solution followed by dialysis. A color dye solution was also mixed with the aqueous silk fibroin solution. The surfactants used for the microemulsion were then removed by methanol and ethanol, yielding color dye-doped silk fibroin nanoparticles, approximately 167 nm in diameter. The secondary structure of the nanoparticles showed a $\beta$-sheet conformation, as characterized by Fourier transform infrared spectroscopy. The morphology of the nanoparticles was determined by field emission scanning electron microscopy, transmission electron microscopy and atomic force microscopy, and their size and size distribution were measured by dynamic light scattering. The color dye-doped silk fibroin nanoparticles were examined by confocal laser scanning microscopy.

수평관군에서 리튬브로마이드 수용액 막의 수증기 흡수과정에 대한 비흡수가스의 영향 (Effects of non-absorbable gases in the absorption process of water vapor Into the Lithium Bromide-water solution film on horizontal tube bank)

  • 김병주;권기석
    • 설비공학논문집
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    • 제12권2호
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    • pp.218-225
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    • 2000
  • In the present study, the effects of film Reynolds number (60∼200) and volumetric content of non-absorbable gases (0∼10%) in water vapor on the absorption process of aqueous LiBr solution were investigated experimentally. The formation of solution film on the horizontal tubes of six rows were observed to be complete for Re>100. Transition film Reynolds number were found to exist above which the Nusselt number and Schmidt number diminishes with solution flow rate. As the concentration of non-absorbable gases increased, mass transfer rate decreased more seriously than heat transfer rate did. The degradation effects of non-absorbable gases seemed to be significant especially when small amount of non-absorbable gases were introduced to the pure water vapor.

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Numerical Study on Simultaneous Heat and Mass Transfer in a Falling Film of Water-Cooled Vertical Plate Absorber

  • Phan, Thanh-Tong;Song, Sung-Ho;Moon, Choon-Geun;Kim, Jae-Dol;Kim, Eun-Pil;Yoon, Jung-In
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2002년도 춘계학술대회논문집
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    • pp.41-47
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    • 2002
  • A model of simultaneous heat and mass transfer process in absorption of refrigerant vapor into a lithium bromide solution of water-cooled vertical plate absorber was developed. The model can predict temperature and concentration profiles as well as the absorption heat and mass fluxes, the total heat and mass transfer rates and the heat and mass transfer coefficients. Besides, the effect of operating condition on absorption mass flux has been investigated, with the result that the absorption mass flux is increased as the inlet cooling water temperature decreases, the system pressure increases and the inlet solution concentration increases. And among the effects of operating parameters on absorption mass flux, the effect of inlet solution concentration is dominant.

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LiBr 수용액을 이용한 수평관 유하액막 증발의 촉진관 전열향상 특성 (Heat Transfer Enhancement Characteristics for Falling-Film Evaporation on Horizontal Enhanced Tubes with Aqueous LiBr Solution)

  • 김동관;김무환
    • 대한기계학회논문집B
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    • 제22권9호
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    • pp.1267-1276
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    • 1998
  • Falling-film evaporation experiments with aqueous lithium bromide (LiBr) solution were performed to investigate the heat transfer characteristics of enhanced copper tubes. Enhanced tubes (a knurled tube, a spirally grooved tube, and a tube coated with $20{\mu}m$ aluminum particles) and a bare tube were selected as test specimens. Averaged evaporation fluxes of water were obtained from horizontal tubes with various film Reynolds numbers, system pressures, LiBr concentrations and degrees of wall superheat. The enhanced performance of steam generation was compared between tubes with varying parameters. The knurled tube geometry showed the most excellent performance among the tubes tested. The specified enhanced tubes were more useful for generating steam on a low grade heat source such as waste heat.