• 한국항공우주학회지
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• 제44권4호
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• pp.333-342
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• 2016

액체로켓 추진시스템은 액체 추진제와 액체 산화제의 화학반응을 통해 추력을 발생하는 방식으로써 우주발사체 및 인공위성을 포함한 우주비행체에 광범위하게 적용되고 있다. 일반적으로 사용되는 액체로켓 추진제로는 모노메틸하이드라진/사산화이질소, 액체수소/액체산소 및 RP-1/액체산소 조합 등이 있다. 본 연구의 목적은 액체로켓 추진제의 열화학적 반응을 수치적으로 분석함으로써, 이를 통해 궁극적으로 액체로켓엔진의 설계와 성능에 필요한 유용한 정보를 예측하고자 하는 데 있다. 이를 위해 앞서 언급한 3가지 조합의 연료와 산화제에 대하여 연소반응 후 화학평형상태에 도달했을 때 주요 요소평형반응들의 평형상수 값들을 이용해 최종 생성물의 성분과 화학조성을 계산하였고 그 결과를 이용해 단열화염온도와 로켓성능변수인 비추력을 예측하는 연구를 진행하였다.

• 대한화학회지
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• 제57권3호
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• pp.370-376
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• 2013

A back propagation artificial neural network model with one hidden layer is established to correlate the liquid-liquid equilibrium data of hydrocarbon-water systems. The model has four inputs and two outputs. The network is systematically trained with 48 data points in the range of 283.15 to 405.37K. Statistical analyses show that the optimised neural network model can yield excellent agreement with experimental data(the average absolute deviations equal to 0.037% and 0.0012% for the correlated mole fractions of hydrocarbon in two coexisting liquid phases respectively). The comparison in terms of average absolute deviation between the correlated mole fractions for each binary system and literature results indicates that the artificial neural network model gives far better results. This study also shows that artificial neural network model could be developed for the phase equilibria for a family of hydrocarbon-water binaries.

• 한국산학기술학회논문지
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• 제14권4호
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• pp.2055-2061
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• 2013

청정대체 에너지로 관심이 고조되고 있는 바이오 에탄올의 경제적 생산은 고유가 시대에 있어 매우 중요하다. 분리공정에서 성공적인 정류탑의 설계에는 정확한 기-액 평형치가 이용된다. 2성분 Ethanol/3-methyl-1-butanol 계에 대하여 정온하 즉 50, 55, 60, 65, 70, 75 및 $80^{\circ}C$에서 2성분 기-액평형측정치를 측정하고, 그 측정치를 이용하여 기액평형치를 추산하는 추산식을 이끌어 내었다. 측정치와 추산치를 비교 검토한 결과 ${\pm}0.0005$, ${\pm}0.0022$의 범위 내에서 잘 일치함을 확인하였다.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.142-147
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• 2008

This paper reports an analysis of self-pressurization in a closed cryogenic liquid storage system and its comparison with experimental data using liquid nitrogen. Partial equilibrium model(PEM), revised thermodynamic analysis of homogeneous model, has been applied for the pressurization in a closed tank. The vapor and liquid bulk temperature and the liquid-vapor interface temperature are separately calculated as their own representative values in this analysis. The analysis results of the partial equilibrium model are compared with the experimental data and other preceding homogeneous temperature models for validation.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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• pp.418-425
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• 2004

Characteristics of a liquid-vapor interface where a nonequilibrium condensation flow exists are considered based on molecular dynamics simulations, The condensation coefficient, the velocity distributions of the reflected and evaporated molecules and the number flux of the evaporated molecules are compared with those under the liquid-vapor equilibrium. The comparison shows that the condensation coefficient under the nonequilibrium condensation is slightly larger and the number flux of the evaporated molecules is considerably smaller than those under the liquid-vapor equilibrium. The net condensation flux under the nonequilibrium condensation is underestimated if it is evaluated from the condensation coefficient and the number flux of the evaporated molecules under the liquid-vapor equilibrium. However the underestimation is relatively small.

• 설비공학논문집
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• 제10권2호
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• pp.238-250
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• 1998

Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC125/134a are measured in the range between 268.15 and 283.15K at five compositions. Twenty-five equilibrium data are obtained. To verify consistency of these data, they are tested for thermodynamic consistency. Based upon the present data, the binary interaction parameter for CSD and RKS equation of state is calculated at five isotherms and comparison with the data in the open literatures is made. Results of Nagel and Bier are in very good agreements with those from this study within 0.32∼1.11% for bubble point pressure and －0.66∼0.18% for vapor mole fraction.

• 설비공학논문집
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• 제9권4호
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• pp.527-535
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• 1997

Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC32/134a are measured in the range between 258.15 and 283.15K at compositions of 0.2, 0.4, 0.6 and 0.8 mole fraction of HFC32. Twenty-two equilibrium data are obtained. Based upon the present data, the binary interaction parameter for Carnahan-Starling-De Santis equation of state is calculated. Temperature range of data is extended to 313.04K using the data in the open literatures. Interaction parameters are determined at nine isotherms.

• 설비공학논문집
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• 제15권7호
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• pp.563-571
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• 2003

The forty vapor-liquid equilibrium data of the binary system, HFC125＋Propane, were measured between 273.15 and 313.15 K at 10 K interval and the composition range 0.2∼0.75, respectively. Experiments were performed in a circulation type apparatus in which the vapor phase was forced through the liquid phase. The composition at equilibrium were mea-sured by gas chromatography, and its response was calibrated using gravimetrically prepared mixtures. Vapor-liquid equilibrium data were calculated by using CSD equation of state and compared with the experimental data.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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• pp.161-167
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• 2009

The liquid solar air conditioning system is introduced as an alternative solution to control air condition and to save electrical energy consumption. The heat and mass transfer performances of dehumidifier/regenerator in liquid solar air conditioning system are influenced by air and desiccant condition. The application of this system, the thermal energy from the sun and inlet air are unable to control, but operation parameter of other components such as pump, fan and sensible cooling unit are able to control. The equilibrium point of heat and mass transfer are the liquid desiccant and inlet air conditions, where, the heat and mass are not transferred between the liquid desiccant and vapor air. By knowing equilibrium point of heat and mass transfer, the suitable optimal desiccant conditions for certain air condition are funded. This present experiment study is investigated the equilibrium point heat and mass transfer in various air and desiccant temperature. The benefit of equilibrium point heat and mass transfer will be helpful in choose and design proper component to optimize electrical energy consumption.

• 한국산업융합학회 논문집
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• 제7권1호
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• pp.97-105
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• 2004

The Vapor-liquid equilibrium data for the binary system of 2-methyl-2-propanol-2-butanone are measured at subatmospheric pressure of 100, 200, 300, 400, 500, 600, 700 and 760 torr. This study shows that the relations between logarithmic values of relative valatility(log ${\alpha}$)and liquid phase composition(${\chi}$) in the above binary systems are expressed as a linear function. When the linear relationships of between logarithmic values of relative volatilities and liquid phase compositions in the binary systems of various pressure intersect at a point, this empirical equation can be applied to the systems of this kind. From these relations the vapor-liquid equilibrium data are estimated and compared with the measured values to be in a good agreement with in accuracy ${\pm}0.0021$ for the various pressure.