• Title/Summary/Keyword: Liquid-Vapor Equilibrium

Search Result 107, Processing Time 0.027 seconds

Validation of RELAP5 MOD3.3 code for Hybrid-SIT against SET and IET experimental data

  • Yoon, Ho Joon;Al Naqbi, Waleed;Al-Yahia, Omar S.;Jo, Daeseong
    • Nuclear Engineering and Technology
    • /
    • v.52 no.9
    • /
    • pp.1926-1938
    • /
    • 2020
  • We validated the performance of RELAP MOD3.3 code regarding the hybrid SIT with available experimental data. The concept of the hybrid SIT is to connect the pressurizer to SIT to utilize the water inside SIT in the case of SBO or SB-LOCA combined with TLOFW. We investigated how well RELAP5 code predicts the physical phenomena in terms of the equilibrium time, stratification, condensation against Separate Effect Test (SET) data. We also conducted the validation of RELAP5 code against Integrated Effect Test (IET) experimental data produced by the ATLAS facility. We followed conventional approach for code validation of IET data, which are pre-test and post-test calculation. RELAP5 code shows substantial difference with changing number of nodes. The increase of the number of nodes tends to reduce the condensation rate at the interface between liquid and vapor inside the hybrid SIT. The environmental heat loss also contributes to the large discrepancy between the simulation results of RELAP5 and the experimental data.

Thermal Wave Transfer and Combustion Response of Droplet Perturbed by Acoustic Pressure (압력파에 교란된 액적내부에서의 에너지 파동 및 반응 메커니즘)

  • Lee Cilyong;Yoon Woongsub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • v.y2005m4
    • /
    • pp.183-188
    • /
    • 2005
  • This study targets to investigate thermal wave transfer in a droplet strongly coupled with acoustic pressure and its effects on combustion response. The one-dimensional vaporization model uses SRK equation of state and flash calculation method to obtain more accurate thermophysical properties and compute vapor-liquid equilibrium. Calculations of an n-pentane droplet exposed into a perturbing nitrogen gas is carried out in terms of different ambient gas pressures and wave frequencies. The thermal wave is transferred more effectively at lower frequencies, which results in the decrease in the amplitude of the response.

  • PDF

Dew Point Prediction by Lower Flash Points of Binary Mixtures (이성분계 혼합물의 하부 인화점에 의한 이슬점 예측)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Society of Safety
    • /
    • v.32 no.6
    • /
    • pp.34-39
    • /
    • 2017
  • Vapor-liquid equilibrium calculation is required to properly design and operation of distillation process. The general calculation method is to use binary interaction parameter. Lower flash points of cyclohexanol+aniline and cyclohexanol+cyclohexanone were measured by using Seta-flash closed cup apparatus. The measured flash points were compared with those calculated by the method based on Raoult's law and the optimization method using Wilson equation. The absolute average errors(A.A.E.) of the results calculated by Raout's law are $0.25^{\circ}C$ and $1.07^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. The absolute average errors of the results calculated by the optimization method are $0.22^{\circ}C$ and $0.65^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. As can be seen from A.A.E., the calculated values based on the optimization method were found to be better than those based on the Raoult's law. The binary interaction parameters calculated by the optimization method are used to predict the dew points of cyclohexanol+aniline and cyclohexanol+cyclohexanone. The A.A.E. for these mixtures show that there is an acceptable agreement between experimental and calculated dew poins.

Droplet Vaporization in High Pressure Environments with Pressure Oscillations (강한 압력 교란에 구속된 고압 액적의 천이 기화)

  • 김성엽;윤웅섭
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2003.10a
    • /
    • pp.157-163
    • /
    • 2003
  • A systematic numerical experiment has been conducted to study droplet gasification in high pressure environments with pressure oscillations. The general frame of previous rigorous model[1] is retained but tailored for flash equilibrium calculation of vapor-liquid interfacial thermodynamics. Time-dependent conservation equations of mass, momentum, energy, and species concentrations are formulated in axisymmetric coordinate system for both the droplet interior and ambient gases. In addition, a unified property evaluation scheme based on the fundamental equation of state and empirical methods are used to find fluid thermophysical properties over the entire thermodynamic domain of interest. The governing equations with appropriate physical boundary conditions are numerically time integrated using an implicit finite-difference method with a dual time-stepping technique. A series of calculation have been carried out to investigate the gasification of an isolated n-pentane droplet in a nitrogen gas environment over a wide range of ambient pressures and frequencies. Results show that the mean pressures and frequencies of the ambient gas have strong influences on the characteristics of the droplet gasification. The amplitude of the response increases with increasing pressure, and the magnitude of the vaporization response increases with the frequency.

  • PDF

Deformation Analysis of Miniature Metal Bellows Charged Nitrogen for Temperature Change to Cryogenic Condition (극저온까지 온도변화에 따른 질소 충전 소형 금속 벨로우즈의 변형 해석)

  • Lee, Seung-Ha;Lee, Tae-Won
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.26 no.10
    • /
    • pp.81-88
    • /
    • 2009
  • Bellows is used to control temperature of a Joule-Thomson micro cryocooler. It is made of Nickelcobalt alloy that retains mechanical properties from cryogenic temperature to temperature of 570K. The geometry of bellows is an axisymmetric shell and Nitrogen with high pressure was charged at temperature of 293K. During cool-down process, the pressure and volume of Nitrogen are changed and must be satisfied with state equation. At cryogenic temperature, Nitrogen can exist as a part liquid and part vapor. Pressure-density-temperature behavior under this vaporliquid phase equilibrium is closely given by the Modified-Benedict-Webb-Rubin(MBWR) state equation. To evaluate deformation of bellows for temperature change, the numerical calculation of the volume within bellows and finite element analysis of bellows under internal pressure were iteratively performed until MBWR state equation is satisfied. The numerical results show that deformation of the bellows can be analyzed by the present method in a wide range of temperature including cryogenic temperature.

Natural Inhibitors for $CO_2$ Hydrate Formation (천연 물질을 이용한 이산화탄소 하이드레이트 형성 억제)

  • Sa, Jeong-Hoon;Lee, Bo Ram;Park, Da-Hye;Han, Kunwoo;Chun, Hee Dong;Lee, Kun-Hong
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2011.11a
    • /
    • pp.122.1-122.1
    • /
    • 2011
  • The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.

  • PDF

Development of a novel amino acid salt solution for $CO_2$ capture (아미노산염수용액을 이용한 이산화탄소 흡수제 개발)

  • Lim, Jin-Ah;Jo, Min;Jeong, Soon-Kwan;Nam, Sung-Chan;Yoon, Yeo-Il;Kim, Dong-Hyun
    • Proceedings of the KAIS Fall Conference
    • /
    • 2011.05a
    • /
    • pp.310-313
    • /
    • 2011
  • 본 논문에서는 지구온난화의 주요원인 중의 하나인 이산화탄소를 포집하기 위한 새로운 흡수제를 연구하였다. 액상 흡수법에서 가장 중요한 핵심 기술요소는 성능과 경제성면에서 우수한 흡수제를 개발하는 것이다. 흡수평형장치인 VLE(Vapor-Liquid Equilibrium)장치를 사용하여 신규흡수제의 이산화탄소 흡수능을 평가하고 특성을 알아봄으로써 신 흡수제를 개발하고자 하였다. 기존 아민흡수제인 MEA(monoethanolamine), DEA(diethanolamine)와 비교한 결과 아미노산염 흡수제의 경우 MEA (1.108), DEA (1.105)의 이산화탄소 흡수능보다 0.15~0.2 (mol $CO_2$/mol absorbent) 더 높은 흡수능과 2.5~3배 더 빠른 겉보기 속도를 나타내는 것을 확인하였다. 본 연구를 통하여 개발된 아미노산염 흡수제가 경제적인 이산화탄소 포집공정을 구현할 수 있는 가능성을 확인하였다.

  • PDF

Numerical Analysis of Partial Cavitaing Flow Past Axisymmetric Cylinders (축대칭 실린더형상 주위 부분공동 유동의 전산해석)

  • Kim, Bong-Su;Lee, Byung-Woo;Park, Warn-Gyu;Jung, Chul-Min
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.33 no.2
    • /
    • pp.69-78
    • /
    • 2009
  • Cavitating flow simulation is of practical importance for many hydraulic engineering systems, such as pump, turbine, nozzle, injector, etc. In the present work, a solver for cavitating flow has been developed and applied to simulate the flows past axisymmetric cylinders. Governing equations are the two-phase Navier-Stokes equations, comprised of continuity equation of liquid and vapor phase. The momentum equation is in the mixture phase. The solver employed an implicit, dual time, preconditioned algorithm in curvilinear coordinates. Computations were carried out for three axisymmetric cylinders: hemispherical, ogive, and caliber-0 forebody shape. Then, the present calculations were compared with experiments and other numerical results to validate the present solver. Also, the code has shown its capability to accurately simulate the re-entrant jet phenomena and ventilated cavitation. Hence, it has been found that the present numerical code has successfully accounted for cavitating flows past axisymmetric cylinders.

Development of a High Flow CHF Correlation for the KMRR Fuel (KMRR 핵연료에 대한 고유량 임계열속 상관식 개발)

  • Park, Cheol;Hwang, Dae-Hyun;Yoo, Yeon-Jong;Park, Jong-Ryul
    • Nuclear Engineering and Technology
    • /
    • v.26 no.2
    • /
    • pp.237-246
    • /
    • 1994
  • A high flow critical heat flux (CHF) correlation, based on the single-pin CHF experimental data for finned and unfinned heated rods, was developed for the thermal-hydraulic design and safety analysis of the Korea Multi-purpose Research Reactor (KMRR) core. The correlation consists of dimensionless parameters such as Reynolds number, thermodynamic equilibrium quality, liquid-to-vapor density ratio, and hydraulic equivalent diameter ratio. The fin effect was taken into account in the correlation by a finned-to-unfinned heated perimeter ratio. The effects of a cold wall and non-uniform axial power distribution ore discussed to verify the applicability of the single-pin based correlation to the KMRR fuel bundle. The correlation limit departure from nucleate boiling ratio (DNBR) was determined as 1.44 from the statistical analysis of the CHF data.

  • PDF

Design of Naphtha Cracker Gas Splitter Process in Petlyuk Column (납사열분해 가스분리공정에서의 Petlyuk Column 설계)

  • Lee, Ju Yeong
    • Journal of the Korean Institute of Gas
    • /
    • v.24 no.1
    • /
    • pp.17-22
    • /
    • 2020
  • Light Naphtha is distillated from crude oil unit and separated into the methane, ethylene and propylene by boiling point difference in sequence. This separation is conducted using a series of binary-like columns. This separation method is known that the energy consumed in the reboiler is used to separate the heaviest components and most of this energy is discarded as vapor condensation in the overhead cooler. In this study, the first two columns of the separation process are replaced with the Petlyuk column. A structural design was exercised by the stage computation with ideal tray efficiency in equilibrium condition. Compared with the performance of a conventional system of 3-column model, The design outcome shows that the procedure is simple and efficient because the composition of the liquid component in the column tray was designed to be similar to the equilibrium distillation curve. The performance of the new process indicates that an energy saving of 12.1% is obtained and the cost savings of 44 million won per day based on gross domestic product is reduced under same total number of trays and the initial investment cost is saved.